Aqueous compositions comprising dicamba and a built-in drift control agent
Disclosed are pesticide composition comprising, by total weight of the composition (i) a pesticide comprising at least one water-soluble salt of an auxin herbicide; (ii) greater than about 1 wt % of an incompletely hydrated drift control agent suspended in a liquid medium; (iii) optionally, a hydration inhibitor component comprising choline chloride, a glycol, a glycol derivative, glycerine, a glycerine derivative or a combination thereof; and (iv) a suspending agent in an amount effective to impart shear thinning properties to the composition. In one embodiment, the suspending agent comprises (i) xanthan gum; and (ii) attapulgite.
1. A pesticide composition comprising, by total weight of the composition:
a pesticide comprising at least one water-soluble salt of an auxin herbicide;
greater than 1 wt % of an incompletely hydrated drift control agent suspended in a liquid medium;
a hydration inhibitor component comprising choline chloride, a glycol, a glycol derivative, glycerine, a glycerine derivative or a combination thereof; and
a suspending agent in an amount effective to impart shear thinning properties to the composition, the suspending agent comprising:
(i) xanthan gum; and
(ii) attapulgite;
wherein the suspending agent is in an amount of at least 0.5 pbw to 10 pbw based on 100 pbw of the composition.
2. The composition of claim 1 wherein the attapulgite is of formula (Mg,Al)5Si8O20.4H2O.
3. The composition of claim 1 wherein the attapulgite has a bulk density lower than 1,000 kg/m3.
4. The composition of claim 1 wherein the attapulgite has a specific gravity greater than 1.3.
5. The composition of claim 1 wherein the drift control agent is a water-soluble polymer.
6. The composition of claim 1 wherein the drift control agent is a polyacrylamide derivative.
7. The composition of claim 1 wherein the polyacrylamide derivative is acrylamide copolymerized with at least one of dimethylacrylamides (DMA), acrylamidomethylpropanesulfonic acids (AMPS), or acrylic acid (AA).
8. The composition of claim 1 wherein the pesticide comprises a dicamba salt, wherein the salt is N,N-bis(3-aminopropyI)methylamine, diethanolamine, monoethanolamine, dimethylamine, isopropylamine, dimethylethanolamine, diglycolamine, potassium, choline, or sodium.
9. The composition of claim 1 wherein the pesticide comprises dicamba diglycolamine salt or dicamba N,N-bis(3-aminopropyI)methylamine salt.
10. The composition of claim 1 wherein the drift control agent comprises a guar derivative, the guar derivative comprising cationic guar, carboxymethyl guar (CM guar), hydroxyethyl guar (HE guar), hydroxypropyl guar (HP guar), carboxymethylhydroxypropyl guar (CMHP guar), hydrophobically modified guar (HM guar), hydrophobically modified carboxymethyl guar (HMCM guar), hydrophobically modified hydroxyethyl guar (HMHE guar), hydrophobically modified hydroxypropyl guar (HMHP guar), cationic hydrophobically modified hydroxypropyl guar (cationic HMHP guar), hydrophobically modified carboxymethylhydroxypropyl guar (HMCMHP guar), hydrophobically modified cationic guar (HM cationic guar), guar hydroxypropyl trimonium chloride, or hydroxypropyl guar hydroxypropyl trimonium chloride.
11. The composition of claim 1 wherein the drift control agent is native guar, polyacrylamide, a cationic hydroxypropyl guar, a cationic guar, or a combination thereof.
12. The composition of claim 1 wherein the hydration inhibitor component comprises propylene glycol or poly(ethylene glycol).
13. The composition of claim 1 wherein the drift control agent is guar gum and the hydration inhibitor component is propylene glycol.
14. The composition of claim 1 whereby the composition is stable at a temperature greater than 50° C. for at least 24 hours.
15. The composition of claim 1 whereby the composition is stable at a temperature greater than 50° C. for at least 48 hours.
16. The composition of claim 1 whereby the composition is stable for at least 24 hours at room temperature.
17. The composition of claim 1 further comprising one or more surfactants.
18. The composition of claim 1 , wherein the suspending agent further comprises hydrophobic fumed silica.
19. The composition of claim 1 , wherein the suspending agent comprises at least a hydrophobic fumed silica which has been hydrophobized by means of dimethyldichlorosilane.
20. The composition of claim 1 wherein the hydration inhibitor component is present in an amount effective to inhibit hydration of the water-soluble polysaccharide in the aqueous medium and wherein the hydration inhibitor component further comprises at least one of: one or more surfactant compounds, one or more water-soluble non-surfactant salts, or one or more water dispersible organic solvents.
21. The composition of claim 1 , wherein the liquid medium is an aqueous liquid medium that comprises water or water and a water immiscible organic liquid, and wherein the composition is in the form of an emulsion, a microemulsion, or a suspoemulsion.
22. The composition of claim 1 wherein the composition exhibits a viscosity of less than 10 Pa·s at a shear rate of greater than or equal to 10 s −1 .
23. The composition of claim 1 wherein the composition comprises greater than 1.8 wt % of an incompletely hydrated drift control agent suspended in a liquid medium.
24. The composition of claim 1 wherein the composition comprises greater than 2 wt % of an incompletely hydrated drift control agent suspended in a liquid medium.
25. The composition of claim 1 wherein the composition comprises greater than 2.4 wt % of an incompletely hydrated drift control agent suspended in a liquid medium.
26. The composition of claim 1 wherein the hydration inhibitor component further comprises choline bicarbonate, choline dihydrogen citrate, choline bitarate, potassium hydrogen phosphate, potassium carbonate, or any combination thereof.
27. The composition of claim 1 wherein the composition exhibits:
a viscosity of greater than or equal to 5 Pa·s at a shear rate of less than 0.01 s−1, and
a viscosity of less than 5 Pa·s at a shear rate of greater than 10 s−1.
28. The composition of claim 1 wherein the composition is free or substantially free of ammonium-containing compounds.
29. The composition of claim 1 , wherein the composition comprises greater than 1 wt % of hydrophobic silica by total weight of composition.
30. The composition of claim 1 further comprising the presence of at least 300 g/L of water soluble salts.
31. The composition of claim 1 , wherein the composition comprises at least 300 g/L of at least one water-soluble salt of an auxin herbicide.
32. The composition of claim 1 , wherein the composition comprises greater than 10 wt % of an aqueous liquid medium by total weight of the composition.
33. A pesticide composition comprising, by total weight of the composition:
a pesticide comprising an auxin herbicide or a salt thereof;
greater than 1 wt % of an incompletely hydrated drift control agent suspended in a liquid medium;
a hydration inhibitor component comprising choline chloride, a glycol, a glycol derivative, glycerine, a glycerine derivative or a combination thereof; and
a suspending agent in an amount effective to impart shear thinning properties to the composition, the suspending agent comprising:
at least one of xanthan gum, rheozan, and diutan gum; and
attapulgite clay;
wherein the suspending agent is in an amount of at least 0.5 pbw to 10 pbw based on 100 pbw of the composition.
34. The composition of claim 1 , wherein the composition is flowable and stable at temperatures greater than −10° C. and up to 54° C.