IP Library Granted Patent US 11,614,409
Granted Patent B2
US 11,614,409 · App. 16/227,807 · Granted Mar 28, 2023

Printed sensor with vibrant colorimetric particles

Inventors: Gabriel Iftime (Dublin, CA); Mahati Chintapalli (Mountain View, CA); Eli Bulger (Nottawa, CA); Warren Jackson (San Francisco, CA); Sean Emerson Doris (San Francisco, CA); Jessica Louis Baker Rivest (Palo Alto, CA); Eric Cocker (Redwood City, CA); Antonio Williams (Concord, CA); Crystal Pham (Anaheim, CA)
Assignee: Palo Alto Research Center Incorporated
G01N21/78G01N33/525
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Quick Facts
Patent No.
US 11,614,409
App. No.
16/227,807
Granted
Mar 28, 2023
Kind
B2
Abstract

A colorimetric sensor has a first material deposited on a surface, and sensing particles on a surface of the first material, wherein the sensing particles comprise sensing species dispersed into porous host structures, such that at least a portion of the sensing particles is exposed to an ambient environment, wherein the first material attaches the sensing particles to surface. A method of forming a colorimetric sensor including depositing a first material onto a substrate, providing porous sensing particles, wherein the sensing particles comprise sensing species dispersed into a porous host structure, and embedding the porous sensing particles onto a surface of the deposited first material, wherein the first material attaches the sensing particles to the substrate such that at least a portion of the sensing particles is exposed to an ambient environment.

Claims (18)

1. A colorimetric sensor, comprising:

a first material comprising an ink deposited on a substrate; and

sensing particles on a surface of the first material, wherein the sensing particles comprise:

a second material comprising an aerogel containing porous host structures; and

a third material comprising a sensing species dispersed into the porous host structures, such that at least a portion of the sensing particles is exposed to an ambient environment, wherein the first material attaches the sensing particles to the substrate.

2. The colorimetric sensor of claim 1 , wherein the first material is transparent.

3. The colorimetric sensor of claim 1 , wherein the porous host structures have a specific surface area of at least 100 m 2 /g.

4. The colorimetric sensor of claim 1 , wherein the porous host structures are one of either a polymeric material, a metal oxide, or a ceramic material.

5. The colorimetric sensor of claim 1 , wherein the sensing particles are selected to have a color of the sensing particles change in the presence of an analyte, wherein the color change occurs in the wavelength range of 200-4000 nm.

6. The colorimetric sensor of claim 1 , wherein the sensing particles are selected to have a color of the sensing particles change in the presence of an analyte, wherein the color change occurs in the wavelength range of 200-800 nm.

7. The colorimetric sensor of claim 1 , wherein the porous host structures comprises a radical crosslinked polymer network.

8. The colorimetric sensor of claim 1 , wherein the sensing species comprise one of an organic molecule, a polymer, a salt, an inorganic complex, a nanoparticle, or a combination of therein.

9. The colorimetric sensor of claim 8 , wherein the sensing species has the characteristic of being chemically reactive with an analyte.

10. The colorimetric sensor of claim 1 , wherein the ink comprises an inkjet ink.

11. The colorimetric sensor of claim 1 , wherein the ink comprises a curable ink.

12. The colorimetric sensor of claim 1 , wherein the curable ink comprises one of a thermally curable ink or an ultraviolet curable ink.

13. The colorimetric sensor of claim 1 , wherein the ink is deposited by one of inkjet printing, screen printing, spray-coating, doctor blading, slot die coating, and lamination.

14. The colorimetric sensor of claim 1 , wherein the substrate comprises one of paper, plastic, wool, polymers, glass, metal, ceramic, fabric, adhesive tape, and cardboard.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 14, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073562/0677 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVAL OF US PATENTS 9356603, 10026651, 10626048 AND INCLUSION OF US PATENT 7167871 PREVIOUSLY RECORDED ON REEL 064038 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 28, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064161/0001 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2023
From: PALO ALTO RESEARCH CENTER INCORPORATED
To: XEROX CORPORATION
Reel/Frame 064038/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 20, 2018
From: IFTIME, GABRIEL; CHINTAPALLI, MAHATI; BULGER, ELI; JACKSON, WARREN; DORIS, SEAN EMERSON; RIVEST, JESSICA LOUIS BAKER; COCKER, ERIC; WILLIAMS, ANTONIO; PHAM, CRYSTAL
To: PALO ALTO RESEARCH CENTER INCORPORATED
Reel/Frame 047833/0636 →
Continuity (1)
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