Polythiol composition for a plastic optical lens
Embodiments relate to a polythiol composition for a plastic optical lens and a polythiourethane-based plastic optical lens prepared therefrom. In the embodiments, a first polythiol compound having mercapto groups only as a hydrogen-bondable functional group and a second polythiol compound having mercapto groups as a hydrogen-bondable functional group and a hydrogen-bondable functional group other than a mercapto group are used in an appropriate amount. Thus, not only is it possible to control the viscosity of a polymerizable composition at the initial stage of polymerization at a low temperature of 5 to 15° C. and to stabilize the rate of increase in the viscosity of the composition and the reaction rate thereof, but also the change in the viscosity at a low temperature is low, thereby preventing the generation of striae, bubbles, and the like. Further, various plastic lenses such as eyeglass lenses, camera lenses, and the like having excellent appearance characteristics (without striae and bubbles) and excellent optical characteristics can be obtained from the composition.
1. A polythiol composition, which comprises a first polythiol compound having at least four mercapto groups only as a hydrogen-bondable functional group; and
a second polythiol compound having at least two mercapto groups as a hydrogen-bondable functional group and at least one hydrogen-bondable functional group other than a mercapto group
wherein the first polythiol compound is a compound represented by the following Formula 1, 2, or 3, and
the second polythiol compound is a compound represented by the following Formula 4 or 5:
2. The polythiol composition of claim 1 , which comprises the first polythiol compound in an amount of 55 to 99.5% by weight and the second polythiol compound in an amount of 0.5 to 45% by weight, based on the total weight of the polythiol composition.
3. The polythiol composition of claim 2 , which comprises the second polythiol compound in an amount of 0.5 to 12% by weight based on the total weight of the polythiol composition.
4. A polymerizable composition, which comprises a polythiol composition comprising a first polythiol compound and a second polythiol compound; and a polyisocyanate compound,
wherein the first polythiol compound has at least four mercapto groups only as a hydrogen-bondable functional group; and
the second polythiol compound has at least two mercapto groups as a hydrogen-bondable functional group and at least one hydrogen-bondable functional group other than a mercapto group
the first polythiol compound is a compound represented by the following Formula 1, 2, or 3, and
the second polythiol compound is a compound represented by the following Formula 4 or 5:
5. The polymerizable composition of claim 4 , which further comprise a polymerization catalyst,
wherein the change (D) in the viscosity of the polymerizable composition according to the following Equation 1 is 0.14 to 0.26:
Ln Y=ln A+DX [Equation 1]
In the above Equation, X is time (hr), Y is the viscosity (cps) of the polymerizable composition at 10° C. with respect to time, and A is the initial viscosity of the polymerizable composition at 10° C.
6. The polymerizable composition of claim 4 , wherein the polyisocyanate compound is selected from the group consisting of 1,3-bis(isocyanatomethyl)cyclohexane, hexamethylene diisocyanate, isophorone diisocyanate, m-xylene diisocyanate, toluene diisocyanate, and a mixture thereof.
7. An optical lens, which comprises a polythiourethane-based resin formed by curing a polymerizable composition, which comprises a polythiol composition comprising a first polythiol compound and a second polythiol compound; and a polyisocyanate compound,
wherein the first polythiol compound has at least four mercapto groups only as a hydrogen-bondable functional group;
the second polythiol compound has at least two mercapto groups as a hydrogen-bondable functional group and at least one hydrogen-bondable functional group other than a mercapto group,
the first polythiol compound is a compound represented by the following Formula 1, 2, or 3, and
the second polythiol compound is a compound represented by the following Formula 4 or 5: