Organic light-emitting display panel and organic light-emitting display device having gradient doped electron transmission regions
Provided is an organic light-emitting display panel, including an array substrate and an organic light-emitting component. The array substrate includes a plurality of driving elements, and the organic light-emitting component is arranged to be associated with the driving element. The organic light-emitting component includes an anode and a cathode, and an organic functional layer therebetween. The organic functional layer includes an organic light-emitting layer, and an electron transmission region between the cathode and the organic light-emitting layer. The electron transmission region is doped with a first dopant comprising alkaline earth metal or rare earth metal elements. The electron transmission region includes first and second electron transmission layers. The doping concentrations C1, C2 of the first dopant in the first and second electron transmission layers satisfy: 0≤C2<C1. The electron transmission region can be at the same time matched with the cathode and the organic light-emitting layer.
1. An organic light-emitting display panel, comprising:
an array substrate comprising a plurality of driving elements; and
a plurality of organic light-emitting components arranged to be associated with the plurality of driving elements, wherein the organic light-emitting components each have an anode, a cathode and an organic functional layer arranged between the anode and the cathode, wherein the organic functional layer comprises an organic light-emitting layer and an electron transmission region arranged between the cathode and the organic light-emitting layer,
wherein the electron transmission region is doped with a first dopant, and the first dopant comprises alkaline earth metal elements or rare earth metal elements, and
wherein the electron transmission region comprises a first electron transmission layer and a second electron transmission layer, and a doping concentration C1 of the first dopant in the first electron transmission layer and a doping concentration C2 of the first dopant in the second electron transmission layer satisfy:
0<C2<C1,
wherein the first electron transmission layer is located between the second electron transmission layer and the cathode, and
wherein C2 is variable so that a doping concentration of the first dopant at a side of the second electron transmission layer close to the first electron transmission layer is higher than a doping concentration of the first dopant at a side of the second electron transmission layer away from the first electron transmission layer.
2. The organic light-emitting display panel according to claim 1 , wherein the second electron transmission layer is undoped with the first dopant, and thus C2=0.
3. The organic light-emitting display panel according to claim 1 , wherein C1 is variable so that a doping concentration of the first dopant at a side of the first electron transmission layer close to the cathode is higher than a doping concentration of the first dopant at a side of the first electron transmission layer away from the cathode.
4. The organic light-emitting display panel according to claim 1 , wherein a basis material of the second electron transmission layer is the same as a basis material of the first electron transmission layer.
5. The organic light-emitting display panel according to claim 1 , wherein the electron transmission region further comprises a third electron transmission layer adjacent to the organic light-emitting layer, and the third electron transmission layer is undoped with the first dopant.
6. The organic light-emitting display panel according to claim 5 , wherein a highest occupied molecular orbital HOMO1 of the third electron transmission layer and a highest occupied molecular orbital HOMO2 of a host material of the organic light-emitting layer satisfy:
|HOMO1−HOMO2|<1 eV.
7. The organic light-emitting display panel according to claim 5 , wherein a basis material of the second electron transmission layer is the same as a basis material of the third electron transmission layer.
8. The organic light-emitting display panel according to claim 1 , wherein the organic light-emitting component further comprises an electron injection layer arranged between the cathode and the electron transmission region, and the electron injection layer is made of an alkaline earth metal and/or a rare earth metal.
9. The organic light-emitting display panel according to claim 8 , wherein a thickness of the electron injection layer is d, and d≤5 nm.
10. The organic light-emitting display panel according to claim 1 , wherein the first dopant comprises at least one of Mg, Ga, Yb, Sm, Y, Tm, Gd or Lu.
11. The organic light-emitting display panel according to claim 1 , wherein the first dopant is an alkaline earth elementary metal or a rare earth elementary metal.
12. The organic light-emitting display panel according to claim 1 , wherein the first dopant is a metal oxide containing alkaline earth metal elements or rare earth metal elements, or the first dopant is a metal halide containing alkaline earth metal elements or rare earth metal elements, or the first dopant is metal complex containing alkaline earth metal elements or rare earth metal elements.
13. An organic light-emitting display device, comprising the organic light-emitting display panel according to claim 1 .
14. An organic light-emitting display panel, comprising:
an array substrate comprising a plurality of driving elements; and
a plurality of organic light-emitting components arranged to be associated with the plurality of driving elements, wherein the organic light-emitting components each have an anode, a cathode and an organic functional layer arranged between the anode and the cathode, wherein the organic functional layer comprises an organic light-emitting layer and an electron transmission region arranged between the cathode and the organic light-emitting layer,
wherein the electron transmission region is doped with a first dopant, and the first dopant comprises alkaline earth metal elements or rare earth metal elements, and
wherein the electron transmission region comprises a first electron transmission layer and a second electron transmission layer, and a doping concentration C1 of the first dopant in the first electron transmission layer and a doping concentration C2 of the first dopant in the second electron transmission layer satisfy:
0≤C2<C1,
wherein the first electron transmission layer is located between the second electron transmission layer and the cathode, and
wherein C1 is variable so that a doping concentration of the first dopant at a side of the first electron transmission layer close to the cathode is higher than a doping concentration of the first dopant at a side of the first electron transmission layer away from the cathode.
15. The organic light-emitting display panel according to claim 14 , wherein the electron transmission region further comprises a third electron transmission layer adjacent to the organic light-emitting layer, and the third electron transmission layer is undoped with the first dopant.
16. The organic light-emitting display panel according to claim 15 , wherein a highest occupied molecular orbital HOMO1 of the third electron transmission layer and a highest occupied molecular orbital HOMO2 of a host material of the organic light-emitting layer satisfy:
|HOMO1−HOMO2|<1 eV.
17. The organic light-emitting display panel according to claim 14 , wherein the organic light-emitting component further comprises an electron injection layer arranged between the cathode and the electron transmission region, and the electron injection layer is made of an alkaline earth metal and/or a rare earth metal.
18. The organic light-emitting display panel according to claim 17 , wherein a thickness of the electron injection layer is d, and d≤5 nm.
19. The organic light-emitting display panel according to claim 14 , wherein the first dopant comprises at least one of Mg, Ga, Yb, Sm, Y, Tm, Gd or Lu.
20. An organic light-emitting display device, comprising the organic light-emitting display panel according to claim 14 .