Halogen Free Flame Retardant Polycarbonate/Thermoplastic Polyester Molding Compositions with Polymeric Phosphorus Flame Retardant
This disclosure relates to halogen-free flame retardant polycarbonate/thermoplastic polyester molding compositions with improved mechanical properties and increased polyester loading level. More particularly, the disclosure relates to halogen-free polycarbonate/thermoplastic polyester resin alloys with polymeric phosphorus flame retardant additive and siloxane impact modifier. Also included are methods for preparing such compositions and articles there from.
1 - 13 . (canceled)
14 . A thermoplastic composition comprising, based on total weight of the composition:
from 10 to 50 weight percent of a terephthalate-based polyester;
from 15 to 65 weight percent of a polycarbonate;
a silicone material selected from the group consisting of: (i) from 20 to 40 weight percent of a polyorganosiloxane-polycarbonate copolymer; (ii) from 1 to 5 weight percent of a silicone rubber; or a mixture thereof; wherein the siloxane content of the silicone material is greater than 15 weight percent;
from 3 to 12 weight percent of a bisphenol A-based polyphosphonate homopolymer flame retardant having repeat units of the structure:
and
from 0.01 to 5 weight percent of an antidripping agent;
and wherein the composition has:
a notched Izod impact strength of greater than 500 J/m measured at room temperature, according to ASTM D256 on a sample bar molded from the composition and having a thickness of 3.2 mm;
a Vicat softening temperature higher than 120° C. in accordance with ASTM D1525 on a sample bar molded from the composition and having a thickness of 3.2 mm;
a heat deflection temperature of at least 90° C. when measured in accordance with ASTM 648 under a load of 1.82 MPa using a sample bar molded from the composition and having a thickness of 3.2 mm; and
a UL-94 flammability rating of V0 measured on a molded sample with a thickness of 1.5 mm.
15 . The thermoplastic composition of claim 14 , wherein the polycarbonate is a bisphenol A-based polycarbonate.
16 . The thermoplastic composition of claim 15 , comprising from 20 to 65 weight percent of a bisphenol A-based polycarbonate.
17 . The thermoplastic composition of claim 14 , wherein the terephthalate-based polyester is a polyethylene terephthalate or a poly(1,4-butylene) terephthalate or a mixture thereof.
18 . The thermoplastic composition of claim 17 , comprising from 15 to 40 weight percent of poly(1,4-butylene terephthalate) (PBT) or poly(ethylene terephthalate) (PET) or a mixture thereof.
19 . The thermoplastic composition of claim 14 , wherein the silicone material is selected form the group consisting of polycarbonate-polysiloxane copolymers, methacrylate-acrylate-siloxane copolymers, and mixtures thereof.
20 . The thermoplastic composition of claim 19 , comprising from 20 to 40 weight percent of a polycarbonate-polysiloxane copolymer, wherein the polycarbonate is a bisphenol A-based polycarbonate.
21 . The thermoplastic composition of claim 19 , comprising from 1 to 5 weight percent of a methacrylate-acrylate-siloxane copolymer.
22 . The thermoplastic composition of claim 14 , comprising:
from 15 to 45 weight percent of a poly(1,4-butylene terephthalate) (PBT);
from 20 to 65 weight percent of a polycarbonate which is selected from bisphenol A polycarbonate and 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP)/bisphenol A (BPA) copolycarbonate, or a combination thereof;
a silicone material where the siloxane content is greater than 15 weight percent wherein the silicone material is selected from the group consisting of: (i) from 20 to 40 weight percent of a polyorganosiloxane-polycarbonate copolymer; and (ii) from 1 to 5 weight percent of a silicone rubber; or a mixture thereof;
from 5 to 12 weight percent of the bisphenol A-based polyphosphonate homopolymer flame retardant; and
from 0.5 to 2 weight percent of an antidripping agent;
and wherein the composition has:
a notched Izod impact strength of greater than 500 J/m measured at room temperature, according to ASTM D256 on a sample bar molded from the composition and having a thickness of 3.2 mm;
a Vicat softening temperature higher than 120° C. in accordance with ASTM D1525 on a sample bar molded from the composition and having a thickness of 3.2 mm; and
a UL-94 flammability rating of V0 measured on a molded sample with a thickness of 1.5 mm.
23 . The thermoplastic composition of claim 22 , comprising:
from 17 to 37 weight percent of a poly(1,4-butylene terephthalate) (PBT);
from 25 to 60 weight percent of a polycarbonate which is selected from bisphenol A polycarbonate and 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP)/bisphenol A (BPA) copolycarbonate, or a combination thereof;
a silicone material where the siloxane content is greater than 15 weight percent wherein the silicone material comprises from 20 to 40 weight percent of a polyorganosiloxane-polycarbonate copolymer and from 1 to 5 weight percent of a silicone rubber;
from 7 to 12 weight percent of the bisphenol A-based polyphosphonate homopolymer flame; and
from 0.5 to 2 weight percent of an antidripping agent which is poly(tetrafluoro ethylene) and styrene-acrylonitrile in a 50:50 weight ratio;
and wherein the composition has:
a notched Izod impact strength of greater than 500 J/m measured at room temperature, according to ASTM D256 on a sample bar molded from the composition and having a thickness of 3.2 mm;
a Vicat softening temperature higher than 120° C. in accordance with ASTM D1525 on a sample bar molded from the composition and having a thickness of 3.2 mm; and
a UL-94 flammability rating of V0 measured on a molded sample with a thickness of 1.5 mm.
24 . The thermoplastic composition of claim 22 , comprising:
from 17 to 37 weight percent of a poly(1,4-butylene terephthalate) (PBT);
from 25 to 60 weight percent of a polycarbonate which is selected from bisphenol A polycarbonate and 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP)/bisphenol A (BPA) copolycarbonate, or a combination thereof;
a silicone material where the siloxane content is greater than 15 weight percent wherein the silicone material is from 22 to 38 weight percent of a polyorganosiloxane-polycarbonate copolymer;
from 7 to 12 weight percent of the bisphenol A-based polyphosphonate homopolymer flame retardant; and
from 0.5 to 2 weight percent of an antidripping agent which is poly(tetrafluoro ethylene) and styrene-acrylonitrile in a 50:50 weight ratio;
and wherein the composition has:
a notched Izod impact strength of greater than 500 J/m measured at room temperature, according to ASTM D256 on a sample bar molded from the composition and having a thickness of 3.2 mm;
a Vicat softening temperature higher than 120° C. in accordance with ASTM D1525 on a sample bar molded from the composition and having a thickness of 3.2 mm; and
a UL-94 flammability rating of V0 measured on a molded sample with a thickness of 1.5 mm.
25 . The thermoplastic composition of claim 22 , comprising:
from 17 to 37 weight percent of a poly(1,4-butylene terephthalate) (PBT);
from 25 to 60 weight percent of a polycarbonate which is selected from bisphenol A polycarbonate and 2-phenyl-3,3-bis(4-hydroxyphenyl)phthalimidine (PPPBP)/bisphenol A (BPA) copolycarbonate, or a combination thereof;
a silicone material where the siloxane content is greater than 15 weight percent wherein the silicone material is from 1 to 5 weight percent of methacrylate-acrylate-siloxane copolymer;
from 7 to 12 weight percent of the bisphenol A-based polyphosphonate homopolymer flame retardant; and
from 0.5 to 2 weight percent of an antidripping agent which is poly(tetrafluoro ethylene) and styrene-acrylonitrile in a 50:50 weight ratio;
and wherein the composition has:
a notched Izod impact strength of greater than 500 J/m measured at room temperature, according to ASTM D256 on a sample bar molded from the composition and having a thickness of 3.2 mm;
a Vicat softening temperature higher than 120° C. in accordance with ASTM D1525 on a sample bar molded from the composition and having a thickness of 3.2 mm; and
a UL-94 flammability rating of V0 measured on a molded sample with a thickness of 1.5 mm.
26 . An article prepared from the composition of claim 14 .
27 . The thermoplastic composition of claim 14 , wherein the bisphenol A-based polyphosphonate homopolymer flame retardant is a reaction product of bisphenol A and tetraphenyl phosphonium phenolate.
28 . The thermoplastic composition of claim 14 , wherein the composition has a notched Izod impact strength that is at least two times greater than a notched Izod impact strength of a comparable composition, each when measured at room temperature, according to ASTM D256 on a sample bar molded from the composition and having a thickness of 3.2 mm,
wherein the comparable composition has a phosphoric or phosphonic acid ester flame retardant and does not comprise the bisphenol A-based polyphosphonate homopolymer flame retardant.
29 . The thermoplastic composition of claim 28 , wherein the phosphoric or phosphonic acid ester flame retardant is bisphenol-A bis-diphenylphosphate.
30 . The thermoplastic composition of claim 14 , wherein the composition has a Vicat softening temperature that is at least 20% greater than a Vicat softening temperature of a comparable composition, each when measured in accordance with ASTM D1525 on a sample bar molded from the composition and having a thickness of 3.2 mm,
wherein the comparable composition has a phosphoric or phosphonic acid ester flame retardant and does not comprise the bisphenol A-based polyphosphonate homopolymer flame retardant.
31 . The thermoplastic composition of claim 30 , wherein the phosphoric or phosphonic acid ester flame retardant is bisphenol-A bis-diphenylphosphate.
32 . The thermoplastic composition of claim 14 , wherein the composition has a heat deflection temperature that is at least 10° C. higher than a heat deflection temperature of a comparable composition, each when measured in accordance with ASTM 648 under a load of 1.82 MPa using a sample bar molded from the composition and having a thickness of 3.2 mm,
wherein the comparable composition has a phosphoric or phosphonic acid ester flame retardant and does not comprise the bisphenol A-based polyphosphonate homopolymer flame retardant.
33 . The thermoplastic composition of claim 32 , wherein the phosphoric or phosphonic acid ester flame retardant is bisphenol-A bis-diphenylphosphate.