Iridium complex and organic electroluminescence device using the same
The present invention discloses an iridium complex represented by the following formula (1) and an organic electroluminescence device using the iridium complex as a phosphorescent dopant material. The phosphorescent dopant material may be for lowering a driving voltage or power consumption or increasing a current efficiency of half-life of the organic electroluminescence device. The same definition as described in the present invention.
1. An iridium complex represented by the following formula (1) having a naphthalene ring:
wherein B-C represents a bidentate ligand; Ar represent a substituted or unsubstituted fused ring hydrocarbon unit fused onto the naphthalene ring, A ring represents an imidazole, a pyridine, a quinolone and an isoquinoline; X is O or S; m represents an integer of 1 to 3; n represents an integer of 0 to 4; and R 1 is independently a hydrogen atom, a halogen, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms.
2. The iridium complex according to claim 1 , wherein the bidentate ligand has one of the following formulas:
wherein Y is selected from the group consisting of O, S, Se, CR 22 R 23 , NR 24 or SiR 25 R 26 ; q, s, and t independently represent an integer of 1 to 4; and R 2 to R 26 are independently a hydrogen atom, a halogen, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted cycloalkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 3 to 30 carbon atoms.
3. The iridium complex according to claim 2 , wherein R 2 to R 21 are independently a hydrogen atom, a methyl group, an isopropyl group, an isobutyl group, a cyclopentyl group, a hexyl group, a cyclohexyl group, or a phenyl group.
4. The iridium complex according to claim 1 , wherein the fused ring hydrocarbons unit is a naphthyl group, an anthracenyl group, a phenanthrenyl group, a triphenylenyl group, a pyrenyl group, a tetracenyl group or one of the following substituents:
5. The iridium complex according to claim 1 , wherein the iridium complex is one of the following compounds:
6. An organic electroluminescence device, comprising a pair of electrodes composed of a cathode and an anode, and a light emitting layer between the pair of electrodes, wherein the light emitting layer comprises the iridium complex of claim 1 .
7. The organic electroluminescence device of claim 6 , wherein the iridium complex of formula (1) is used as a phosphorescent dopant material.
8. The organic electroluminescence device of claim 6 , wherein the light emitting layer emits red, yellow or green phosphorescence.
9. The organic electroluminescence device of claim 6 , wherein the organic electroluminescence device is a lighting panel.
10. The organic electroluminescence device of claim 6 , wherein the organic electroluminescence device is a backlight panel.