Supercapacitor electrode having highly oriented and closely packed expanded graphite flakes
Provided is a supercapacitor electrode, comprising: (a) preparing a deformable mass of multiple flakes of exfoliated graphite worms or expanded graphite dispersed in or impregnated by a liquid or gel electrolyte; and (b) subjecting the deformable mass to a forced assembling and orientating procedure, forcing the deformable mass to form the electrode, wherein these fakes are spaced by thin electrolyte layers, having an electrolyte layer thickness from 0.4 nm to 10 nm, and the flakes are substantially aligned along a desired direction, and wherein the electrode has a physical density from 0.5 to 1.7 g/cm 3 and a specific surface area from 50 to 3,300 m 2 /g, when measured in a dried state of the flakes without the electrolyte. This supercapacitor has a large electrode thickness, high active mass loading, high tap density, and exceptional energy density.
1. A supercapacitor comprising an anode current collector, an anode supported by said anode current collector, a cathode, a cathode current collector supporting said cathode, an ion-permeable separator that electronically separates said anode and said cathode, and an electrolyte in ionic contact with said anode and said cathode, wherein the anode and/or the cathode contain electrolyte-impregnated flakes of expanded graphite and the flakes are spaced by thin electrolyte layers having a thickness from 0.4 nm to 5 nm, and said flakes are substantially aligned along a desired direction, and wherein said electrolyte-impregnated flakes have a physical density from 0.5 to 1.7 g/cm 3 and a specific surface area from 50 to 3,300 m 2 /g, when measured in a dried state of said flakes without the presence of said electrolyte.
2. The supercapacitor of claim 1 wherein said anode contains a prelithiated anode active material or a pre-sodiated anode active material.
3. The electrolyte-impregnated flakes of expanded graphite of claim 1 , wherein said flakes are oriented parallel to the current collector surface plane.
4. The electrolyte-impregnated flakes of expanded graphite of claim 1 , wherein said flakes are oriented perpendicular to the current collector surface plane.
5. The electrolyte-impregnated flakes of expanded graphite of claim 1 , wherein said flakes have a coating with a thickness less than 100 nm, and said coating is selected from the group consisting of intrinsically conductive polymers, transition metal oxides, and organic molecules.
6. The electrolyte-impregnated flakes of expanded graphite of claim 5 , wherein coating is selected from the group consisting of polyacetylene, polypyrrole, polyaniline, polythiophene, and their derivatives.
7. The electrolyte-impregnated flakes of expanded graphite of claim 5 , wherein coating is selected from the group consisting of RuO 2 , IrO 2 , NiO, MnO 2 , VO 2 , V 2 O 5 , V 3 O 8 , TiO 2 , Cr 2 O 3 , Co 2 O 3 , Co 3 O 4 , PbO 2 , Ag 2 O, MoC x , Mo 2 N, and combinations thereof.
8. The electrolyte-impregnated flakes of expanded graphite of claim 1 wherein said electrolyte-impregnated flakes of expanded graphite are activated.
9. The electrolyte-impregnated flakes of expanded graphite of claim 1 wherein said electrolyte-impregnated flakes of expanded graphite are chemically functionalized, or are doped with atomic, ionic, or molecular species.
10. The electrolyte-impregnated flakes of expanded graphite of claim 1 wherein said electrolyte-impregnated flakes of expanded graphite comprise polymer grafting, wherein polymer is selected from the group consisting of polyacetylene, polypyrrole, polyaniline, polythiophene, sulfonated versions thereof, and their derivatives.
11. A supercapacitor comprising an anode current collector, an anode supported by said anode current collector, a cathode, a cathode current collector supporting said cathode, an ion-permeable separator that electronically separates said anode and said cathode, and an electrolyte in ionic contact with said anode and said cathode, wherein the anode and/or the cathode contain electrolyte-impregnated flakes of exfoliated graphite and the flakes are spaced by thin electrolyte layers having a thickness from 0.4 nm to 5 nm, and said flakes are substantially aligned along a desired direction, and wherein said electrolyte-impregnated flakes have a physical density from 0.5 to 1.7 g/cm 3 and a specific surface area from 50 to 3,300 m 2 /g, when measured in a dried state of said flakes without the presence of said electrolyte.
12. The supercapacitor of claim 11 wherein said anode contains a prelithiated anode active material or a pre-sodiated anode active material.
13. The electrolyte-impregnated flakes of exfoliated graphite of claim 11 , wherein said flakes are oriented parallel to the current collector surface plane.
14. The electrolyte-impregnated flakes of exfoliated graphite of claim 11 , wherein said flakes are oriented perpendicular to the current collector surface plane.
15. The electrolyte-impregnated flakes of exfoliated graphite of claim 11 , wherein said flakes have a coating with a thickness less than 100 nm, and said coating is selected from the group consisting of intrinsically conductive polymers, transition metal oxides, and organic molecules.
16. The electrolyte-impregnated flakes of exfoliated graphite of claim 15 , wherein coating is selected from the group consisting of polyacetylene, polypyrrole, polyaniline, polythiophene, and their derivatives.
17. The electrolyte-impregnated flakes of exfoliated graphite of claim 15 , wherein coating is selected from the group consisting of RuO 2 , IrO 2 , NiO, MnO 2 , VO 2 , V 2 O 5 , V 3 O 8 , TiO 2 , Cr 2 O 3 , Co 2 O 3 , Co 3 O 4 , PbO 2 , Ag 2 O, MoC x , Mo 2 N, and combinations thereof.
18. The electrolyte-impregnated flakes of exfoliated graphite of claim 11 wherein said electrolyte-impregnated flakes of expanded graphite are activated.
19. The electrolyte-impregnated flakes of exfoliated graphite of claim 11 wherein said electrolyte-impregnated flakes of expanded graphite are chemically functionalized, or are doped with atomic, ionic, or molecular species.
20. The electrolyte-impregnated flakes of exfoliated graphite of claim 11 wherein said electrolyte-impregnated flakes of expanded graphite comprise polymer grafting, wherein polymer is selected from the group consisting of polyacetylene, polypyrrole, polyaniline, polythiophene, sulfonated versions thereof, and their derivatives.