Crosslinking cellulose with Glyoxal to improve absorption properties
The present invention is directed to a novel dialdehyde based reagent that is neutralized, wherein the preparation of the reagent includes the steps of provide a dialdehyde; provide a caustic soda; mix both reagents until pH of the dialdehyde is 5.5 to 7.5; and stir the mixture.
1. A dialdehyde based reagent, which consists of:
a solution of dialdehyde and a caustic soda in water,
wherein the solution has a pH of about 5.5 to 7.5, and
wherein the dialdehyde is 2.0% by weight in the solution.
2. The dialdehyde based reagent of claim 1 , wherein the reagent is suitable for making liquid surge fiber.
3. The dialdehyde based reagent of claim 2 , wherein the surge fiber is useful as a surge layer in an absorbent article.
4. The dialdehyde based reagent of claim 1 , wherein the dialdehyde is selected from glyoxal, glutaraldehyde, 1,4-cyclohexane dicarbaldehyde, and 1,3-cyclohexane dicarbaldehyde, and mixtures thereof.
5. The dialdehyde based reagent of claim 1 , wherein the caustic soda is sodium hydroxide or potassium hydroxide.
6. A method of making liquid surge fiber, comprising: providing a solution of the dialdehyde based reagent of claim 1 ; providing cellulosic fiber derived from wood pulp; applying the solution of the dialdehyde based reagent to the cellulosic fibers to impregnate the cellulosic fibers; and drying the treated cellulosic fibers.
7. The method of claim 6 , wherein the solution of the dialdehyde based reagent is applied to the cellulosic fiber by spraying, dipping or applying with a puddle press, size press or a blade-coater.
8. The method of claim 6 , wherein the cellulosic fiber is provided in sheet or roll form.
9. The method of claim 6 , wherein the solution of the reagent is applied to the cellulosic fibers to provide 1 wt % to about 3 wt % of dialdehyde based reagent on the fiber.
10. The method of claim 6 , wherein the cellulosic fiber is a cellulose fiber selected from the group consisting of: hardwood cellulose pulp, softwood cellulose pulp obtained from a kraft or sulfite chemical process, caustic-treated pulp and combinations and mixtures thereof.
11. The method of claim 6 , wherein the drying is conducted at a temperature within the range of about 120° C. to about 160° C.
12. The method of claim 6 , wherein the treated cellulosic fibers are dried for a period that affords the fibers with a moisture content of less than 7%.
13. A cellulose fiber which is crosslinked by the dialdehyde based reagent of claim 1 .
14. An article of manufacture comprising the cellulose fiber of claim 13 .
15. A composition consisting of the dialdehyde based reagent according to claim 1 and cellulose fibers derived from wood pulp.
16. A composition according to claim 15 , wherein the concentration of the dialdehyde based reagent to cellulose fibers is 0.5 to 3.0 wt % of reagent to fibers.
17. A composition consisting of cellulose fibers derived from wood pulp, which are crosslinked with the dialdehyde based reagent according to claim 1 .
18. The composition according to claim 17 , wherein the fibers have a free swell (FS) greater than about 9.0 g/g, and an absorbency under load of 0.3 psi of greater than about 8.0 g/g.
19. A method of making a liquid surge fiber, comprising:
providing a solution of the dialdehyde based reagent of claim 1 ,
applying the solution of the dialdehyde based reagent to cellulosic fibers derived from wood pulp in sheet form to impregnate the cellulosic fibers,
removing excess solution from the cellulosic fibers by pressing to a desired pickup, and
drying and curing the cellulosic fibers at a temperature not higher than 135° C. for a period sufficient to afford completely dry cellulosic fibers.
20. The method of claim 19 , wherein the completely dry cellulosic fibers contain less than 30.0% knots and fines and has and ISO brightness of over 80%.