IP Library Granted Patent US 10,957,826
Granted Patent B2
US 10,957,826 · App. 16/196,095 · Granted Mar 23, 2021

White light source including LED and phosphors

Inventors: Tatsunori Itoga (Yokohama, JP); Ryoji Tsuda (Fujisawa, JP); Naotoshi Matsuda (Chigasaki, JP); Yoshitaka Funayama (Yokohama, JP)
Assignees: Kabushiki Kaisha Toshiba; Toshiba Materials Co., Ltd.
H01L33/504C09K11/0883C09K11/64C09K11/66C09K11/73C09K11/7734C09K11/7739C09K11/7774H01L25/0753H01L33/50Y02B20/00
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Quick Facts
Patent No.
US 10,957,826
App. No.
16/196,095
Granted
Mar 23, 2021
Kind
B2
Abstract

According to one embodiment, a white light source includes a combination of a light emitting diode and phosphors. One of the phosphors is at least a cerium activated yttrium aluminum garnet-based phosphor. There is no light emission spectrum peak at which a ratio of a largest maximum value to a minimum value is greater than 1.9. The largest maximum value is largest among at least one maximum value present in a wavelength range of 400 nm to 500 nm in a light emission spectrum of white light emitted from the white light source. The minimum value is adjacent to the largest maximum value in a longer wavelength side of the light emission spectrum.

Claims (29)

1. A white light source comprising:

a light emitting diode (LED); and

phosphors,

wherein one of the phosphors is at least a cerium activated yttrium aluminum garnet-based phosphor,

wherein there is no light emission spectrum peak that has a ratio of a largest maximum value to a minimum value of greater than 1.9,

wherein the ratio is defined by a light emission spectrum intensity in a wavelength that indicates the largest maximum value divided by a light emission spectrum intensity in a wavelength that indicates the minimum value,

wherein the largest maximum value is a largest value among at least one maximum light emission intensity value present in a wavelength range of 400 nm to 500 nm in a light emission spectrum of white light emitted from the white light source,

wherein the minimum value is a light emission intensity value having a minimum value and being adjacent to the largest maximum value in a longer wavelength side of the light emission spectrum, and

wherein an average color rendering index Ra of white light emitted from the white light source is 96 or higher, and wherein all color rendering indices R1 to R15 are 85 or higher.

2. The white light source according to claim 1 , wherein the LED emits ultraviolet to violet light having an emission peak in a wavelength range of 350 nm to 420 nm,

wherein the phosphors constitute a mixed phosphor that further includes a blue phosphor, and

wherein white light emitted from the mixed phosphor has a continuous spectrum over a wavelength range of 400 nm to 780 nm.

3. The white light source according to claim 2 , wherein the cerium activated yttrium aluminum garnet-based phosphor is a green to yellow phosphor having an emission peak in a wavelength range of 510 nm to 570 nm, and

wherein the blue phosphor is made of at least one of a europium activated alkaline earth halophosphate phosphor and a europium activated barium magnesium aluminate phosphor, and has an emission peak in a wavelength range of 430 nm to 480 nm.

4. The white light source according to claim 2 , wherein the cerium activated yttrium aluminum garnet-based phosphor is a green to yellow phosphor having an emission peak in a wavelength range of 510 nm to 570 nm, and

wherein the blue phosphor is a mixed phosphor consisting of at least one type of a first blue phosphor having an emission peak in a range of 430 nm to 470 nm, and at least one type of a second blue phosphor having an emission peak in a range of a wavelength longer than 470 nm to 485 nm,

wherein the first blue phosphor is at least one of a europium activated alkaline earth halophosphate phosphor and a europium activated alkaline earth aluminate phosphor, and

wherein the second blue phosphor is a europium activated alkaline earth halophosphate phosphor.

5. The white light source according to claim 4 , wherein the first blue phosphor in the mixed phosphor is present in an amount of 50 wt % by weight or more with respect to an entire amount of the blue phosphor, and

wherein the second blue phosphor in the mixed phosphor is present in an amount of 50 wt % or less with respect to the entire amount of the blue phosphor.

6. The white light source according to claim 3 , wherein the blue phosphor is a europium activated alkaline earth halophosphate phosphor having a chemical composition expressed as (Sr 1-x-y Ba x Ca y ) 5 (PO 4 ) 3 Cl: Eu, wherein x and y satisfy 0≤x≤0.44, 0≤y≤0.1.

7. The white light source according to claim 3 , further comprising a europium activated alkaline earth orthosilicate phosphor as the green to yellow phosphor.

8. The white light source according to claim 6 , wherein an emission peak wavelength of the blue phosphor is in a range of 440 nm to 470 nm.

9. The white light source according to claim 6 , wherein the blue phosphor is a europium activated alkaline earth halophosphate phosphor having a chemical composition expressed as (Sr 1-x-y Ba x Ca y ) 5 (PO 4 ) 3 Cl: Eu, wherein x and y satisfy 0≤x≤0.35 and 0≤y≤0.1.

10. The white light source according to claim 6 , wherein the phosphors include two kinds of phosphors, including the cerium activated yttrium aluminum garnet-based phosphor and a europium activated alkaline earth halophosphate phosphor, and

wherein a weight ratio of the cerium activated yttrium aluminum garnet-based phosphor to the europium activated alkaline earth halophosphate phosphor is in a range of 29:71 parts by weight to 10:90 parts by weight.

11. The white light source according to claim 1 , wherein the phosphors include a red phosphor, and

wherein the red phosphor is at least one of a europium activated strontium sialon phosphor, a europium activated alkaline earth nitride aluminosilicate phosphor, and a manganese activated magnesium fluorogermanate phosphor.

12. The white light source according to claim 1 , wherein an average particle diameter of the phosphors is 10 μm or longer and 50 μm or shorter.

Assignments (3)
NUNC PRO TUNC ASSIGNMENT Recorded Nov 26, 2021
From: TOSHIBA MATERIALS CO.,LTD.
To: SEOUL SEMICONDUCTOR CO.,LTD.
Reel/Frame 058251/0316 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 5, 2021
From: KABUSHIKI KAISHA TOSHIBA
To: TOSHIBA MATERIALS CO., LTD.
Reel/Frame 057089/0601 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 20, 2018
From: ITOGA, TATSUNORI; TSUDA, RYOJI; MATSUDA, NAOTOSHI; FUNAYAMA, YOSHITAKA
To: KABUSHIKI KAISHA TOSHIBA; TOSHIBA MATERIALS CO., LTD.
Reel/Frame 047551/0671 →
Priority Claims (1)
JP JP2016-101548 · May 20, 2016 · national
Continuity (2)
Continuation PCTJP2017018892 · May 19, 2017
Related Publication 20190088833A1 · Mar 21, 2019
Cited By (5)
US 12,245,445 US 12,321,060 US 12,547,027 US 12,554,159 US 12,619,111