Composite separator, preparation method of the same, and electrochemical device using the same
The present disclosure relates to a composite separator, a preparation method of the composite separator, and an electrochemical device containing the composite separator. The composite separator includes a substrate and an inorganic layer disposed on at least one surface of the substrate. The substrate is a porous substrate, and the inorganic layer is an inorganic dielectric layer which is a continuous dense film layer with porosity lower than 10% and contains no binder. A thickness of the inorganic layer is 20 nm-1000 nm. An interfacial peeling force between the inorganic layer and the substrate is no less than 30 N/m. The separator of the present application has high wettability with respect to electrolyte, almost no thermal shrinkage, relatively high mechanical strength, and favorable corrosion resistance and durability performances, and thus, a battery using the separator has relatively high thermal stability and nailing strength.
1. A composite separator comprising:
(a) a substrate with a porous structure, and
(b) an inorganic layer provided on at least one surface of the substrate,
wherein the inorganic layer is an inorganic dielectric layer which is a continuous dense film layer with porosity lower than 10% and contains no binder, a thickness of the inorganic layer is 20 nm-1000 nm, and an interfacial peeling force between the inorganic layer and the substrate is no less than 30 N/m,
wherein the inorganic layer is uniformly coated on the surface of the porous substrate and inner walls of at least a part of pores; and a ratio of a depth of the pores coated with the inorganic layer to a thickness of the porous substrate is 1/1000-1/20, and
wherein the composite separator has a puncture resistance of at least 300 gram force.
2. The composite separator according to claim 1 , wherein the inorganic layer contains a material having electron-isolation property and ion-conduction performance, and the material is at least one of inorganic oxide, inorganic fluoride, inorganic nitride, or inorganic hydroxide.
3. The composite separator according to claim 2 , wherein the inorganic layer contains at least one of aluminum oxide, hydrated alumina, silicon oxide, silicon nitride, titanium oxide, titanium nitride, zinc oxide, zinc nitride, magnesium oxide, magnesium nitride, zirconium oxide, zirconium nitride, calcium oxide, calcium nitride, barium oxide, or barium nitride.
4. The composite separator according to claim 1 , wherein the substrate comprises a material selected from a group consisting of polyethylene, polypropylene, polyvinylidene fluoride, aramid fiber, polyethylene glycol terephthalate, polytetrafluoroethylene, polyacrylonitrile, polyimide, polyamide, polyester, natural fiber or any combination thereof.
5. The composite separator according to claim 1 , wherein a porosity of the substrate is 20% -80%.
6. The composite separator according to claim 1 , wherein a pore diameter of the substrate is 0.02 μm-0.5 μm.
7. The composite separator according to claim 1 , wherein a thickness of the substrate is 5 μm-50 μm.
8. The composite separator according to claim 1 , wherein air permeability of the composite separator is between 130 s and 350 s.
9. The composite separator according to claim 1 , wherein after the composite separator is placed at 90° C. for 1 hour, both a transverse thermal shrinkage percentage and a longitudinal thermal shrinkage percentage are lower than 3%, preferably lower than 2%, more preferably lower than 1%.
10. An electrochemical device comprising a positive electrode, a negative electrode, a separator and electrolyte, wherein the separator is the composite separator according to claim 1 .
11. The composite separator according to claim 5 , wherein the porosity of the substrate is 40% -70%.
12. The composite separator according to claim 7 , wherein the thickness of the substrate is 7 μm-30 μm.
13. The composite separator according to claim 12 , wherein the thickness of the substrate is 7 μm-15 μm.
14. The composite separator according to claim 9 , wherein the longitudinal thermal shrinkage percentage is lower than 2%.
15. The composite separator according to claim 14 , wherein the longitudinal thermal shrinkage percentage is lower than 1%.