Electrode plate, electrochemical device and safety coating
The present invention relates to an electrode plate, an electrochemical device and a safety coating. The electrode plate comprises a current collector, an electrode active material layer and a safety coating disposed between the current collector and the electrode active material layer, the safety coating layer comprising a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix, a conductive material and an inorganic filler. The electrode plate can quickly open the circuit when the electrochemical device (for example, a capacitor, a primary battery, or a secondary battery) is in a high temperature condition or an internal short circuit occurs, and thus it may improve the high temperature safety performance of the electrochemical device.
1. An electrode plate comprising a current collector, an electrode active material layer and a safety coating disposed between the current collector and the electrode active material layer, the safety coating comprising a polymer matrix, a conductive material and an inorganic filler in which the polymer matrix is a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix, wherein based on the total weight of the safety coating, the weight percentage of the polymer matrix is from 35 wt % to 75 wt %; the weight percentage of the conductive material is from 5 wt % to 25 wt %; and the weight percentage of the inorganic filler is from 15 wt % to 45 wt %, and
wherein the inorganic filler has a conductivity a that satisfies 10 −3 S/m≤σ≤10 2 S/m, and
wherein the inorganic filler has a microhardness of more than 150 MPa, and
wherein the inorganic filler is selected from at least one of conductive carbon coating modified lithium cobalt oxide, conductive carbon coating modified lithium nickel manganese cobalt oxide, conductive carbon coating modified lithium iron phosphate, conductive carbon coating modified lithium cobalt phosphate, conductive carbon coating modified spinel lithium manganese oxide, conductive carbon coating modified lithium titanate.
2. The electrode plate as claimed in claim 1 , wherein the polymer matrix is selected from at least one of polyvinylidene fluoride (PVDF), carboxylic acid modified PVDF, acrylic acid modified PVDF, PVDF copolymer, polyvinylidene chloride (PVDC), carboxylic acid modified PVDC, acrylic acid modified PVDC and PVDC copolymer.
3. The electrode plate as claimed in claim 1 , wherein the conductive material is selected from at least one of a conductive carbon-based material, a conductive metal material, and a conductive polymer material,
wherein the conductive carbon-based material is selected from at least one of conductive carbon black, acetylene black, graphite, graphene, carbon nanotubes, carbon nanofibers;
the conductive metal material is selected from at least one of Al powder, Ni powder, and gold powder; and
the conductive polymer material is selected from at least one of conductive polythiophene, conductive polypyrrole, and conductive polyaniline.
4. The electrode plate as claimed in claim 1 , wherein the inorganic filler has a specific surface area (BET) of no more than 500 m 2 /g.
5. The electrode plate as claimed in claim 1 , wherein the inorganic filler has an average particle diameter D of 100 nm≤D≤10 μm.
6. The electrode plate as claimed in claim 1 , wherein the safety coating has a thickness H of 1 μm≤H≤20 μm.
7. The electrode plate as claimed in claim 1 , wherein the weight percentage of the polymer matrix is from 50 wt % to 75 wt %; the weight percentage of the conductive material is from 5 wt % to 15 wt %; and the weight percentage of the inorganic filler is from 15 wt % to 45 wt %.
8. The electrode plate as claimed in claim 1 , wherein the safety coating consists essentially of the polymer matrix, the electrically conductive material, and the inorganic filler.
9. The electrode plate as claimed in claim 1 , which is a positive electrode plate.
10. An electrochemical device comprising a positive electrode plate and a negative electrode plate wherein the positive electrode plate and/or the negative electrode plate is the electrode plate as claimed in claim 1 , and the electrochemical device is a capacitor, a primary battery or a secondary battery.
11. A safety coating for an electrode plate, comprising: a polymer matrix, a conductive material and an inorganic filler, wherein the polymer matrix is a fluorinated polyolefin and/or chlorinated polyolefin polymer matrix, and wherein based on the total weight of the safety coating, the weight percentage of the polymer matrix is from 35 wt % to 75 wt %; the weight percentage of the conductive material is from 5 wt % to 25 wt %; and the weight percentage of the inorganic filler is from 15 wt % to 45 wt %, and
wherein the inorganic filler has a conductivity σ that satisfies 10 −3 S/m≤σ≤10 2 S/m; and
wherein the inorganic filler has a microhardness of more than 150 MPa; and
wherein the inorganic filler is selected from at least one of conductive carbon coating modified lithium cobalt oxide, conductive carbon coating modified lithium nickel manganese cobalt oxide, conductive carbon coating modified lithium iron phosphate, conductive carbon coating modified lithium cobalt phosphate, conductive carbon coating modified spinel lithium manganese oxide, conductive carbon coating modified lithium titanate.