Stabilized lithium metal powder for li-ion application composition
The present invention provides a lithium metal powder protected by a wax. The resulting lithium metal powder has improved stability and improved storage life.
1. An anode comprising a host material capable of absorbing or desorbing lithium in an electrochemical system and a stabilized lithium metal powder dispersed in the host material, wherein the stabilized lithium metal powder is coated with a wax, wherein the stabilized lithium metal powder has a mean diameter of from 10 μm to 200 μm in N-methyl-2-pyrrolidine or gamma butyrolactone, the wax is a continuous layer and has a thickness of 20 nm to 200 nm.
2. An anode according to claim 1 , wherein the wax is selected from the group consisting of natural waxes, synthetic waxes, petroleum waxes, and microcrystalline waxes.
3. An anode according to claim 1 , further comprising an inorganic coating.
4. The anode of claim 3 , wherein the inorganic coating is selected from the group consisting of Li 2 CO 3 , LiF, Li 3 PO 4 , SiO 2 , Li 2 SO 4 , LiAlO 2 , Li 2 TiO 3 , and LiNbO 3 .
5. The anode of claim 1 , wherein said host material comprises at least one material selected from the group consisting of carbonaceous materials, silicon, tin, tin oxides, composite tin alloys, transition metal oxides, lithium metal nitrides, graphite, carbon black, and lithium metal oxides.
6. A battery incorporating the anode of claim 1 .