IP Library Granted Patent US 11,054,530
Granted Patent B2
US 11,054,530 · App. 16/196,215 · Granted Jul 6, 2021

Substrate including scintillator materials, system including substrate, and method of use

Inventor: Peter R. Menge (Novelty, OH)
Assignee: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
G01T1/2006D21H21/48G01N21/6408G01T1/2008G01T1/2023G07D7/06G07D7/12G07D7/1205G07D7/205G07D7/206
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Quick Facts
Patent No.
US 11,054,530
App. No.
16/196,215
Granted
Jul 6, 2021
Kind
B2
Abstract

A substrate can include at least two scintillator materials that are mixed at a predetermined ratio. In an embodiment, the scintillator materials can have a decay time difference of at least 50% when exposed to a same radiation source. In another embodiment, the scintillator materials can have a maximum emission wavelength difference of at least 25 nm when exposed to a same radiation source. At least one of the scintillator materials has a decay time of at most 10 μs. A system can include the substrate and a logic element configured to determine an identity represented by the substrate. A method can include generating an electronic pulse in response to the substrate being exposed to a radiation source; and analyzing the electronic pulse to determine an identity represented by the substrate.

Claims (27)

1. A substrate, comprising a first scintillator material and a second scintillator material that is different from the first scintillator material, wherein:

the first and second scintillator materials are present in the substrate at a predetermined ratio; and

the first and second scintillator materials have a decay time difference of at least 50% and a maximum emission wavelength difference of at least 25 nm when exposed to a same radiation source,

wherein at least one of the first and second scintillator materials comprises a chelate, an organosilicon compound, and organo-metallic compound, or a triplet harvesting organic compound.

2. The substrate of claim 1 , wherein the substrate includes a fiber, a thread, a plastic film, an ink, or any combination thereof.

3. The substrate of claim 1 , wherein each of the first and second scintillator materials has a decay time of at most 1 μs.

4. The substrate of claim 1 , wherein at least one of the first and second scintillator materials has a decay time of at most 100 ns.

5. The substrate of claim 1 , wherein at least one of the first and second scintillator materials comprises an inorganic compound.

6. The substrate of claim 1 , wherein at least one of the first and second scintillator materials comprises an organic material.

7. The substrate of claim 1 , wherein the first scintillator material is mixed with the second scintillator material.

8. The substrate of claim 1 , wherein at least one of the first and second scintillator materials comprises p-terphenyl (C 18 H 14 ), 2,5-diphenyloxazole (PPO, C 15 H 11 NO), 1,1,4,4,-tetraphenylbutadiene (TBP, C 28 H 22 ), 1,2,4-trimethyl benzene (C 9 H 12 ), dimethyl stilbene (DPS, C 26 H 18 ), bis-MSB (C 24 H 22 ), dimethyl POPOP (C 26 H 20 N 2 O), K27 (C 26 H 14 O 6 N 6 S 2 Ru), tris [1-phenylisoquinolinato] iridum (III) (C 15 NlrH 10 ), or a combination thereof.

9. The substrate of claim 1 , wherein the first or the second scintillator material is not sensitive to a visible light.

10. A system, comprising:

the substrate of claim 1 ; and

a logic element configured to determine an identity represented by the substrate based at least in part on a decay time, a maximum emission wavelength, or both.

11. The system of claim 10 , wherein the logic element includes a field programmable gate array, application-specific integrated circuit, a processor, or a combination thereof.

12. A substrate, comprising a first scintillator material and a second scintillator material that is different from the first scintillator material, wherein:

the first and second scintillator materials are present in the substrate at a predetermined ratio; and

each of the first and second scintillator materials has a decay time of at most 10 μs and a maximum emission wavelength difference of at least 25 nm when exposed to a same radiation source, wherein at least one of the first and second scintillator materials comprises a chelate, an organosilicon compound, an organo-metallic compound, or a triplet harvesting organic compound.

13. The substrate of claim 12 , wherein each of the first and second scintillator materials has a decay time of at most 100 ns.

14. The substrate of claim 12 , wherein the organic material comprise p-terphenyl (C 18 H 14 ), 2,5-diphenyloxazole (PPO, C 15 H 11 NO), 1,1,4,4,-tetraphenylbutadiene (TBP, C 28 H 22 ), 1,2,4-trimethyl benzene (C 9 H 12 ), dimethyl stilbene (DPS, C 26 H 18 ), bis-MSB (C 24 H 22 ), dimethyl POPOP (C 26 H 20 N 2 O), K27 (C 26 H 14 O 6 N 6 S 2 Ru), tris [1-phenylisoquinolinato] iridum (III) (C 15 NlrH 10 ), or a combination thereof.

15. The substrate of claim 12 , wherein at least one of the scintillator materials emits a scintillation light having a wavelength from 390 nm to 700 nm when exposed to the radiation source.

16. The substrate of claim 15 , wherein the scintillation light forms a predetermined pattern.

17. The substrate of claim 12 , wherein the substrate further comprises a third scintillator material that is different from the first and second scintillator materials.

18. A method, comprising: generating an electronic pulse in response to a substrate being exposed to a radiation source; analyzing the electronic pulse; and determining an identity represented by the substrate based on the electronic pulse, wherein determining the identity represented by the substrate comprises determining a composition of the substrate that includes at least two different scintillator materials that have a decay time difference of at least 50% and a maximum emission wavelength difference of at least 25 nm, wherein at least one of the at least two different scintillator materials comprises a chelate, an organosilicon compound, an organo-metallic compound, or a triplet harvesting organic compound.

19. The method of claim 18 , wherein the radiation source emits an ultraviolet light having a pulse time of at most 500 ns.

20. The method of claim 18 , wherein analyzing the electronic pulse comprises obtaining a decay time, a maximum emission wavelength, or a combination thereof based on the electronic pulse.

Assignments (4)
INTELLECTUAL PROPERTY SECURITY AGREEMENT SUPPLEMENT Recorded May 8, 2026
From: LUXIUM SOLUTIONS, LLC
To: GOLUB CAPITAL MARKETS LLC, AS COLLATERAL AGENT
Reel/Frame 075574/0443 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 18, 2023
From: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
To: LUXIUM SOLUTIONS, LLC
Reel/Frame 062419/0232 →
SECURITY INTEREST Recorded Dec 2, 2022
From: LUXIUM SOLUTIONS, LLC
To: KEYBANK NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 062049/0300 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 5, 2019
From: MENGE, PETER R.
To: SAINT-GOBAIN CERAMICS & PLASTICS, INC.
Reel/Frame 048239/0256 →
Continuity (2)
Provisional Application 62590404 · Nov 24, 2017
Related Publication 20190162864A1 · May 30, 2019