Paper comprising aramid pulp and a friction paper made therefrom
A paper comprises from 60 to 99 weight percent of a aramid fibrous pulp and from 1 to 40 weight percent of a polyvinylpyrrolidone coating on the fiber surface, the coating being neither chemically nor electrostatically bound to the fibers. A friction paper composite comprising the paper and a resin coating is also described.
1. A paper comprising from 60 to 99 weight percent based on the total weight of the paper of an aramid fibrous pulp, said fibrous pulp comprising fibers, and from 1 to 40 weight percent based on the total weight of the paper of polyvinylpyrrolidone present as a coating on the surface of the fibers, the coating being neither chemically nor electrostatically bound to the fibers.
2. The paper of claim 1 comprising from 80 to 98 weight percent of aramid fibrous pulp and from 2 to 20 weight percent of polyvinylpyrrolidone.
3. The paper of claim 1 comprising from 80 to 95 weight percent of aramid fibrous pulp and from 5 to 20 weight percent of polyvinylpyrrolidone.
4. The paper of claim 1 comprising from 80 to 90 weight percent of aramid fibrous pulp and from 10 to 20 weight percent of polyvinylpyrrolidone.
5. The paper of claim 1 having a ratio of tensile strength to average Gurley air permeability 300 cc value of at least 4.0 MPa/s.
6. The paper of claim 1 consisting of, or consisting essentially of, from 60 to 99 weight percent of aramid fibrous pulp and from 1 to 40 weight percent of polyvinylpyrrolidone.
7. The paper of claim 1 further comprising aramid floc, said floc comprising fibers, which floc is present in an amount of from 1 to 30 weight percent based on the total weight of the paper, wherein the polyvinylpyrrolidone is present as a coating on the surface of the aramid fibrous pulp fibers and the aramid floc fibers, and wherein the aramid fibrous pulp is no more than 98 weight percent based on the total weight of the paper.
8. The paper of claim 1 further comprising a combination of aramid floc and aramid fibrids, said aramid floc and aramid fibrids comprising fibers, which combination of aramid floc and aramid fibrids is present in an amount of from 1 to 30 weight percent based on the total weight of the paper, wherein the polyvinylpyrrolidone is present as a coating on the surface of the aramid fibrous pulp fibers and the aramid floc fibers and the aramid fibrids, and wherein the aramid fibrous pulp is no more than 98 weight percent based on the total weight of the paper.
9. The paper of claim 1 or 7 further comprising fillers or friction modifying particles.
10. The paper of claim 9 wherein the fillers or friction modifying particles are one or more of: silica, diatomaceous earth, graphite, alumina, metal oxides, metal nitrides, or metal carbides.
11. The paper of claim 7 consisting of, or consisting essentially of, from 60 to 98 weight percent based on the total weight of the paper of aramid fibrous pulp, from 1 to 30 weight percent based on the total weight of the paper of aramid floc, and from 1 to 20 weight percent based on the total weight of the paper of polyvinylpyrrolidone.
12. A composite comprising from 40 to 95 weight percent of the paper of claim 1 and from 5 to 60 weight percent of a resin wherein the resin is phenolic, silicone, polyimide or combinations thereof.
13. A composite comprising from 60 to 90 weight percent of the paper of claim 1 and from 10 to 40 weight percent of a resin wherein the resin is phenolic, silicone, polyimide or combinations thereof.
14. A composite comprising from 40 to 95 weight percent of the paper of claim 7 and from 5 to 60 weight percent of a resin wherein the resin is phenolic, silicone, polyimide or combinations thereof.
15. A composite comprising from 60 to 90 weight percent of the paper of claim 7 and from 10 to 40 weight percent of a resin wherein the resin is phenolic, silicone, polyimide or combinations thereof.