IP Library Granted Patent US 10,765,494
Granted Patent B2
US 10,765,494 · App. 16/222,231 · Granted Sep 8, 2020

Titanium nano-scale etching on an implant surface

Inventors: Robert L Mayfield (Jupiter, FL); Ross W Towse (San Marcos, CA)
Assignee: Biomet 3I, LLC
A61C8/0015A61C8/00A61C8/0012A61C8/0013A61C8/0022A61C8/0037A61C13/00A61L27/04B82Y30/00C23F1/00C23F1/26C23F1/30C23F1/38C23G1/106A61C2008/0046A61L2400/18
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Quick Facts
Patent No.
US 10,765,494
App. No.
16/222,231
Granted
Sep 8, 2020
Kind
B2
Abstract

A method of forming an implant to be implanted into living bone is disclosed. The method comprises the act of roughening at least a portion of the implant surface to produce a microscale roughened surface. The method further comprises the act of immersing the microscale roughened surface into a solution containing hydrogen peroxide and a basic solution to produce a nanoscale roughened surface consisting of nanopitting superimposed on the microscale roughened surface. The nanoscale roughened surface has a property that promotes osseointegration.

Claims (29)

1. A method of forming an implant to be implanted into living bone, the method comprising:

acid etching at least a portion of the implant surface to produce a microscale roughened surface; and

treating the microscale roughened surface to provide a nanoscale topography superimposed on the microscale roughened surface, wherein treating the microscale roughened surface to include the nanoscale topography includes immersing the implant in a solution including hydrogen peroxide and a basic solution.

2. The method of claim 1 , wherein the basic solution is a potassium hydroxide solution.

3. The method of claim 1 , wherein the basic solution is a sodium hydroxide solution.

4. The method of claim 1 , wherein the nanoscale roughened surface includes nanopitting.

5. The method of claim 1 , further including:

depositing discrete nanoparticles on the nanoscale roughened surface, the nanoscale roughened surface including nanopitting.

6. The method claim 1 , wherein, prior to acid etching, the method includes:

removing the native oxide layer from least the portion of the implant surface.

7. A method of forming an implant to be implanted into living bone, the method comprising:

roughening at least a portion of the implant surface to produce a dual microscale roughened surface including a first microscale surface having first peak-to-valley distances and a second microscale surface superimposed on the first microscale surface, the second microscale surface having second peak-to-valley distances that are less than the first peak-to-valley distances; and

treating the dual microscale roughened surface to provide a nanoscale topography superimposed on the dual microscale roughened surface.

8. The method of claim 7 , roughening at least the portion of the implant surface includes:

grit blasting the portion of the implant surface to form the first microscale surface.

9. The method of claim 8 , wherein the first peak-to-valley distances of the first microscale surface are about 10 microns to 30 microns.

10. The method of claim 8 , wherein roughening at least the portion of the implant surface includes:

acid etching the first microscale surface to form the second microscale surface superimposed on the first microscale surface.

11. The method of claim 10 , wherein the second peak-to-valley distances of the second microscale surface are less than 10 microns.

12. The method of claim 10 , wherein the second peak-to-valley distances of the second microscale surface are about 1 micron to about 3 microns.

13. The method of claim 10 , wherein the second microscale surface includes micropitting superimposed on the grit blasted surface.

14. The method of claim 7 , wherein treating the dual microscale roughened surface to include the nanoscale topography includes immersing the implant in a solution including hydrogen peroxide and a basic solution.

15. The method of claim 14 , wherein the basic solution is a potassium hydroxide solution.

16. The method of claim 14 , wherein the basic solution is a sodium hydroxide solution.

17. The method of claim 7 , wherein the nanoscale roughened surface includes nanopitting.

18. The method of claim 17 , further including:

depositing discrete nanoparticles on the nanoscale roughened surface.

19. The method claim 7 , wherein, prior to roughening at least the portion of the implant, the method includes:

removing the native oxide layer from at least the portion of the implant surface.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Oct 20, 2025
From: JPMORGAN CHASE BANK, N.A.
To: BIOMET 3I, LLC; ZIMMER DENTAL INC.
Reel/Frame 073142/0312 →
SECURITY INTEREST Recorded Oct 20, 2025
From: BIOMET 3I, LLC; ZIMMER DENTAL INC.; IMPLANT CONCIERGE, LLC
To: GOLUB CAPITAL LLC, AS COLLATERAL AGENT
Reel/Frame 073142/0384 →
SECURITY INTEREST Recorded Mar 2, 2022
From: BIOMET 3I, LLC; EBI, LLC; ZIMMER BIOMET SPINE, INC.; ZIMMER DENTAL INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 059293/0213 →