Ethylene-(meth)acrylic acid copolymer and water-dispersive composition including the same
An ethylene-(meth)acrylic acid copolymer has a polydispersity index (PDI) in a range from 3.5 to 8.0, and has a melt flow index (MFI) measured at 190° C. and 2.16 kg in a range from 350 g/10 min to 1800 g/10 min A water-dispersive composition includes the ethylene (meth)acrylic acid copolymer, a neutralizing agent and an aqueous medium.
1. An ethylene-(meth)acrylic acid copolymer having a polydispersity index (PDI) calculated from an absolute method using a gel permeation chromatography(GPC)-light scattering(LS) detector in a range from 3.5 to 8.0, and having a melt flow index (MFI) measured at 190° C. and 2.16 kg in a range from 350 g/10 min to 1800 g/10 min;
wherein a ratio of a z-average molecular weight (Mz) measured by a GPC-LS detector relative to a weight average molecular weight (Mw) measured by a GPC-LS detector is in a range from 6 to 10.
2. The ethylene-(meth)acrylic acid copolymer according to claim 1 , wherein a content of (meth)acrylic acid is 15 to 30 wt %, and a content of ethylene is 70 to 85 wt %.
3. The ethylene-(meth)acrylic acid copolymer according to claim 1 , wherein a melting point of the ethylene-(meth)acrylic acid copolymer is in a range from 50° C. to 95° C.
4. The ethylene-(meth)acrylic acid copolymer according to claim 1 , wherein a the weight average molecular weight (Mw) measured by a gel permeation chromatography (GPC)-light scattering (LS) detector of the ethylene-(meth)acrylic acid copolymer is in a range from 10,000 to 60,000.
5. The ethylene-(meth)acrylic acid copolymer according to claim 1 , wherein a ratio of a z-average molecular weight (Mz) measured by a relative method using a gel permeation chromatography (GPC) relative to a weight average molecular weight (Mw) measured by a relative method using a GPC is in a range from 2.5 to 5.0.
6. The ethylene-(meth)acrylic acid copolymer according to claim 1 , wherein the PDI of the copolymer is 3.8 to 6.0, and the MFI of the copolymer is in a range from 1,000 g/10 min to 1,500 g/10 min.
7. A water-dispersive composition comprising:
the ethylene-(meth)acrylic acid copolymer according to claim 1 ;
a neutralizing agent; and
an aqueous dispersion medium.
8. The water-dispersive composition according to claim 7 , wherein a solid content of the composition is in a range from 20% to 50%.
9. The water-dispersive composition according to claim 7 , wherein a solid content of the composition is in a range from 30% to 40%.
10. The water-dispersive composition according to claim 7 , wherein a viscosity of the composition at 25° C. is in a range from 100 cps to 10,000 cps measured using a Brookfield DV-II viscometer, Spindle No. 52.
11. The water-dispersive composition according to claim 7 , wherein a viscosity of the composition at 25° C. is in a range from 100 cps to 2,500 cps measured using a Brookfield DV-II viscometer, Spindle No. 52.
12. The water-dispersive composition according to claim 11 , wherein a degree of neutralization of acid groups included in the ethylene-(meth)acrylic acid copolymer is in a range from 25% to 50%.
13. The water-dispersive composition according to claim 7 , wherein the neutralizing agent includes at least one of NH 4 OH, an organic amine, KOH, NaOH, CsOH, or LiOH.
14. The water-dispersive composition according to claim 7 , further comprising at least one a polyolefin-based polymer.