Compound and organic electroluminescent device comprising same

1. A compound of the following Formula 5, 6, 7, or 9:

wherein,

Y 1 to Y 4 are each independently N or CR 3 , and, when CR 3 is present in a plural number, they are the same as or different from each other, Y 5 to Y 8 are each independently N or CR 4 , and, when CR 4 is present in a plural number, they are the same as or different from each other, and

provided that at least one of Y 5 to Y 8 is CR 4 , and the at least one R 4 is a substituent of the following Formula 3;

in Formula 3,

L is a single bond, or selected from the group consisting of a substituted or unsubstituted C 6 to C 60 arylene group, and a substituted or unsubstituted heteroarylene group having 5 to 60 nuclear atoms, and

wherein one or more substituents each introduced into the arylene group and the heteroarylene group of L are each independently selected from the group consisting of deuterium, halogen, cyano, a C 1 to C 40 alkyl group, a C 3 to C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other;

R a and R b are each independently selected from the group consisting of a substituted or unsubstituted C 1 to C 40 alkyl group, a substituted or unsubstituted C 3 to C 40 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group having 3 to 40 nuclear atoms, a substituted or unsubstituted C 6 to C 60 aryl group, and a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms, and

wherein one or more substituents each introduced into the alkyl group, the cycloalkyl group, the heterocycloalkyl group, the aryl group, and the heteroaryl group of R a and R b are each independently selected from the group consisting of deuterium, halogen, cyano, a C 1 to C 40 alkyl group, a C 3 to C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, a C 1 to C 40 alkylsilyl group, a C 6 to C 60 arylsilyl group, a C 1 to C 40 alkyl boron group, a C 6 to C 60 aryl boron group, a C 6 to C 60 arylphosphine group, a C 6 to C 60 arylphosphine oxide group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other;

provided that L, R a , and R b , taken with an adjacent substituent, optionally form a fused ring;

X 1 and X 2 are each N(Ar 1 ), and are the same as or different from each other;

Ar 1 is selected from the group consisting of a substituted or unsubstituted C 1 to C 40 alkyl group, a substituted or unsubstituted C 3 to C 40 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group having 3 to 40 nuclear atoms, a substituted or unsubstituted C 6 to C 60 aryl group, a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms, a substituted or unsubstituted C 1 to C 40 alkyloxy group, a substituted or unsubstituted C 6 to C 60 aryloxy group, a substituted or unsubstituted C 1 to C 40 alkylsilyl group, a substituted or unsubstituted C 6 to C 60 arylsilyl group, a substituted or unsubstituted C 1 to C 40 alkyl boron group, a substituted or unsubstituted C 6 to C 60 aryl boron group, a substituted or unsubstituted C 6 to C 60 arylphosphine group, a substituted or unsubstituted C 6 to C 60 arylphosphine oxide group, or a substituted or unsubstituted C 6 to C 60 arylamine group;

R 1 to R 4 are each independently selected from the group consisting of hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted C 1 to C 40 alkyl group, a substituted or unsubstituted C 3 to C 40 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group having 3 to 40 nuclear atoms, a substituted or unsubstituted C 6 to C 60 aryl group, a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms, a substituted or unsubstituted C 1 to C 40 alkyloxy group, a substituted or unsubstituted C 6 to C 60 aryloxy group, a substituted or unsubstituted C 1 to C 40 alkylsilyl group, a substituted or unsubstituted C 6 to C 60 arylsilyl group, a substituted or unsubstituted C 1 to C 40 alkyl boron group, a substituted or unsubstituted C 6 to C 60 aryl boron group, a substituted or unsubstituted C 6 to C 60 arylphosphine group, a substituted or unsubstituted C 6 to C 60 arylphosphine oxide group, and a substituted or unsubstituted C 6 to C 60 arylamine group; and

wherein one or more substituents each introduced into the alkyl group, the cycloalkyl group, the heterocycloalkyl group, the aryl group, the heteroaryl group, the alkyloxy group, the aryloxy group, and the arylamine group of R 1 to R 4 and Ar 1 are each independently selected from the group consisting of deuterium, halogen, cyano, a C 1 to C 40 alkyl group, a C 3 to C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, a substituted or unsubstituted C 1 to C 40 alkylsilyl group, a C 6 to C 60 arylsilyl group, a C 1 to C 40 alkyl boron group, a C 6 to C 60 aryl boron group, a C 6 to C 60 arylphosphine group, a C 6 to C 60 arylphosphine oxide group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other.

2. The compound of claim 1 , wherein the compound is selected from the group consisting of compounds represented by the following Formulae 11 to 13, and 15:

wherein,

R 1 , R 2 , Ar 1 , R a , R b , and L are each the same as those defined in claim 1 , and

when Ar 1 is present in a plural number, they are the same as or different from each other.

3. The compound of claim 1 , wherein Ar 1 is selected from the group consisting of a substituted or unsubstituted C 6 to C 60 aryl group, and a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms,

wherein one or more substituents, which are optionally each introduced into the aryl group and the heteroaryl group of Ar 1 , are each independently selected from the group consisting of deuterium, halogen, a nitrile group, a nitro group, a cyano group, a C 1 to C 40 alkyl group, a C 2 to C 40 alkenyl group, a C 1 to C 40 alkoxy group, a C 1 to C 40 amino group, a cycloalkyl group having 3 to 40 nuclear atoms, a C 3 to C 40 heterocycloalkyl group, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, a C 1 to C 40 alkylsilyl group, a C 6 to C 60 arylsilyl group, a C 1 to C 40 alkyl boron group, a C 6 to C 60 aryl boron group, a C 6 to C 60 arylphosphine group, a C 6 to C 60 arylphosphine oxide group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other.

4. An organic electroluminescence device comprising: an anode; a cathode; and an organic material layer comprising one or more layers interposed between the anode and the cathode,

wherein at least one of the one or more layers of the organic material layer comprises the compound of claim 1 .

5. The organic electroluminescent device of claim 4 , wherein the organic material layer comprising one or more layers, which comprises the compound, is selected from the group consisting of a hole injection layer, a hole transporting layer, and a light-emitting layer.

6. The organic electroluminescent device of claim 4 , wherein the organic material layer comprising the compound is a hole transporting layer.

7. The organic electroluminescent device of claim 4 , wherein the compound is selected from the group consisting of compounds of the following Formulae 11 to 13 and 15:

wherein,

L is a single bond, or selected from the group consisting of a substituted or unsubstituted C 6 to C 60 arylene group, and a substituted or unsubstituted heteroarylene group having 5 to 60 nuclear atoms, wherein one or more substituents each introduced into the arylene group and the heteroarylene group of L are each independently selected from the group consisting of deuterium, halogen, cyano, a C 1 to C 40 alkyl group, a C 3 to C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other;

R a and R b are each independently selected from the group consisting of a substituted or unsubstituted C 1 to C 40 alkyl group, a substituted or unsubstituted C 3 to C 40 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group having 3 to 40 nuclear atoms, a substituted or unsubstituted C 6 to C 60 aryl group, and a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms, and

in this case, one or more substituents each introduced into the alkyl group, the cycloalkyl group, the heterocycloalkyl group, the aryl group, and the heteroaryl group of R a and R b are each independently selected from the group consisting of deuterium, halogen, cyano, a C 1 to C 40 alkyl group, a C 3 to C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, a C 1 to C 40 alkylsilyl group, a C 6 to C 60 arylsilyl group, a C 1 to C 40 alkyl boron group, a C 6 to C 60 aryl boron group, a C 6 to C 60 arylphosphine group, a C 6 to C 60 arylphosphine oxide group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other;

provided that L, R a , and R b , taken together with an adjacent substituent, optionally form a fused ring;

Ar 1 is selected from the group consisting of a substituted or unsubstituted C 1 to C 40 alkyl group, a substituted or unsubstituted C 3 to C 40 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group having 3 to 40 nuclear atoms, a substituted or unsubstituted C 6 to C 60 aryl group, a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms, a substituted or unsubstituted C 1 to C 40 alkyloxy group, a substituted or unsubstituted C 6 to C 60 aryloxy group, a substituted or unsubstituted C 1 to C 40 alkylsilyl group, a substituted or unsubstituted C 6 to C 60 arylsilyl group, a substituted or unsubstituted C 1 to C 40 alkyl boron group, a substituted or unsubstituted C 6 to C 60 aryl boron group, a substituted or unsubstituted C 6 to C 60 arylphosphine group, a substituted or unsubstituted C 6 to C 60 arylphosphine oxide group, or a substituted or unsubstituted C 6 to C 60 arylamine group;

R 1 and R 2 are each independently selected from the group consisting of hydrogen, deuterium, halogen, cyano, a substituted or unsubstituted C 1 to C 40 alkyl group, a substituted or unsubstituted C 3 to C 40 cycloalkyl group, a substituted or unsubstituted heterocycloalkyl group having 3 to 40 nuclear atoms, a substituted or unsubstituted C 6 to C 60 aryl group, a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms, a substituted or unsubstituted C 1 to C 40 alkyloxy group, a substituted or unsubstituted C 6 to C 60 aryloxy group, a substituted or unsubstituted C 1 to C 40 alkylsilyl group, a substituted or unsubstituted C 6 to C 60 arylsilyl group, a substituted or unsubstituted C 1 to C 40 alkyl boron group, a substituted or unsubstituted C 6 to C 60 aryl boron group, a substituted or unsubstituted C 6 to C 60 arylphosphine group, a substituted or unsubstituted C 6 to C 60 arylphosphine oxide group, and a substituted or unsubstituted C 6 to C 60 arylamine group; and

one or more substituents each introduced into the alkyl group, the cycloalkyl group, the heterocycloalkyl group, the aryl group, the heteroaryl group, the alkyloxy group, the aryloxy group, and the arylamine group of R 1 to R 4 and Arl are each independently selected from the group consisting of deuterium, halogen, cyano, a C 1 to C 40 alkyl group, a C 3 to C 40 cycloalkyl group, a heterocycloalkyl group having 3 to 40 nuclear atoms, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, a substituted or unsubstituted C 1 to C 40 alkylsilyl group, a C 6 to C 60 arylsilyl group, a C 1 to C 40 alkyl boron group, a C 6 to C 60 aryl boron group, a C 6 to C 60 arylphosphine group, a C 6 to C 60 arylphosphine oxide group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other,

in this case, when Ar 1 is present in a plural number, they are the same as or different from each other.

8. The organic electroluminescent device of claim 4 , wherein Ar 1 is selected from the group consisting of a substituted or unsubstituted C 6 to C 60 aryl group, and a substituted or unsubstituted heteroaryl group having 5 to 60 nuclear atoms,

wherein one or more substituents, which are optionally each introduced into the aryl group and the heteroaryl group of Ar 1 , are each independently selected from the group consisting of deuterium, halogen, a nitrile group, a nitro group, a cyano group, a C 1 to C 40 alkyl group, a C 2 to C 40 alkenyl group, a C 1 to C 40 alkoxy group, a C 1 to C 40 amino group, a cycloalkyl group having 3 to 40 nuclear atoms, a C 3 to C 40 heterocycloalkyl group, a C 6 to C 60 aryl group, a heteroaryl group having 5 to 60 nuclear atoms, a C 1 to C 40 alkyloxy group, a C 6 to C 60 aryloxy group, a C 1 to C 40 alkylsilyl group, a C 6 to C 60 arylsilyl group, a C 1 to C 40 alkyl boron group, a C 6 to C 60 aryl boron group, a C 6 to C 60 arylphosphine group, a C 6 to C 60 arylphosphine oxide group, and a C 6 to C 60 arylamine group, and provided that when the substituent is present in a plural number, they are the same as or different from each other.