Strengthened glass with ultra deep depth of compression
Chemically strengthened glass articles having at least one deep compressive layer extending from a surface of the article to a depth of compression DOC of at least about 125 μm within the glass article. The compressive stress profile includes a single linear segment or portion extending from the surface to the depth of compression DOC. Alternatively, the compressive stress profile may include an additional portion extending from the surface to a relatively shallow depth and the linear portion extending from the shallow depth to the depth of compression.
1. A glass article, the glass article comprising a thickness tin a range from 0.1 mm to 1.0 mm, and a compressive region having a compressive stress CS s , in a range from about 400 MPa to about 1200 MPa at a surface of the glass article, wherein the compressive region extends from the surface to a depth of compression DOC, wherein 0.12 ·t ≤DOC ≤ 0.22·t, and has a compressive stress profile, the compressive stress profile comprising:
a. a first portion b extending from the surface to a depth d b below the surface and having a slope m b ; and
b. a second portion c extending from about d c to the depth of compression DOC and having a slope m c , wherein −0.4 MPa/μm ≥m c ≥−3.0 MPa/μm.
2. The glass article of claim 1 , wherein the depth of compression DOC is in a range from about 95 μm to about 250 μm.
3. The glass article of claim 1 , wherein the depth of compression DOC is in a range from about 100 μm to about 190 μm.
4. The glass article of claim 1 , wherein the slope m c is in a range from about −0.7 MPa/μm to about −2.7 MPa/μm.
5. A glass article, the glass article comprising a thickness t and a compressive region having a compressive stress CS s , in a range from about 400 MPa to about 1200 MPa at a surface of the glass article, wherein the compressive region extends from the surface to a depth of compression DOC, wherein 0.1 ·t≤DOC≤0.25·t, and has a compressive stress profile, the compressive stress profile comprising:
a. a first portion b extending from the surface to a depth d b below the surface and having a slope m h ; and
b. a second portion c extending from about d c to the depth of compression DOC and having a slope m c wherein the slope m c is in a range from about −1.5 MPa/μm to about −2.7 MPa/μm.
6. The glass article of claim 1 , wherein the glass article comprises an alkali aluminosilicate glass.
7. The glass article of claim 6 , wherein the alkali aluminosilicate glass comprises up to about 10 mol % Li 2 O.
8. The glass article of claim 6 , wherein the alkali aluminosilicate glass comprises at least about 4 mol % P 2 O 5 and from 0 mol % to about 4 mol % B 2 O 3 , wherein 1.3<[(P 2 O 5 +R 2 O)/M 2 O 3 ]<2.3, where M 2 O 3 =Al 2 O 3 +B 2 O 3 , and R 2 O is the sum of monovalent cation oxides present in the alkali aluminosilicate glass.
9. The glass article of claim 6 , wherein the glass is lithium-free.
10. The glass article of claim 6 , wherein the glass consists essentially of from about 40 mol % to about 70 mol % SiO 2 ; from about 11 mol % to about 25 mol % Al 2 O 3 ; from about 4 mol % to about 15 mol % P 2 O 5 ; from about 13 mol % to about 25 mol % Na 2 O; from about 13 to about 30 mol % R x 0 , wherein R x O is the sum of the alkali metal oxides, alkaline earth metal oxides, and transition metal monoxides present in the glass; from about 11 to about 30 mol % M 2 O 3 ,where M 2 O 3 =Al 2 O 3 +B 2 O 3 ; from 0 mol % to about 1 mol % K 2 O; from 0 mol % to about 4 mol % B 2 O 3 , and 3 mol % or less of one or more of TiO 2 , MnO, Nb 2 O 5 , MoO 3 , Ta 2 O 5 , WO 3 , ZrO 2 , Y 2 O 3 , La 2 O 3 , HfO 2 , CdO, SnO 2 , Fe 2 O 3 , CeO 2 , As 2 O 3 , Sb 2 O 3 , Cl, and Br; and 1.3<[(P 2 O 5 +R 2 O)/M 2 O 3 ]<2.3, where R 2 O is the sum of monovalent cation oxides present in the glass.
11. An electronic device comprising the glass article of claim 1 .
12. The glass article of claim 5 , wherein the depth of compression DOC is in a range from about 100 μm to about 190 μm.
13. The glass article of claim 5 , wherein 0.12·t DOCS ≤0.224·t “and the thickness is in a range from 0.1 mm to about 1.0 mm”.
14. The glass article of claim 5 , wherein the glass article comprises an alkali aluminosilicate glass.
15. The glass article of claim 14 , wherein the alkali aluminosilicate glass comprises up to about 10 mol % Li 2 O.
16. The glass article of claim 14 , wherein the alkali aluminosilicate glass comprises at least about 4 mol % P 2 O 5 and from 0 mol % to about 4 mol % B 2 O 3 , wherein 1.3<[(P 2 O 5 +R 2 O)/M 2 O 3 ]<2.3, where M 2 O 3 =Al 2 O 3 +B 2 O 3 , and R 2 O is the sum of monovalent cation oxides present in the alkali aluminosilicate glass.
17. The glass article of claim 14 , wherein the glass consists essentially of from about 40 mol % to about 70 mol % SiO 2 ; from about 11 mol % to about 25 mol % Al 2 O 3 ; from about 4 mol % to about 15 mol % P 2 O 5 ; from about 13 mol % to about 25 mol % Na 2 O; from about 13 to about 30 mol % R x O is the sum of the alkali metal oxides, alkaline earth metal oxides, and transition metal monoxides present in the glass; from about 11 to about 30 mol % M 2 O 3 ,where M 2 O 3 =Al 2 O 3 +B 2 O 3 ; from 0 mol % to about 1 mol % K 2 O; from 0 mol % to about 4 mol % B 2 O 3 , and 3 mol % or less of one or more of TiO 2 , MnO, Nb 2 O 5 , MoO 3 , Ta 2 O 5 , WO 3 , ZrO 2 , Y 2 O 3 , La 2 O 3 , HfO 2 , CdO, SnO 2 , Fe 2 O 3 , CeO 2 , As 2 O 3 , Sb 2 O 3 , Cl, and Br; and 1.3<[(P 2 O 5 +R 2 O)/M 2 0 3 ]<2.3, where R 2 O is the sum of monovalent cation oxides present in the glass.
18. An electronic device comprising the glass article of claim 5 .