Method for producing porous graphite, and porous graphite
A method for producing porous graphite capable of realizing higher durability, output and capacity, and porous graphite. A carbon member having microvoids is obtained by a dealloying step for selectively eluting other non-carbon main components into a metal bath by immersing a carbon-containing material, composed of a compound including carbon or an alloy or non-equilibrium alloy, in the metal bath, wherein the metal bath has a solidifying point lower than the melting point of the carbon-containing material, and is controlled to a temperature lower than the minimum value of a liquidus temperature within a composition fluctuation range extending from the carbon-containing material to carbon by reducing the other non-carbon main components. The carbon member obtained in the dealloying step is graphitized by heating in a graphitization step. The carbon member graphitized in the graphitization step is subjected to activation treatment by an activation step.
1. A porous graphite, wherein the (002) average interplanar spacing as calculated from (002) diffraction peak of graphite in bulk is 0.342 nm or less, pores having a size of 2 nm to 100 nm are contained at 80% or more of total pore volume, BET specific surface area is 100 m 2 /g or more, the full width at half maximum of the (002) diffraction peak is 1.02° or less and crystallite size is 9 nm or more and 11.754 nm or less.
2. The porous graphite according to claim 1 , wherein the ratio I D /I G of peak intensity (I D ) of the D band having a Raman shift in the vicinity of 1350 cm −1 to peak intensity (I G ) of the G band having a Raman shift in the vicinity of 1582 cm −1 of the Raman spectrum is 0.5 or less and full width at half maximum in the G band is 45 cm −1 or less.
3. The porous graphite according to claim 1 , wherein BET specific surface area is 2400 m 2 /g or more.
4. The porous graphite according to claim 1 , which is in the form of a sheet.
5. The porous graphite according to claim 1 , wherein BET specific surface area is 300 m 2 /g or more.
6. The porous graphite according to claim 1 , wherein BET specific surface area is 700 m 2 /g or more.