IP Library Granted Patent US 12,258,475
Granted Patent B2
US 12,258,475 · App. 16/267,830 · Granted Mar 25, 2025

Warm mix asphalt binder compositions containing lubricating additives

Inventors: Gerald H. Reinke (La Crosse, WI); Gaylon L. Baumgardner (Arkadelphia, AR); Steven L. Engber (Onalaska, WI)
Assignees: A.L.M. Holding Company; Ergon Asphalt & Emulsions, Inc.
C08L95/00C04B26/26C08K5/0008C09D195/00E01C7/265E01C19/08E01C19/10C04B2111/0075C08K5/17C08K5/521C08L2555/24C08L2555/34C08L2555/40C08L2555/60C08L2555/72C08L2555/80Y02A30/30Y02W30/91
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Quick Facts
Patent No.
US 12,258,475
App. No.
16/267,830
Granted
Mar 25, 2025
Kind
B2
Abstract

The present invention provides a functionally dry warm mix asphalt binder composition modified with lubricating agents or additives that can be mixed with aggregate and compacted at temperatures substantially below asphalt binder compositions that do not contain the disclosed lubricating additives.

Claims (19)

1. An asphalt paving composition comprising an aggregate and a functionally dry, warm mix asphalt binder composition coating the aggregate, said functionally dry, warm mix asphalt binder composition comprising an asphalt binder, an antistrip additive, and one or more lubricating additives selected from a lubricating surfactant, a lubricating non-surfactant, a lubricating acid or combination thereof.

2. The asphalt paving composition according to claim 1 , wherein the antistrip additive comprises a surfactant.

3. The asphalt paving composition according to claim 1 , wherein the antistrip additive provides improved moisture resistance to the asphalt paving composition.

4. The asphalt paving composition according to claim 1 , wherein the antistrip additive comprises a compound selected from a cationic surfactant, a phosphate ester, an amine, a polyamine, and a combination thereof.

5. The asphalt paving composition according to claim 1 , wherein the asphalt paving composition is a warm mix asphalt paving composition at a temperature of 280° F. or lower and wherein the aggregate is uncompacted.

6. The asphalt paving composition according to claim 1 , wherein the aggregate comprises reclaimed asphalt pavement (RAP), wherein the antistrip additive comprises a polyamine, wherein the one or more lubricating additives comprise an ethoxylated tallow diamine, and wherein the asphalt paving composition is produced by a method comprising mixing the asphalt binder composition and the aggregate at a temperature of 220-240° F.

7. The asphalt paving composition according to claim 1 , wherein the aggregate comprises reclaimed asphalt pavement (RAP), wherein the antistrip additive comprises a polyamine, wherein the one or more lubricating additives comprise an ethoxylated tallow diamine, and wherein the asphalt paving composition can be adequately compacted at a temperature of 205-225° F.

8. The asphalt paving composition according to claim 1 , wherein the asphalt paving composition when paved and compacted at a warm mix temperature has a compacted density 91% or higher compared to a maximum theoretical density.

9. The asphalt paving composition according to claim 1 , wherein the presence of the one or more lubricating additives allows the asphalt binder composition to adequately coat the aggregate at a warm mix temperature that is 30-50° F. lower than the temperature needed for the asphalt binder on its own to adequately coat the aggregate without the one or more lubricating additives and the antistrip additive.

10. The asphalt paving composition according to claim 1 , wherein the lubricating additive is about 0.1-1.0 weight percent of the asphalt binder composition based on the weight of the asphalt binder composition.

11. The asphalt paving composition according to claim 1 , wherein the asphalt binder comprises an asphalt binder selected from a polymer-modified asphalt binder, an acid-modified asphalt binder, or a polymer- and acid-modified asphalt binder.

12. The asphalt paving composition according to claim 1 , wherein the aggregate comprises reclaimed asphalt pavement (RAP).

13. The asphalt paving composition according to claim 1 , wherein the functionally dry, warm mix asphalt binder composition has a measured maximum normal force no more than about 5.5 Newtons at 90° C. using a dynamic shear rheometer with a 50 μm gap.

14. The asphalt paving composition according to claim 1 , wherein the asphalt paving composition contains less than 5 weight percent water based on the weight of the asphalt paving composition.

15. The asphalt paving composition according to claim 1 , wherein the one or more lubricating additives comprise ethoxylated tallow diamine.

16. The asphalt paving composition of claim 1 , wherein the one or more lubricating additives comprise a lubricating non-surfactant, and wherein the lubricating non-surfactant comprises a wax.

17. The asphalt paving composition of claim 1 , wherein the one or more lubricating additives comprises a lubricating acid, and wherein the lubricating acid is polyphosphoric acid.

18. The asphalt paving composition according to claim 1 , wherein the asphalt paving composition is produced by a method comprising mixing the asphalt binder composition and the aggregate at a warm mix temperature.

19. The asphalt paving composition according to claim 1 , wherein the asphalt paving composition is produced by a method comprising adequately coating the aggregate with the asphalt binder composition at a warm mix temperature, wherein the adequate coating would require a temperature at least 30° F. higher in the absence of the one or more lubricating additives.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 5, 2019
From: REINKE, GERALD H.; BAUMGARDNER, GAYLON L.; ENGBER, STEVEN L.
To: ALM HOLDING CO.
Reel/Frame 048241/0236 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 5, 2019
From: ALM HOLDING COMPANY
To: ALM HOLDING COMPANY; ERGON ASPHALT & EMULSIONS, INC.
Reel/Frame 048241/0478 →
Continuity (11)
Continuation 14926752 · Oct 29, 2015
Continuation 14223569 · Mar 24, 2014
Continuation 13683043 · Nov 21, 2012
Continuation 13112815 · May 20, 2011
Continuation 12896488 · Oct 1, 2010
Continuation 12896570 · Oct 1, 2010
Continuation 12896532 · Oct 1, 2010
Continuation 11871782 · Oct 12, 2007
Provisional Application 60976141 · Sep 28, 2007
Provisional Application 60970809 · Sep 7, 2007
Related Publication 20190218395A1 · Jul 18, 2019
References Cited (230)
US 1014103A · Wallbaum · 1912 [cited by applicant]
US 1373661A · Johansen · 1921 [cited by applicant]
US 1384805A · McSwiney · 1921 [cited by applicant]
US 1542626A · MacKay · 1925 [cited by applicant]
US 1640544A · Headley · 1927 [cited by applicant]
US 1674523A · Sadtler · 1928 [cited by applicant]
US 1778760A · Hay · 1930 [cited by applicant]
US 1815089A · Alsdorf · 1931 [cited by applicant]
US 1834552A · Sadtler et al. · 1931 [cited by applicant]
US 1842139A · Alsdorf · 1932 [cited by applicant]
US 1887518A · Sadtler · 1932 [cited by applicant]
US 1888295A · Smith · 1932 [cited by applicant]
US 1932648A · Taylor · 1933 [cited by applicant]
US 1948881A · Kirschbaum · 1934 [cited by applicant]
US 1988336A · Roediger · 1935 [cited by applicant]
US 1988879A · Steininger · 1935 [cited by applicant]
US 2023068A · Flood · 1935 [cited by applicant]
US 2025945A · Forrest · 1935 [cited by applicant]
US 2046902A · Kirschbaum · 1936 [cited by applicant]
US 2087401A · Fair · 1937 [cited by applicant]
US 2191295A · Dohse · 1940 [cited by applicant]
US 2243519A · Barth · 1941 [cited by applicant]
US 2283192A · Ditto · 1942 [cited by applicant]
US 2317959A · Johnson et al. · 1943 [cited by applicant]
US 2340449A · Barwell · 1944 [cited by applicant]
US 2374732A · Colburn · 1945 [cited by applicant]
US 2427488A · Anderson et al. · 1947 [cited by applicant]
US 2461971A · Fischer · 1949 [cited by applicant]
US 2550481A · Jense · 1951 [cited by applicant]
US 2861787A · Csanyi · 1958 [cited by applicant]
US 2888418A · Albanese et al. · 1959 [cited by applicant]
US 2901369A · Pordes · 1959 [cited by applicant]
US 2917395A · Csanyi · 1959 [cited by applicant]
US 3855167A · Bowman · 1974 [cited by applicant]
US 3904428A · McConnaughay · 1975 [cited by applicant]
US 4197209A · Zinke et al. · 1980 [cited by applicant]
US 4198177A · Brett et al. · 1980 [cited by applicant]
US 4234346A · Latta, Jr. et al. · 1980 [cited by applicant]
US 4244747A · Leonard, Jr. et al. · 1981 [cited by applicant]
US 4348237A · Ruckel · 1982 [cited by applicant]
US 4592507A · Benedict · 1986 [cited by applicant]
US 4692350A · Clarke et al. · 1987 [cited by applicant]
US 4724003A · Treybig et al. · 1988 [cited by applicant]
US 4743304A · Gilmore et al. · 1988 [cited by applicant]
US 4836857A · Hopkins · 1989 [cited by applicant]
US 5109041A · Matsuno et al. · 1992 [cited by applicant]
US 5539029A · Burris · 1996 [cited by applicant]
US 5622554A · Krogh et al. · 1997 [cited by applicant]
US 5721296A · Mizunuma et al. · 1998 [cited by applicant]
US 5772749A · Schilling et al. · 1998 [cited by applicant]
US 5788755A · Salminen · 1998 [cited by applicant]
US 5827360A · Salminen · 1998 [cited by applicant]
US 5911817A · Hayner · 1999 [cited by examiner]
US 5925233A · Miller et al. · 1999 [cited by applicant]
US 6117926A · Engber et al. · 2000 [cited by applicant]
US 6136898A · Loza et al. · 2000 [cited by applicant]
US 6197837B1 · Hill et al. · 2001 [cited by applicant]
US 6399680B1 · Engber et al. · 2002 [cited by applicant]
US 6451885B1 · Dresin et al. · 2002 [cited by applicant]
US 6559206B1 · Durand et al. · 2003 [cited by applicant]
US 6576050B1 · Samanos · 2003 [cited by applicant]
US 6588974B2 · Hildebrand · 2003 [cited by examiner]
US 6793964B2 · Hoad · 2004 [cited by applicant]
US 6846354B2 · Larsen et al. · 2005 [cited by applicant]
US 6913416B2 · Hildebrand et al. · 2005 [cited by applicant]
US 7041165B2 · Malot · 2006 [cited by applicant]
US 7114843B2 · Romier et al. · 2006 [cited by applicant]
US 7114875B2 · Romier et al. · 2006 [cited by applicant]
US 7160943B2 · Burris et al. · 2007 [cited by applicant]
US 7297204B2 · Crews et al. · 2007 [cited by applicant]
US 7309390B2 · Falkiewicz · 2007 [cited by applicant]
US 7815725B2 · Reinke et al. · 2010 [cited by applicant]
US 7902277B2 · Reinke et al. · 2011 [cited by applicant]
US 7951858B2 · Barreto et al. · 2011 [cited by applicant]
US 7968627B2 · Reinke et al. · 2011 [cited by applicant]
US 7981466B2 · Reinke et al. · 2011 [cited by applicant]
US 7981952B2 · Reinke et al. · 2011 [cited by applicant]
US 8138242B2 · Reinke et al. · 2012 [cited by applicant]
US 8323394B2 · Reinke et al. · 2012 [cited by applicant]
US 8404037B2 · Naidoo et al. · 2013 [cited by applicant]
US 8440011B2 · Naidoo et al. · 2013 [cited by applicant]
US 8679245B2 · Reinke et al. · 2014 [cited by applicant]
US 8840717B2 · Naidoo et al. · 2014 [cited by applicant]
US 9394652B2 · Reinke et al. · 2016 [cited by applicant]
US 10214646B2 · Reinke et al. · 2019 [cited by applicant]
US 20020170464A1 · Larsen et al. · 2002 [cited by applicant]
US 20040014845A1 · Takamura et al. · 2004 [cited by applicant]
US 20040223808A1 · Romier et al. · 2004 [cited by applicant]
US 20040244646A1 · Larsen et al. · 2004 [cited by applicant]
US 20050018530A1 · Romier et al. · 2005 [cited by applicant]
US 20050284333A1 · Falkiewicz · 2005 [cited by applicant]
US 20060086288A1 · Bourrel et al. · 2006 [cited by applicant]
US 20060169173A1 · Dupuis et al. · 2006 [cited by applicant]
US 20060236614A1 · Antoine et al. · 2006 [cited by applicant]
US 20060240185A1 · Antoine et al. · 2006 [cited by applicant]
US 20060288907A1 · Fox · 2006 [cited by applicant]
US 20070039520A1 · Crews et al. · 2007 [cited by applicant]
US 20070060676A1 · Reinke · 2007 [cited by applicant]
US 20070082983A1 · Crews et al. · 2007 [cited by applicant]
US 20070169668A1 · Moss et al. · 2007 [cited by applicant]
US 20070191514A1 · Reinke et al. · 2007 [cited by applicant]
US 20090088499A1 · Barreto et al. · 2009 [cited by applicant]
US 20100055304A1 · Reinke et al. · 2010 [cited by applicant]
US 20110017096A1 · Reinke · 2011 [cited by applicant]
US 20110020537A1 · Reinke · 2011 [cited by applicant]
US 20110021673A1 · Reinke · 2011 [cited by applicant]
US 20110152410A1 · Reinke · 2011 [cited by applicant]
US 20110214589A1 · Reinke · 2011 [cited by applicant]
US 20120213584A1 · Reinke et al. · 2012 [cited by applicant]
US 20230257585A1 · Reinke et al. · 2023 [cited by applicant]
AU 433003 · 1973 [cited by applicant]
AU 2006231250 · 2006 [cited by applicant]
AU 2007255222C1 · 2007 [cited by applicant]
CN 1644625 · 2004 [cited by applicant]
EP 0077632A1 · 1983 [cited by applicant]
EP 0568021 · 1993 [cited by applicant]
EP 0994923 · 2000 [cited by applicant]
EP 1398351 · 2004 [cited by applicant]
EP 1263885 · 2004 [cited by applicant]
EP 1469038 · 2004 [cited by applicant]
EP 2062943A1 · 2009 [cited by applicant]
EP 3425007A1 · 2019 [cited by applicant]
EP 2185649B1 · 2019 [cited by applicant]
GB 429548 · 1935 [cited by applicant]
GB 783015 · 1957 [cited by applicant]
GB 2234512 · 1989 [cited by applicant]
JP 2002332606 · 2002 [cited by applicant]
JP 2006132131 · 2006 [cited by applicant]
WO 19950022661 · 1995 [cited by applicant]
WO WO9911737A1 · 1999 [cited by examiner]
WO 9957199 · 1999 [cited by applicant]
WO 0056346A1 · 2000 [cited by applicant]
WO 200116233 · 2001 [cited by applicant]
WO 2001062852 · 2001 [cited by applicant]
WO 2002016499 · 2002 [cited by applicant]
WO 2002103116 · 2002 [cited by applicant]
WO 2005081775 · 2005 [cited by applicant]
WO 2006106222 · 2006 [cited by applicant]
WO 2007032915 · 2007 [cited by applicant]
WO 2007054503A1 · 2007 [cited by applicant]
WO 2007112335 · 2007 [cited by applicant]
WO 2008148974 · 2008 [cited by applicant]
WO 2009033060 · 2009 [cited by applicant]
AKZO International Highway Chemical Newsletter, Chemical Division, Spring 1989, pp. 1-9. [cited by applicant]
Anderson, David A., et al., “The Effect of Antistrip Additives on the Properties of Asphalt Cement,” Asphalt Paving Technology 1982, Proceedings Association of Asphalt Paving Technologists Technical Sessions, Kansas Cit… [cited by applicant]
Barreto, “Warm Asphalt Mixes Containing Dispersed Water,” Arkema-Ceca France, Abstract No. 658, 2006, 7 pp. [cited by applicant]
Bonola et al., “Technologies for the Production of Asphalt Mixes with Low Temperature Processes,” World Road Association Italian National Committee, Dec. 2005, 31 pp. [cited by applicant]
Caillot et al., “Warm Mix Asphalts and Cold Recycling for Controlled Use of Effective Road Techniques Reducing Nuisances,” Technical Department for Transport, Roads, and Bridges, Engineering for Road Safety, Ministry fo… [cited by applicant]
Ceca Arkema Group, “Green Road Formulation—Warm Asphalt Mix. 2007 Innovation: helping to lower our planet's temperature,” www.siliporite.com, accessed Nov. 21, 2007, 1 pg. [cited by applicant]
Cervarich, “Cooling Down the Mix” NAPA Explores New “Warm Mix Asphalt” Technologies Developed in Europe, Hot Mix Asphalt Technology, Mar./Apr. 2003, pp. 13-16. [cited by applicant]
Choi, Y., Warm Asphalt Review, Austroads Report, Arrb Research, RETT220B, Publication No. AP-T91/07, Nov. 2007. [cited by applicant]
Damm, K., Abraham, J., Butz, T., Hildebrand, G., Riebeschl, G., “Asphalt Flow Improvers as Intelligent Fillers for Hot Asphalts—A New Chapter in Asphalt Technology,” Journal of Applied Asphalt Binder, vol. 2, Issue 1, p… [cited by applicant]
Diefenderfer et al., “Research Report: Installation of Warm Mix Asphalt Projects in Virginia,” Virginia Transportation Research Council, Apr. 2007, 34 pp. [cited by applicant]
Gibson, Nelson, Modified Asphalt Research Activities at FHWA's Turner-Fairbank Highway Research Center (TFHRC), Pavement Materials and Construction Team, AMAP Conference, Feb. 2005, Orlando, FL, 18 pages. [cited by applicant]
Goh et al., “Laboratory Evaluation and Pavement Design for Warm Mix Asphalt,” Proceedings of the 2007 Mid-Continent Transportation Research Symposium, Ames, IA, Aug. 2007, 11 pp. [cited by applicant]
Gudimettla, Jagan M., et al., “Workability of Hot Mix Asphalt,” National Center for Asphalt Technology, Apr. 2003, 66 pages. [cited by applicant]
Hurley et al., “Evaluation of Aspha-Min™ Zeolite for Use in Warm Mix Asphalt,” National Center for Asphalt Technology Report, Auburn University, 30 pp., Jun. 2005. [cited by applicant]
Hurley et al., “Evaluation of Evotherm™ for Use in Warm Mix Asphalt,” National Center for Asphalt Technology Report, Auburn University, Jun. 2006, 49 pp. [cited by applicant]
Hurley et al., “Evaluation of Potential Processes for Use in Warm Mix Asphalt,” National Center for Asphalt Technology, 2006, 46 pp. [cited by applicant]
Hurley, Graham C., et al., “Evaluation of Sasobit™ for Use in Warm Mix Asphalt,” National Center for Asphalt Technology Report, Auburn University, Jun. 2005, 32 pp. [cited by applicant]
International Search Report issued in PCT/US/2006/33907, dated Sep. 24, 2007, 4 pages. [cited by applicant]
International Search Report and Written Opinion issued in PCT/US2008/075452, dated Feb. 13, 2009, 13 pages. [cited by applicant]
International Search Report for PCT/US2009/034742, dated May 26, 2009, 10 pages. [cited by applicant]
International Search Report and Written Opinion issued in PCT/US2009/052830, dated Sep. 16, 2010, 9 pages. [cited by applicant]
James, A.D., et al., “Adhesion Agents for Use in Hot Mixes and Cut-Back Bituments,” presented at the 3 [cited by applicant]
Jenkins et al., “Half-Warm Foamed Bitumen Treatment, A New Process,” 7 [cited by applicant]
Jones, “Warm Mix Asphalt Pavements: Technology of the Future?” Asphalt, Fall 2004, pp. 8-11. [cited by applicant]
Koenders et al., “Innovative process in asphalt production and application to obtain lower operating temperatures,” 2 [cited by applicant]
Kristjansdottir, Olof, “Warm Mix Asphalt for Cold Weather Paving,” a thesis, University of Washington, 2006, 127 pp. [cited by applicant]
LaPointe, Dennis G., e-mail correspondence, May 2011, 4 pages. [cited by applicant]
Lavin, Patrick, “Asphalt Pavements: A practical guide to design, production and maintenance for engineers and architects,” 2003, pp. 347. [cited by applicant]
Logaraj, Sundaram, et al., “Surface-active bitumen additive for warm mix asphalt with adhesion promoting properties,” 2009, 12 pages. [cited by applicant]
“Low Energy Asphalt (LEA) with the Performance of Hot-Mix Asphalt (HMA)”, European Roads Review, Special Issue, BGRA, Feb. 2004 (pp. 1-11). [cited by applicant]
Malick, R.BN, Bradley, J.E., Bradbury, R.L., An Evaluation of Heated Reclaimed Asphalt Pavement (RAP) Material and Wax Modified Asphalt for Use in Recycled Hot Mix Asphalt (HMA), 2007. [cited by applicant]
Naidoo, P., “Fischer-Tropsch Hard Wax Chemistry in Warm Mix Asphalt Applications,” Petersen Asphalt Research Conference, Abstract and Presentation Slides, Jun. 20-22, 2005. [cited by applicant]
Naidoo, P., Sasobit in Warm Mix Asphalt Applications 9 Years of Global Successes, World Asphalt Conference Presentation Slides, Mar. 14, 2006. [cited by applicant]
Paez, R., “Production of Modifier Asphalt Additives in Equator,” 2005 International Symposium on Pavement Recycling, Sau Paulo, Brazil, Mar. 14-16, 2005, pp. 1-11. [cited by applicant]
Progress Report 2006, The German Bitumen Forum, Jun. 2006, 36 pp. [cited by applicant]
Schwartz, Anthony M., et al., Surface Active Agents and Detergents, vol. 2, 1977, pp. 673-677. [cited by applicant]
Tarrer, A.R., et al., “The Effect of the Physical and Chemical Characteristics of the Aggregate on Bonding,” Strategic Highway Research Program, Feb. 1991, 31 pages. [cited by applicant]
Iterchimica Company; “Abstract of the 2005 production categories and applications,” Iterchimica Brochure, p. 2 (2005). [cited by applicant]
Giannattasio, Allessandro, “To improve the quality of road bitumen,” Reprint from the Italian Building and Construction Issue No. 69/1998-19 [cited by applicant]
Petersen, J. Claine, “Relationships Between Asphalt Chemical Composition and Performance-Related Properties,” ISSA Meeting, Phoenix Arizona, Jan. 23-27, 1982, 10 [cited by applicant]
Declaration of Patrick Lavin, Jun. 6, 2011; explains 26 years of experience with essentially water-free, non-foaming binders along with the use of additives and the effects of temperature on paving. [cited by applicant]
Declaration of Gerald H. Reinke Under 37 CFR 1.132, Jun. 1, 2012. [cited by applicant]
Declaration of Jan Alboszta Under 37 CFR 1.132, Jun. 1, 2012. [cited by applicant]
Boldyrev et al., Experience in Using AMDOR-9 Adhesion Additive in the Practice of Road Construction, International Conference ‘Bitumen in road construction’, 2005. [cited by applicant]
Chiman, “Aspects of Influence of Additives on Characteristics of Non-Polimetricos Asphalt,” Corporation for Research and Development in Asphalt Transport Sector and Industrial Corasfaltatos. [cited by applicant]
Butz et al., “Motification of Road Bituments with the Fischer-Tropsch Paraffin Sasobit,” Journal of Applied Asphalt Technology, Oct. 2001. [cited by applicant]
Florida Department of Transportation, Standard Specifications for Road and Bridge Construction, 2007. [cited by applicant]
Gaudefroy et al., “Laboratory Investigations on the Mechanical Performances of Foamed Bitumen Mixes Using Half-Warm Aggregates,” TRB 2007 Annual Meeting CD-ROM. [cited by applicant]
Kanitpong et al., “Laboratory Study on Warm Mix Asphalt Additives,” TRB 2007 Annual Meeting CD-ROM. [cited by applicant]
Kristjansdottir et al., “Assessing the Potential for Warm Mix Asphalt Technology Adoption,” TRB 2007 Annual Meeting CD-ROM. [cited by applicant]
Modern Asphalts, Autumn 2006, Issue No. 18. [cited by applicant]
Prowell et al., “Field Performance of Warm Mix Asphalt at the NCAT Test Track,” TRB 2007 Annual Meeting CD-ROM. [cited by applicant]
Sasobit Product Information 124, 9 pgs., Apr. 22, 2004. [cited by applicant]
Sasobit Roads and Trials with Sasobit, 7 pgs. [cited by applicant]
Transportation Research Board, 86 [cited by applicant]
Wasiuddin et al., “A Comparative Laboratory Study of Sasobit and Aspha-Min for Warm Mix Asphalt,” TRB 2007 Annual Meeting CD-ROM. [cited by applicant]
DIN 1995 Requirements for the Binders, Oct. 1989. [cited by applicant]
Edwards et al., “Rehological effects of commercial waxes and polyphosphoric acid in bitumen 160/220—low temperature performance.” Apr. 20, 2005. [cited by applicant]
Forbes, Robert J., (1993) “Studies in Ancient Technology”, Third Edit, E.J. Brill, pp. 1-124. [cited by applicant]
Hollander, D., et al., (2000) “Annealing, Distilling, Reheating and Recycling: Bitumen Processing in the Ancient Near East”, Paleorient, vol. 26, No. 2, pp. 83-91. [cited by applicant]
Edwards, Ylva, (2005) “Influence of Waxes on Bitumen and Asphalt Concrete Mixture Performance”, Thesis, pp. 1-54. [cited by applicant]
Mahoney, J.P., et al., (1982) “Suffer Extended Asphalt Laboratory Investigation—Mixture Characterization”, Highway Administration Building, Olympia, WA, retrieved from the internet: URL:https://www.wsdot.wa.gov/research… [cited by applicant]
Anonymous (2011): “Recommended Mixing and Compaction Temperatures for Performance Graded (PG) Binders (Unmodified PG Binders and Modified PG Binders)”, retrieved from the internet: URL:http://www.asphalt-materials.com/d… [cited by applicant]
Brian D. Prowell, Ph.D., P.E., “Warm Mix Asphalt” The International Technology Scanning Program, Desk Scan, National Center for Asphalt Technology, Nov. 2, 2006, coverpage, pp. i-iv, and pp. 1-20. [cited by applicant]
Boldyrev A.V., Avanesova H.M., Zao “Amdor”, St. Petersburg, “Application the bitumen emulsions in highway engineering”, (2005) cover pages—p. 3, p. 74-85, with English translation (total 19 pgs). [cited by applicant]
USSR National Standard, GOST 11508-74 “Petroleum bitumen, Methods of determination of bitumen adhesion to marble and sand” Apr. 2, 1974, No. 250. (1974) pp. 1-5. [cited by applicant]
Olaf Kristjansd6ttir, “Warm Mix Asphalt Technology Adoption” NVF 33 Annual Meeting, Norway, Jun. 2007, pp. 1-9. [cited by applicant]
Mats Jonsson et al., Report, Adhesion test, Swedish Road Administration, (Jul. 6, 2007) pp. 1-20, with English translation (total 40 pgs). [cited by applicant]
Barthel et al., “Warm Asphalt Mixes By Adding a Synthetic Zeolite” Proceedings of the Third Eurasphalt and Eurobitume, (2004) pp. 1241-1249. [cited by applicant]
US Department of Transportation, Background of Superpave Asphalt Mixture Design and Analysis, “Ch III, Materials Selection”, Publication No. FHWA-SA-95-003, Feb. 1995, cover pages, table of contents pp. 33-52. [cited by applicant]
R.G. Hicks et al., Asphalt Paving Design Guide, Chapter 2, “Considerations for Materials, Mix Selection and Mix Design” Department of Civil Engineering, Oregon State University, prepared for Asphalt Pavement Association… [cited by applicant]
Freddy L. Roberts et al., Hot Mix Asphalt Materials, Mixture Design and Construction, Chapter 3. Aggerates, NAPA Education Foundation, Lanham, Maryland, 2d Ed. (1996) pp. 121-172. [cited by applicant]
US Army Corps of Engineers, “Hot-Mix Asphalt Paving Handbook 2000” AC 150/5370-14A Appendix 1, (2000) pp. 1-9. [cited by applicant]
G.P. Moss et al., Glossary of Class Names of Organic Compounds and Reactive Intermediates Based on Structure, Pure & Appl. Chem., vol. 67, Nos. 8/9, (1995) pp. 1307-1375. [cited by applicant]
M.J. Rosen, “Surfactants and Interfacial Phenomena”, 3d edition, p. 26 (2024), coverpages, pp. 3-4 and 26-28. [cited by applicant]
AMDOR-9, Adhesive Dopes for Road Application, Russia, 193148, Sankt-Peresburg, Box 67, [email protected], English translation, total pages 10. [cited by applicant]
US Department of Transportation, International Technology Exchange Program, Gibbs, et al., “Quiet Pavement Systems in Europe” May 2005, pp. 1-36 (total pgs. 50). [cited by applicant]
Akzo Nobel, Surfactants, Wetfix BE Product Information, Akzo Nobel Surace Chemistry AB, Version: 1.0, Issued May 24, 2006, pp. 1-2. [cited by applicant]
A Wirtgen Group Company, Brochure “Innovative laboratory equipment. Preliminary testing to determine the mix quality” WIRTGEN GmbH, (2016) pp. 1-16. [cited by applicant]
Techbrief, “Analytical Method to Measure Water in Asphalt and Its Application to Emulsion Residue Recovery”, Turner-Fairbank Highway Research Center, www.fhwa.dot./research, FHWA Publication No. FHWA-HRT-15-056, (Jun. 2… [cited by applicant]
International Technology Scanning Program, “Warm-Mix Asphalt: European Practice”, Sponsored by US Department of Transportation, Federal Highway Administration (Feb. 2008) 72 pgs. [cited by applicant]
D. Weaire and S. Hutzler, The Physics of Foam (1999) coverpages, pp. 3, 6-7, 12. [cited by applicant]
Notice of Opposition against EP 2 185 649 B1 (Application No. 08829379.9) of A.L.M. Holding Company filed Jan. 31, 2020, pp. 13. [cited by applicant]
EP No. 18 186 378.9, EPO Form 1507, Search Opinion, Oct. 17, 2018, pp. 1-7. [cited by applicant]
Akzo Nobel Surfactants—Asphalt Homepage, “The New Warm Mix System—Rediset WMX” http://www.surfactants.akzonobel.com/asphalt/newwarmmixsystem.cfm (viewed Mar. 12, 2009) 2 pgs. [cited by applicant]
Akzo Nobel, Rediset, “Adhesion Promoters” Technical Bulletin, www.surfactants.akzonobel.com (no date) pp. 1-28. [cited by applicant]
Akzo Nobel, “Redicote E-6”, Technical Information, Asphalt Applications, Akzo Nobel Chemicals Inc., E-6 LAS. DOC-LAS, (Apr. 11, 2003) 2 pgs. [cited by applicant]