Aqueous leaching solutions and methods of leaching at least one interstitial constituent from a polycrystalline diamond body using the same
In an embodiment, a polycrystalline diamond table includes a plurality of bonded diamond grains and a plurality of interstitial regions defined by the plurality of bonded diamond grains. The polycrystalline diamond table may be at least partially leached such that at least a portion of at least one interstitial constituent has been removed from at least a portion of the plurality of interstitial regions by exposure to a leaching agent. The leaching agent may include a mixture having a ratio of weight % hydrofluoric acid to weight % nitric acid of about 1.0 to about 2.4, and water in a concentration of about 50 weight % to about 85 weight %. Various other materials, articles, and methods are also disclosed.
1. A polycrystalline diamond table comprising;
a plurality of bonded diamond grains; and
a plurality of interstitial regions defined by the plurality of bonded diamond grains,
wherein the polycrystalline diamond table includes a leaching agent in at least a portion of the plurality of interstitial regions, the leaching agent including a mixture comprising:
a ratio of weight % hydrofluoric acid to weight % nitric acid of about 1.0 to about 2.4, and
water in a concentration of about 50 weight % to about 85 weight %.
2. The polycrystalline diamond table of claim 1 , wherein substantially all of the at least one interstitial constituent has been removed from the entire polycrystalline diamond table by the exposure to the leaching agent.
3. The polycrystalline diamond table of claim 1 , wherein the mixture comprises the hydrofluoric acid in a concentration of about 25 weight % to about 30 weight %, the nitric acid in a concentration of about 10 weight % to about 15 weight %, and the water in a concentration of about 55 weight % to about 65 weight %.
4. The polycrystalline diamond table of claim 1 , wherein the mixture comprises the hydrofluoric acid in a concentration of greater than about 15 weight % and the nitric acid in a concentration of less than about 20 weight %.
5. The polycrystalline diamond table of claim 4 , wherein the mixture exhibits a viscosity of less than about 0.5 centipoise.
6. The polycrystalline diamond table of claim 1 , wherein the mixture comprises the hydrofluoric acid in a concentration of about 15 weight % to about 25 weight % and the nitric acid in a concentration of about 10 weight % to about 20 weight %.
7. The polycrystalline diamond table of claim 6 , wherein the mixture exhibits a viscosity of less than about 0.4 centipoise.
8. A polycrystalline diamond compact comprising:
a polycrystalline diamond table comprising a plurality of bonded diamond grains defining a plurality of interstitial regions; and
a substrate bonded to the polycrystalline diamond table at an interfacial surface,
wherein the polycrystalline diamond table includes a leaching agent in at least a portion of the plurality of interstitial regions, the leaching agent including a mixture comprising:
a ratio of weight % hydrofluoric acid to weight % nitric acid of about 1.0 to about 2.4, and
water in a concentration of about 50 weight % to about 85 weight %.
9. The polycrystalline diamond compact of claim 8 , wherein the mixture comprises the hydrofluoric acid in a concentration of about 25 weight % to about 30 weight %, the nitric acid in a concentration of about 10 weight % to about 15 weight %, and the water in a concentration of about 55 weight % to about 65 weight %.
10. The polycrystalline diamond compact of claim 8 , wherein the mixture comprises the hydrofluoric acid in a concentration of greater than about 15 weight % and the nitric acid in a concentration of less than about 20 weight %.
11. The polycrystalline diamond compact of claim 10 , wherein the mixture exhibits a viscosity of less than about 0.5 centipoise.
12. The polycrystalline diamond compact of claim 8 , wherein the mixture comprises the hydrofluoric acid in a concentration of about 15 weight % to about 25 weight % and the nitric acid in a concentration of about 10 weight % to about 20 weight %.
13. The polycrystalline diamond compact of claim 12 , wherein the mixture exhibits a viscosity of less than about 0.4 centipoise.
14. The polycrystalline diamond compact of claim 8 , wherein the mixture includes one or more additional constituents composed to reduce a viscosity of the mixture.
15. The polycrystalline diamond compact of claim 8 , wherein at least the portion of the at least one interstitial constituent was removed from at least the portion of the plurality of interstitial regions by exposure to the leaching agent at a temperature greater than about 75° C.
16. The polycrystalline diamond compact of claim 8 , wherein the substrate is bonded to the polycrystalline diamond table such that an at least partially leached portion of the polycrystalline diamond table is at least partially infiltrated with at least one infiltrant from the substrate.
17. A polycrystalline diamond compact comprising;
a polycrystalline diamond table comprising a plurality of bonded diamond grains defining a plurality of interstitial regions; and
a substrate bonded to the polycrystalline diamond table at an interfacial surface,
wherein the polycrystalline diamond table includes a leaching agent in at least a portion of the plurality of interstitial regions, the leaching agent including a mixture comprising a ratio of weight % hydrofluoric acid to weight % nitric acid of about 1.0 to about 2.4, the mixture exhibiting a viscosity of less than about 0.55 centipoise.
18. The polycrystalline diamond compact of claim 17 , wherein the mixture comprises the hydrofluoric acid in a concentration of greater than about 15 weight % and the nitric acid in a concentration of less than about 20 weight %.
19. The polycrystalline diamond compact of claim 17 , wherein the mixture comprises the hydrofluoric acid in a concentration of about 15 weight % to about 25 weight % and the nitric acid in a concentration of about 10 weight % to about 20 weight %.
20. The polycrystalline diamond compact of claim 19 , wherein the mixture exhibits a viscosity of less than about 0.4 centipoise.