IP Library Granted Patent US 10,947,447
Granted Patent B2
US 10,947,447 · App. 16/253,934 · Granted Mar 16, 2021

Hydraulic fracture composition and method

Inventors: Calder Hendrickson (Lubbock, TX); Tommy K. Thrash (Lubbock, TX); Todd Naff (Lubbock, TX)
Assignee: AQUASMART ENTERPRISES, LLC
C09K8/805
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Quick Facts
Patent No.
US 10,947,447
App. No.
16/253,934
Granted
Mar 16, 2021
Kind
B2
Abstract

A method for improving the performance of fracturing processes in oil production fields may rely on polymer coated particles carried in the fracturing fluid. The particles may include heavy substrates, such as sand, ceramic sand, or the like coated with polymers selected to absorb water, increasing the area and volume to travel more readily with the flow of fluid without settling out, or allowing the substrate to settle out. Ultimately, the substrate may become lodged in the fissures formed by the pressure or hydraulic fracturing, resulting in propping open of the fissures for improved productivity.

Claims (41)

1. A method for producing a self-suspending proppant particle, the method comprising:

providing a substrate, constituted as discrete particles;

providing a water soluble material as a binder;

providing a first composition containing a polymer, characterized by a chemistry and formed as a first powder;

coating the substrate individually with the binder;

forming granules by coating the binder on the substrate individually with the first powder;

providing a second composition containing a flowing agent to increase flowability of the resultant granules, characterized by a chemistry and formed as a second powder; and

forming granules by coating the first powder on the substrate individually with the second powder, wherein the self-suspending proppant particles are configured to remain suspended in a 1000 ppm CaCO 3 aqueous solution for at least 30 minutes at a temperature of 170° F.

2. The method of claim 1 , wherein the second composition is selected from the group consisting of sodium aluminosilicate, fumed silica, and whey protein[, and DFC].

3. The method of claim 1 , wherein the second composition is whey protein.

4. The method of claim 1 , wherein the first composition comprises a plurality of polymers, distinct from one another.

5. The method of claim 3 , where in the first composition comprises a plurality of polymers, distinct from one another.

6. The method of claim 1 , wherein the second composition comprises a plurality of flowing agents, distinct from one another.

7. The method of claim 1 , wherein the second composition consists of whey protein and fumed silica.

8. The method of claim 1 , wherein the second composition consists of whey protein and sodium aluminosilicate.

9. The method of claim 1 , wherein the substrate has a first density and the first powder has a second density, the first density being greater than the second density.

10. The method of claim 9 , wherein the first and second densities are selected, and the size of the granules is selected to effect sinking the polymer, by the substrate, into a fluid.

11. The method of claim 10 , wherein the fluid is moving as a carrier, characterized by a viscosity, and the polymer is selected based on its effectiveness to increase in size by absorbing the fluid.

12. A method for producing a self-suspending proppant particle, the method comprising:

providing a substrate, constituted as discrete particles;

providing a water soluble material as a binder;

providing a first composition containing a polymer, characterized by a chemistry and formed as a first powder, wherein the substrate has a first density and the first powder has a second density, the first density being greater than the second density;

coating the substrate individually with the binder;

forming granules by coating the binder on the substrate individually with the first powder;

providing a second composition containing a flowing agent to increase flowability of the resultant granules, characterized by a chemistry and formed as a second powder, wherein the second composition is selected from the group consisting of whey protein, fumed silica, and sodium aluminosilicate[, and DFC]; and

forming granules by coating the first powder on the substrate individually with the second powder, wherein the self-suspending proppant particles are configured to remain suspended in a 1000 ppm CaCO 3 aqueous solution for at least 30 minutes at a temperature of 170° F.

13. The method of claim 12 , wherein the second composition consists of whey protein and fumed silica.

14. The method of claim 12 , wherein the second composition consists of whey protein and sodium aluminosilicate.

15. The method of claim 12 , wherein the first and second densities are selected, and the size of the granules is selected to effect sinking the polymer, by the substrate, into a fluid.

16. The method of claim 15 , wherein the fluid is moving as a carrier, characterized by a viscosity, and the polymer is selected based on its effectiveness to increase in size by absorbing the fluid.

17. The method of claim 12 , wherein the substrate is a proppant selected from the group consisting of a sand, a ceramic, and a rock product.

18. A method for producing a self-suspending proppant particle, the method comprising:

providing a substrate comprising discrete particles;

providing a water soluble material as a binder;

providing a first composition containing a polymer, characterized by a chemistry and formed as a first powder, wherein the first composition comprises a plurality of polymers distinct from one another;

coating the substrate individually with the binder;

forming granules by coating the binder on the substrate individually with the first powder;

providing a second composition containing a flowing agent to increase flowability of the resultant granules, characterized by a chemistry and formed as a second powder, wherein the second composition is selected from the group consisting of sodium aluminosilicate, fumed silica, and whey protein[and DFC]; and

forming granules by coating the first powder on the substrate individually with the second powder, wherein the self-suspending proppant particles are configured to remain suspended in a 1000 ppm CaCO 3 aqueous solution for at least 30 minutes at a temperature of 170° F.

19. The method of claim 18 , wherein the substrate is a proppant selected from the group consisting of a sand, a ceramic, and a rock product.

20. The method of claim 19 , wherein the second composition comprises a plurality of flowing agents, distinct from one another.

Cited By (9)
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