Coated wavelength converting material for a light emitting device
Embodiments of the invention include a transparent material such as glass including a metal such as bismuth, particles of luminescent material such as a nitride phosphor disposed in the transparent material, and a coating disposed over the particles of luminescent material. The coating is formed to prevent reaction between the particles of luminescent material and the metal. The coating may be silica.
1. A wavelength converting structure comprising:
a transparent material comprising a metal ion;
particles of luminescent material disposed in the transparent material; and
a coating disposed over the particles of luminescent material, the coating comprising silica and having a density of from 2.1-2.16 g/cm 3 to prevent reaction between the particles of luminescent material and the metal ion.
2. The wavelength converting structure of claim 1 wherein the transparent material is glass and the metal ion comprises bismuth.
3. The wavelength converting structure of claim 1 wherein the luminescent material is a phosphor containing nitrogen.
4. The wavelength converting structure of claim 1 wherein the coating is between 20 and 400 nm thick.
5. The wavelength converting structure of claim 1 wherein the metal ion is Bi(III), the luminescent material is a phosphor comprising one of amine and hydroxyl groups, and the coating is formed to prevent the amine and hydroxyl groups from interacting with the Bi(III) and forming B(0).
6. The wavelength converting structure of claim 1 wherein the coating comprises a material selected from the group consisting of a binary oxide, a ternary oxide, a multinary oxide, Al 2 O 3 , AlPO 4 , and ZrO 2 .
7. The wavelength converting structure of claim 1 wherein the coating comprises an oxide comprising a material selected from the group consisting of aluminum, boron, germanium and phosphorus.
8. A method comprising:
coating particles of phosphor with silica;
after said coating, heating the coated particles to densify the coating; and
after said heating, embedding the coated particles in a glass comprising bismuth, wherein the coating is formed to prevent the bismuth from being reduced due to contact with the phosphor.
9. The method of claim 8 wherein coating particles of phosphor comprises using a sol gel process.
10. The method of claim 8 wherein coating particles of phosphor comprises:
dispersing the particles of phosphor in an alcohol;
after said dispersing, adding ammonia and a silicon alkoxide precursor; and
heating the coated particles of phosphor at a temperature of at least 450° C. and no more than 550° C. to densify the coating.
11. The method of claim 8 wherein coating particles of phosphor comprises forming a coating between 20 and 400 nm thick with a density of at least 2.1 g/cm 3 .
12. The method of claim 8 wherein the phosphor comprises nitrogen.