Poly(glycerol sebacate) fibers, fabrics formed therefrom, and methods of fiber manufacture
A manufacturing process includes spinning at least one continuous poly(glycerol sebacate) (PGS)/alginate fiber from a polymeric solution comprising PGS and alginate in water, drafting the at least one continuous PGS/alginate fiber in at least one coagulation bath, and drawing the at least one continuous PGS/alginate fiber from the at least one coagulation bath. A yarn includes at least one continuous PGS fiber. A continuous poly(glycerol sebacate) (PGS)/alginate fiber forming system includes a feeding tank holding a polymeric solution of alginate and PGS, a pump, a spinneret, a first coagulation bath, a first winder, a second coagulation bath, a second winder, and a bobbin winder, the system forming at least one continuous PGS/alginate fiber from the polymeric solution of alginate and PGS.
1. A manufacturing process comprising:
spinning at least one continuous poly(glycerol sebacate) (PGS)/alginate fiber from a polymeric solution comprising PGS and alginate in water;
drafting the at least one continuous PGS/alginate fiber in at least one coagulation bath; and
drawing the at least one continuous PGS/alginate fiber from the at least one coagulation bath.
2. The manufacturing process of claim 1 , wherein the at least one continuous PGS/alginate fiber comprises a plurality of continuous PGS/alginate fibers.
3. The manufacturing process of claim 2 further comprising intermingling the plurality of continuous PGS/alginate fibers to form a multifilament yarn round.
4. The manufacturing process of claim 1 further comprising drying the at least one continuous PGS/alginate fiber to form a yarn having a predetermined moisture content.
5. The manufacturing process of claim 1 further comprising winding the at least one continuous PGS/alginate fiber on a bobbin at a traverse angle of about 6 degrees or greater.
6. The manufacturing process of claim 1 further comprising combining molten PGS and an alginate solution of alginate in water to form the polymeric solution.
7. The manufacturing process of claim 6 , wherein the alginate solution comprises alginate in water at 3% to 10% by weight of the alginate solution, the molten PGS being combined at a ratio of 1:1 to 3:1 by weight with respect to the alginate.
8. The manufacturing process of claim 1 , wherein the at least one coagulation bath comprises a first coagulation bath containing a first coagulation solution comprising at least 2% by weight calcium chloride in water.
9. The manufacturing process of claim 8 , wherein the at least one coagulation bath further comprises a second coagulation bath containing a second coagulation solution comprising 1% or less by weight calcium chloride in distilled water.
10. The manufacturing process of claim 1 further comprising forming a fabric from the at least one continuous poly(glycerol sebacate) (PGS)/alginate fiber.
11. The manufacturing process of claim 10 , wherein the forming is selected from the group consisting of weaving, knitting, and braiding.
12. The manufacturing process of claim 10 further comprising curing the PGS of the at least one continuous poly(glycerol sebacate) (PGS)/alginate fiber after forming the fabric.