Methods for producing graphene from coal
A method of preparing graphene from coal can include thermally processing raw coal and, after the coal has been at least partially cooled from thermal processing, forming reduced graphene oxide from the coal.
1. A method of producing reduced graphene oxide, comprising:
thermally processing an amount of coal to achieve a predetermined concentration of an one or more impurity atoms in the amount of coal;
oxidizing at least some of the amount of coal to form a coal oxide including a predetermined concentration of the one or more impurity atoms;
processing the coal oxide to form reduced graphene oxide including a predetermined concentration between about 0.1 atomic % and about 10 atomic % of the one or more impurity atoms.
2. The method of claim 1 , wherein the one or more impurity atoms occur naturally in the amount of coal.
3. The method of claim 1 , wherein the one or more impurity atoms comprise one or more of cadmium, selenium, boron, nitrogen, or silicon.
4. The method of claim 1 , wherein the impurity atoms comprise one or more of boron, nitrogen, or silicon.
5. The method of claim 1 , wherein thermally processing the amount of coal comprises heating the amount of coal to a temperature of at least about 300° F.
6. The method of claim 1 , wherein thermally processing the amount of coal comprises:
heating the amount of coal to a first temperature of less than 350° F.;
transferring the coal to a mercury removal reactor; and
heating the amount of coal in the mercury removal reactor to a second temperature of at least 500° F.; and
contacting the amount of coal with an inert gas to remove at least a portion of mercury present in the coal.
7. The method of claim 1 , wherein processing the coal oxide to form reduced graphene oxide comprises:
centrifuging the coal oxide;
collecting a precipitate from the coal oxide after centrifuging, the precipitate comprising graphene oxide; and
reducing the graphene oxide to form reduced graphene oxide.
8. The method of claim 7 , further comprising diluting the coal oxide with water before centrifuging the coal oxide.
9. The method of claim 7 , wherein reducing the graphene oxide to form reduced graphene oxide comprises:
sonicating the graphene oxide; and
hydrothermally treating the graphene oxide in a par reactor after sonicating the graphene oxide.
10. The method of claim 1 , wherein processing the coal oxide to form reduced graphene oxide comprises forming the reduced graphene oxide from the coal oxide at a reduced graphene oxide yield rate of between about 10 weight percent and about 20 weight percent of the amount of coal.
11. The method of claim 1 , wherein oxidizing at least some of the amount of coal comprises mixing at least some of the amount of coal with at least one of sulfuric acid, nitric acid, potassium permanganate, or hydrogen peroxide.
12. The method of claim 11 , wherein mixing at least some of the amount of coal with at least one of sulfuric acid, nitric acid, potassium permanganate, or hydrogen peroxide comprises:
mixing the coal with at least one of sulfuric acid or nitric acid;
stirring the coal mixed with at least one of sulfuric acid or nitric acid;
mixing potassium permanganate with the coal mixed with at least one of sulfuric acid or nitric acid;
stirring the coal mixed with the potassium permanganate and at least one of sulfuric acid or nitric acid;
diluting, with water, the coal mixed with potassium permanganate and at least one of sulfuric acid or nitric acid to form a solution;
mixing the solution with hydrogen peroxide;
performing a first centrifuging of the solution mixed with hydrogen peroxide; and
separating a supernatant of the solution mixed with hydrogen peroxide from a precipitate of the solution mixed with the hydrogen peroxide, the supernatant comprising the coal oxide.