Lithium secondary battery
A lithium secondary battery comprises a cathode active material including a first cathode active material particle having a concentration gradient region and a second cathode active material particle having a single particle structure, to obtain improved electrical performance and mechanical stability.
1. A lithium secondary battery, comprising:
a cathode formed from a cathode active material including a first cathode active material particle and a second cathode active material particle;
an anode; and
a separator interposed between the cathode and the anode,
wherein the first cathode active material particle includes a lithium metal oxide including a concentration gradient region between a central portion and a surface,
wherein the second cathode active material particle includes a lithium metal oxide having a single particle structure, and is represented by Chemical Formula 1, and a blending weight ratio of the first cathode active material particle and the second cathode active material particle is in a range from 8:2 to 1:9:
Li x M1′ a M2′ b M3′ c O y [Chemical Formula 1]
wherein, in Chemical Formula 1, M1′, M2′ and M3′ are selected from Ni, Co, Mn, Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga, W or B, M1′ includes Ni, M2′ includes Co, M3′ includes Mn, and 0<x≤1.1, 2≤y≤2.02, 0.7≤a≤0.9, 0.1≤b+c≤0.3 and a+b+c=1.
2. The lithium secondary battery according to claim 1 , wherein the single particle structure includes a single crystalline structure.
3. The lithium secondary battery according to claim 1 , wherein the first cathode active material particle includes a first metal having a concentration decreasing region between the central portion and the surface, and a second metal having a concentration increasing region between the central portion and the surface.
4. The lithium secondary battery according to claim 3 , wherein the first cathode active material particle further includes a third metal having a constant concentration from the central portion to the surface.
5. The lithium secondary battery according to claim 4 , wherein the first cathode active material particle is represented by Chemical Formula 2:
Li x M1 a M2 b M3 c O y [Chemical Formula 2]
wherein, in Chemical Formula 2, M1, M2 and M3 each represents the first metal, the second metal and the third metal, and are selected from Ni, Co, Mn, Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga or B, and
0<x≤1.1, 2≤y≤2.02, 0<a<1, 0<b<1, 0<c<1, and 0<a+b+c≤1.
6. The lithium secondary battery according to claim 5 , wherein 0.6≤a≤0.95 and 0.05≤b+c≤0.4 in Chemical Formula 2.
7. The lithium secondary battery according to claim 5 , wherein 0.7≤a≤0.9 and 0.1≤b+c≤0.3 in Chemical Formula 2.
8. The lithium secondary battery according to claim 5 , wherein the first metal is nickel (Ni), the second metal is manganese (Mn) and the third metal is cobalt (Co).
9. The lithium secondary battery according to claim 1 , wherein a blending weight ratio of the first cathode active material particle and the second cathode active material particle is in a range from 8:2 to 6:4.
10. The lithium secondary battery according to claim 1 , an average diameter (D 50 ) of the first cathode active material particle is in a range from 6 μm to 20 μm.
11. The lithium secondary battery according to claim 1 , an average diameter (D 50 ) of the second cathode active material particle is in a range from 2 μm to 6 μm.