Polymerizable composition and optically anisotropic body using same
The present invention provides a polymerizable composition containing a specific polymerizable compound and a fluorosurfactant having a specific polyoxyalkylene skeleton and having specific molecular weight. The invention also provides an optically anisotropic body, a retardation film, an antireflective film, and a liquid crystal display device that are produced using the polymerizable composition of the present invention. The present invention is useful because, when an optically anisotropic body is produced by photo-polymerization of the polymerizable composition, three features including the leveling properties of the surface of the optically anisotropic body, offset onto the substrate, and liquid crystal alignment can be improved simultaneously.
1. A method for producing a polymer product;
providing a polymerizable composition; and
polymerizing the polymerizable composition, wherein the polymerizable composition comprising:
a) a polymerizable compound having one polymerizable group or two or more polymerizable groups and satisfying formula (I)
Re(450 nm)/Re(550 nm)<1.0 (I)
(wherein Re(450 nm) is an in-plane retardation at a wavelength of 450 nm when the polymerizable compound having one polymerizable group is aligned on a substrate such that the direction of long axes of molecules of the polymerizable compound is horizontal to the substrate, and Re(550 nm) is an in-plane retardation at a wavelength of 550 nm when the polymerizable compound having one polymerizable group is aligned on the substrate such that the direction of the long axes of the molecules of the polymerizable compound is horizontal to the substrate); and
b) at least one fluorosurfactant selected from the group consisting of copolymers (III) having a weight average molecular weight of 2,500 to 30,000 and each obtained by copolymerizing essential monomers including a polymerizable monomer containing a fluorine atom and a polymerizable monomer represented by general formula (B), having a solubility parameter (SP value) of 8.9 to 10.5 (cal/cm 3 ) 0.5 , and satisfying the following formula (1A):
1.00<100×( s+t+u )/ MB< 2.10 (1A)
(wherein s is an integer of 1 or more; t and u are each an integer of 0 or 1 or more; and MB is the molecular weight of the polymerizable monomer represented by general formula (B)):
(wherein R is a hydrogen atom or a methyl group; X, Y, and Z are each independently an alkylene group; s is an integer of 1 or more; t and u are each an integer of 0 or 1 or more; and W is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or an aryl group).
2. The method according to claim 1 , wherein the polymer product is an optically anisotropic body.
3. The method according to claim 1 , wherein the polymer product is a retardation film.
4. The method according to claim 1 , further comprising using the polymer product as an optically anisotropic body to obtain a display device.
5. The method according to claim 1 , further comprising using the polymer product as an optically anisotropic body to obtain a light-emitting device.
6. The method according to claim 1 , further comprising using the polymer product to obtain a light-emitting diode lighting device.
7. The method according to claim 1 , further comprising using the polymer product to obtain a lens sheet.
8. The method according to claim 1 , wherein the polymerizable composition further comprises a dichroic pigment.
9. The method according to claim 1 , further comprising using the polymer product to obtain a polarizing film.
10. The method according to claim 1 , further comprising using the polymer product as a retardation film to obtain a display device.
11. The method according to claim 1 , further comprising using the polymer product as a retardation film to obtain a a light-emitting device.