IP Library Granted Patent US 11,118,070
Granted Patent B2
US 11,118,070 · App. 16/228,853 · Granted Sep 14, 2021

Low specular reflectance surface

Inventor: Kevin D. Lofftus (Fairport, NY)
Assignee: EASTMAN KODAK COMPANY
C09D5/006C09D7/61C09D7/65C09D7/69C09D7/70
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Quick Facts
Patent No.
US 11,118,070
App. No.
16/228,853
Granted
Sep 14, 2021
Kind
B2
Abstract

A low-specular-reflectance surface, includes a coating on a surface, wherein the coating includes a plurality of substantially spherical particles having a multimodal particle size distribution, wherein the particles protrude from a top surface of the coating to provide substantially spherical caps. The multimodal particle size distribution has two or more modes, each mode having a peak defining an associated mode particle size, wherein the distribution function includes a first mode having a first peak corresponding to a first particle size and a second mode having a second peak corresponding to a second particle size. A ratio of the second particle size to the first particle size is between 1.7-4.0. A smallest of the mode particle sizes is greater than or equal to 1.0 microns, and a largest of the mode particle sizes is greater than or equal to 3.0 microns.

Claims (39)

1. A low-specular-reflectance surface, comprising:

a coating on a surface, wherein the coating includes a plurality of substantially spherical particles having a multimodal particle size distribution, the particles protruding from a top surface of the coating to provide substantially spherical caps;

wherein the multimodal particle size distribution has a distribution function having two or more modes, each mode having a peak defining an associated mode particle size, wherein the distribution function includes a first mode having a first peak corresponding to a first particle size and a second mode having a second peak corresponding to a second particle size;

wherein a mode width parameter for each of the modes is less than or equal to 1.0, the mode width parameter for a particular mode being given by a ratio of a full-width half-maximum width of the particular mode to the particle size of the particular mode;

wherein a ratio of the second particle size to the first particle size is between 1.7 and 4.0;

wherein a smallest of the mode particle sizes is greater than or equal to 1.0 microns, and a largest of the mode particle sizes is greater than or equal to 3.0 microns;

wherein the coating includes a binder which adheres the particles to the surface; and

wherein a volume percent of the binder in the coating is less than a volume percent of the particles.

2. The low-specular-reflectance surface of claim 1 , wherein a total volume of the particles in the first mode is in the range of 20-70% of a total volume of all of the particles.

3. The low-specular-reflectance surface of claim 1 , wherein a total volume of the particles in the second mode is in the range of 20-70% of a total volume of all of the particles.

4. The low-specular-reflectance surface of claim 1 , wherein the distribution function further includes a third mode having a third peak corresponding to a third particle size, and wherein a ratio of the third particle size to the second particle size is between 1.7 and 4.0.

5. The low-specular-reflectance surface of claim 4 , wherein a total volume of the particles in the third mode is between 10-40% of a total volume of all of the particles.

6. The low-specular-reflectance surface of claim 4 , wherein the distribution function further includes a fourth mode having a fourth peak corresponding to a fourth particle size, and wherein a ratio of the fourth particle size to the third particle size is between 1.7 and 4.0.

7. The low-specular-reflectance surface of claim 1 , wherein the mode width parameter for each of the modes is less than or equal to 0.6.

8. The low-specular-reflectance surface of claim 1 , wherein a minimum value of the distribution function between adjacent modes is no more than 50% of the adjacent mode peaks.

9. The low-specular-reflectance surface of claim 1 , wherein the particles are adhered to the surface with a binder.

10. The low-specular-reflectance surface of claim 1 , wherein the first particle size is at least 2 microns.

11. The low-specular-reflectance surface of claim 1 , wherein at least some of the particles are substantially transparent.

12. The low-specular-reflectance surface of claim 1 , wherein at least some of the particles include a colorant.

13. The low-specular-reflectance surface of claim 1 , wherein at least some of the particles are inorganic particles.

14. The low-specular-reflectance surface of claim 1 , wherein at least some of the particles are polymeric particles.

15. The low-specular-reflectance surface of claim 1 , wherein at least some of the particles are porous.

16. The low-specular-reflectance surface of claim 1 , wherein G20, G60 and G85 gloss values of the low-specular-reflectance surface are each no more than 3.0.

17. The low-specular-reflectance surface of claim 1 , wherein an onset of grazing-incidence specular reflection occurs at an incidence angle of at least 85 degrees.

18. The low-specular-reflectance surface of claim 1 , wherein the particles are distributed over the surface in substantially a monolayer.

19. A low-specular-reflectance surface, comprising:

a surface including a plurality of protruding substantially spherical caps having a multimodal size distribution;

wherein the multimodal size distribution has a distribution function having two or more modes, each mode having a peak defining an associated mode cap size, wherein the distribution function includes a first mode having a first peak corresponding to a first cap size and a second mode having a second peak corresponding to a second cap size;

wherein a mode width parameter for each of the modes is less than or equal to 1.0, the mode width parameter for a particular mode being given by a ratio of a full-width half-maximum width of the particular mode to the cap size of the particular mode;

wherein a ratio of the second cap size to the first cap size is between 1.7 and 4.0;

wherein a smallest of the mode cap sizes is greater than or equal to 1.0 microns, and a largest of the mode cap sizes is greater than or equal to 3.0 microns; and

wherein the surface is the surface of a layer, and wherein the caps are molded features of the layer.

20. A low-specular-reflectance surface, comprising:

a surface including a plurality of protruding substantially spherical caps having a multimodal size distribution;

wherein the multimodal size distribution has a distribution function having two or more modes, each mode having a peak defining an associated mode cap size, wherein the distribution function includes a first mode having a first peak corresponding to a first cap size and a second mode having a second peak corresponding to a second cap size;

wherein a mode width parameter for each of the modes is less than or equal to 1.0, the mode width parameter for a particular mode being given by a ratio of a full-width half-maximum width of the particular mode to the cap size of the particular mode;

wherein a ratio of the second cap size to the first cap size is between 1.7 and 4.0;

wherein a smallest of the mode cap sizes is greater than or equal to 1.0 microns, and a largest of the mode cap sizes is greater than or equal to 3.0 microns; and

wherein the surface is the surface of an object, and wherein the caps are molded features of the object.

Assignments (7)
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056733/0681 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0001 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: ALTER DOMUS (US) LLC
Reel/Frame 056734/0233 →
NOTICE OF SECURITY INTERESTS Recorded Mar 4, 2021
From: EASTMAN KODAK COMPANY
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 056984/0001 →
SECURITY INTEREST Recorded Apr 26, 2019
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD.; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; LASER-PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.
To: BANK OF AMERICA, AS AGENT
Reel/Frame 049004/0013 →
SECURITY INTEREST Recorded Apr 26, 2019
From: EASTMAN KODAK COMPANY; FAR EAST DEVELOPMENT LTD; FPC INC.; KODAK (NEAR EAST), INC.; KODAK AMERICAS, LTD.; LASER-PACIFIC MEDIA CORPORATION; QUALEX INC.; KODAK PHILIPPINES, LTD.; NPEC INC.
To: JP MORGAN CHASE BANK, N.A.
Reel/Frame 049004/0499 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 21, 2018
From: LOFFTUS, KEVIN D.
To: EASTMAN KODAK COMPANY
Reel/Frame 047838/0741 →
Continuity (1)
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