Light stable transparent adhesive compositions and methods for use thereof
Provided herein are high refractive index compositions with excellent light stability, and methods for the use thereof, as well as assemblies and articles prepared using invention formulations and methods.
1. A stable, high refractive index, non-yellowing, optically transparent adhesive formulation comprising:
phenoxy butyl acrylate and one or more of 1,4-cyclohexanediol monoacrylate, benzyl methacrylate or
and
ZrO 2 nanoparticles having a refractive index in the range of 1.70 up to 4.50,
wherein:
the resulting formulation has a refractive index in the range of about 1.55 up to about 2.0, and
the resulting formulation passes the standard industrial QUV test for at least 500 hours without a significant increase in its yellow index value.
2. The formulation of claim 1 having a yellow index value, B*, of <1.
3. The formulation of claim 1 wherein said formulation is in film form and has a thickness in the range of about 1 μm up to about 1000 μm.
4. The formulation of claim 1 wherein said formulation is at least 97% transparent.
5. The formulation of claim 1 wherein said nanoparticles have an average particle size of less than 40 nm.
6. The formulation of claim 1 wherein said nanoparticles are stabilized by the presence of one or more capping agents.
7. The formulation of claim 6 wherein said capping agent is a member selected from the group consisting of polyvinyl alcohol, poly(N-vinyl-2-pyrrolidone), gum arabic, α-methacrylic acid, 11-mercaptoundecanoic acid or the disulfide derivative thereof, citric acid, trisodium citrate, stearic acid, palmitic acid, octanoic acid, decanoic acid, polyethylene glycol and derivatives thereof, polyacrylic acid and amino modified polyacrylic acid, 2-mercaptoethanol, starch, as well as mixtures of any two or more thereof.
8. The formulation of claim 6 wherein the amount of capping agent falls in the range of about 1 up to about 40 weight percent of the composition.
9. The formulation of claim 1 wherein the refractive index of said formulation falls in the range of about 1.55 up to about 2.0.
10. The formulation of claim 1 wherein the formulation comprises:
in the range of about 5 up to about 98 wt % of said light stable resin and
in the range of about 2 up to about 95 wt % of said nanoparticles having high refractive index.
11. The formulation of claim 1 further comprising a member selected from the group consisting of flow additives, adhesion promoters, rheology modifiers, toughening agents, film flexibilizers, UV stabilizers, epoxy-curing catalysts, curing agents, photo-initiators, as well as mixtures of any two or more thereof.
12. An assembly comprising a first transparent component and a second transparent component separated only by an aliquot of the formulation of claim 1 .
13. The assembly of claim 12 wherein the aliquot when applied to said first and/or second transparent component has a thickness of about 1 μm up to about 1000 μm.
14. An article comprising a first transparent component and a second transparent component adhered thereto with a cured aliquot of the formulation of claim 1 .
15. A light emitting element wherein at least a light transmitting portion thereof is adhered thereto with a cured aliquot of the formulation of claim 1 .