IP Library Granted Patent US 10,923,761
Granted Patent B2
US 10,923,761 · App. 16/272,917 · Granted Feb 16, 2021

Lithium-ion battery

Inventors: Jiao Cao (Ningde, CN); Qifan Zou (Ningde, CN); Guangbo Lu (Ningde, CN); Shengwei Wang (Ningde, CN); Wenzhu Xu (Ningde, CN)
Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
H01M10/0525H01M4/505H01M4/525H01M4/583H01M2004/021
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 10,923,761
App. No.
16/272,917
Granted
Feb 16, 2021
Kind
B2
Abstract

The present disclosure provides a lithium-ion battery, and the lithium-ion battery comprises a positive electrode plate, a negative electrode plate, a separator and an electrolyte. The positive active material comprises a material with a chemical formula of Li a Ni x Co y M 1-x-y O 2 , the negative active material comprises graphite, the OI value of the positive film represented by OI c and the OI value of the negative film represented by OI a satisfy a relationship: 0.05≤OI a /OI c ≤10. By reasonably matching the OI value of the positive film represented by OI c and the OI value of the negative film represented by OI a and making OI a /OI c between 0.05 and 10, the dynamics performance of the positive electrode plate and the dynamics performance of the negative electrode plate can achieve an optimal match, the lithium-ion battery can have higher charging capability, and also have excellent cycle life and excellent safety performance during the long-term fast charging use.

Claims (43)

1. A lithium-ion battery comprising a positive electrode plate, a negative electrode plate, a separator and an electrolyte, the positive electrode plate comprising a positive current collector and a positive film, the positive film being provided on at least one surface of the positive current collector and comprising a positive active material, the negative electrode plate comprising a negative current collector and a negative film, the negative film being provided on at least one surface of the negative current collector and comprising a negative active material;

wherein

the positive active material comprises a material with a chemical formula of Li a Ni x Co y M 1-x-y O 2 , M is one or two selected from Al and Mn, 0.95≤a≤1.2, 0<x<1, 0<y<1, 0<x+y<1;

the negative active material comprises graphite;

an OI value of the positive film represented by OI c and an OI value of the negative film represented by OI a satisfy a relationship: 0.05≤OI a /OI c ≤10;

OI c =C 003 /C 110 , C 003 represents characteristic diffraction peak area of (003) crystal plane in X-ray diffraction pattern of the positive film, C 110 represents characteristic diffraction peak area of (110) crystal plane in X-ray diffraction pattern of the positive film;

OI a =C 004 /C 110 , C 004 represents characteristic diffraction peak area of (004) crystal plane in X-ray diffraction pattern of the negative film, C 110 represents characteristic diffraction peak area of (110) crystal plane in X-ray diffraction pattern of the negative film; and

the OI value of the positive film represented by OI c is 5˜80.

2. The lithium-ion battery according to claim 1 , wherein the OI value of the positive film represented by OI c and the OI value of the negative film represented by OI a satisfy a relationship: 0.2≤OI a /OI c ≤3.

3. The lithium-ion battery according to claim 1 , wherein

the OI value of the negative film represented by OI a is 5˜30.

4. The lithium-ion battery according to claim 1 , wherein

an average particle diameter D50 of the positive active material is 3 μm˜12 μm;

an average particle diameter D50 of the negative active material is 4 μm˜15 μm.

5. The lithium-ion battery according to claim 1 , wherein

an OI value of a powder of the positive active material represented by G OI is 3˜15;

an OI value of a powder of the negative active material represented by V OI is 2˜15;

G OI =C′ 003 /C′ 110 , C′ 003 represents characteristic diffraction peak area of (003) crystal plane in X-ray diffraction pattern of the powder of the positive active material, C′ 110 represents characteristic diffraction peak area of (110) crystal plane in X-ray diffraction pattern of the powder of the positive active material; and

V OI =C′ 004 /C′ 110 , C′ 004 represents characteristic diffraction peak area of (004) crystal plane in X-ray diffraction pattern of the powder of the negative active material, C′ 110 represents characteristic diffraction peak area of (110) crystal plane in X-ray diffraction pattern of the powder of the negative active material.

6. The lithium-ion battery according to claim 5 , wherein

the OI value of a powder of the positive active material represented by G OI is 5˜10;

the OI value of a powder of the negative active material represented by V OI is 2˜11.

7. The lithium-ion battery according to claim 1 , wherein

the pressing density of the positive film is 3.0 g/cm 3 ˜3.5 g/cm 3 ;

the pressing density of the negative film is 1.0 g/cm 3 ˜1.6 g/cm 3 .

8. The lithium-ion battery according to claim 1 , wherein the positive active material further comprises one or more selected from a group consisting of layered LiMnO 2 , spinel LiMn 2 O 4 , LiNi x Mn 2-x O 4 , LiCoO 2 and LiFePO 4 , 0<x<2.

9. The lithium-ion battery according to claim 1 , wherein

doping modification and/or coating modification is further performed on the positive active material.

10. The lithium-ion battery according to claim 1 , wherein the negative active material further comprises one or more selected from a group consisting of soft carbon, hard carbon, carbon fiber, mesocarbon microbeads, silicon-based material, tin-based material and lithium titanate.

11. The lithium-ion battery according to claim 2 , wherein the OI value of the positive film represented by OI c and the OI value of the negative film represented by OI a satisfy a relationship: 0.2≤OI a /OI c ≤0.60.

12. The lithium-ion battery according to claim 3 , wherein the OI value of the positive film represented by OI c is 10˜80.

13. The lithium-ion battery according to claim 12 , wherein the OI value of the positive film represented by OI c is 15˜80.

14. The lithium-ion battery according to claim 13 , wherein the OI value of the positive film represented by OI c is 28˜50.

15. The lithium-ion battery according to claim 3 , wherein the OI value of the negative film represented by OI a is 12˜30.

16. The lithium-ion battery according to claim 15 , wherein the OI value of the negative film represented by OI a is 15˜30.

17. The lithium-ion battery according to claim 4 , wherein

the average particle diameter D50 of the positive active material is 3 μm˜7.8 μm;

and/or, the average particle diameter D50 of the negative active material is 4 μm˜12 μm.

18. The lithium-ion battery according to claim 7 , wherein

the pressing density of the positive film is 3.3 g/cm 3 ˜3.5 g/cm 3 ;

and/or, the pressing density of the negative film is 1.40 g/cm 3 ˜1.6 g/cm 3 .

19. The lithium-ion battery according to claim 1 , wherein the positive active material comprises one or more selected from a group consisting of LiNi 0.5 Co 0.2 Mn 0.3 O 2 , LiNi 0.6 Co 0.2 Mn 0.2 O 2 , LiNi 0.8 Co 0.1 Mn 0.1 O 2 , LiNi 0.8 Co 0.1 Al 0.1 O 2 and LiNi 0.85 Co 0.15 Al 0.05 O 2 .

20. The lithium-ion battery according to claim 1 , wherein at least a part of the positive active material is monocrystal particles.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 6, 2024
From: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
To: CONTEMPORARY AMPEREX TECHNOLOGY (HONG KONG) LIMITED
Reel/Frame 068338/0723 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2019
From: CAO, JIAO; ZOU, QIFAN; LU, GUANGBO; WANG, SHENGWEI; XU, WENZHU
To: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITED
Reel/Frame 048555/0903 →
Priority Claims (1)
CN 2018 1 0695585 · Jun 29, 2018 · national
Continuity (1)
Related Publication 20200006801A1 · Jan 2, 2020