Secondary battery
A secondary battery is provided. The secondary battery includes an electrode assembly, a case that accommodates the electrode assembly, and a protection member disposed within the case. The protection member includes a curing promoter, an adhesive, and a protective film that separates the curing promoter and the adhesive.
1. A secondary battery comprising:
an electrode assembly;
a case that accommodates the electrode assembly; and
a protecting member disposed within the case between an outer surface of the electrode assembly and an inner surface of the case,
wherein the protecting member comprises:
a curing promoter;
an adhesive; and
a protective film that separates the curing promoter and the adhesive, and
wherein, when the curing promoter and the adhesive are reacted with each other, a curing layer is formed on the inner surface of the case to strengthen the case.
2. The secondary battery of claim 1 , wherein the protective film is configured to be destroyed when pressure is equal to or greater than a predetermined pressure.
3. The secondary battery of claim 2 , wherein the predetermined pressure is about 0.5 MPa.
4. The secondary battery of claim 2 , wherein the curing promoter and the adhesive are configured to contact and react with each other when the protective film is destroyed.
5. The secondary battery of claim 2 , wherein the protective film includes one or more materials selected from the group consisting of low density polyethylene (LDPE), high density polyethylene (HDPE), oriented polypropylene (OPP), casting polypropylene (CPP), oriented nylon (ON), casting nylon (CN), and polyethylene terephthalate (PET).
6. The secondary battery of claim 2 , wherein the protective film has a thickness of about 10 μm to 50 μm.
7. The secondary battery of claim 1 , wherein the curing promoter includes one or more materials selected from the group consisting of a polyol, a polyether polyol, and a polyester polyol.
8. The secondary battery of claim 1 , wherein the adhesive includes one or more materials selected from the group consisting of toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI), hexamethylene diisocyanate (HDI), and isophorone diisocyanate (IPDI).
9. The secondary battery of claim 1 , wherein a content ratio between the curing promoter and the adhesive is between about 30:70 and about 70:30.
10. The secondary battery of claim 1 , wherein the protective film includes a preliminary breakage part having a thickness less than thicknesses of other portions of the protective film.
11. The secondary battery of claim 10 , wherein the preliminary breakage part includes a line form or a dotted line form.
12. The secondary battery of claim 1 , wherein the protective film includes a tube including a cross-linking agent therein.