IP Library Granted Patent US 10,722,755
Granted Patent B1
US 10,722,755 · App. 16/291,290 · Granted Jul 28, 2020

Graphene based golf ball coating

Inventors: Vijay Chavan (Vista, CA); David Bartels (Carlsbad, CA)
Assignee: Callaway Golf Company
A63B37/0022A63B37/0032A63B37/0033A63B37/0039A63B37/0044A63B37/0045A63B37/0092A63B37/0074A63B37/0075A63B37/0076A63B37/0078A63B2037/0079A63B2102/32
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Quick Facts
Patent No.
US 10,722,755
App. No.
16/291,290
Granted
Jul 28, 2020
Kind
B1
Abstract

A golf ball with a coating disposed on a cover that is infused with graphene in an amount ranging from 0.01% to 5% based on a dry weight of the paint film is disclosed herein. The coating is preferably based on polyurethane chemistry where hydroxyl functional polymers are cured with polyisocyanate-based hardeners. The coating is preferably applied in a dipping process or a spraying process.

Claims (45)

1. A golf ball comprising:

a center core

a cover layer disposed over the center core; and

a coating disposed on the cover that is infused with graphene in an amount ranging from 0.01% to 5% based on a dry weight of the coating further comprising an outer core disposed over the center core and the outer core comprises polybutadiene and a graphene material in an amount ranging from 0.4 to 2.5 weight percent of the outer core.

2. The golf ball according to claim 1 wherein the cover has a thickness ranging from 0.025 inch to 0.045 inch.

3. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.025 inch to 0.040 inch, the inner mantle layer composed of an ionomer material, the inner mantle layer material having a plaque Shore D hardness ranging from 65 to 71;

an outer mantle layer disposed over the inner mantle layer, the outer mantle layer having a thickness ranging from 0.070 inch to 0.090 inch;

and

wherein the cover layer is disposed over the outer mantle layer, the cover layer has a thickness ranging from 0.025 inch to 0.040 inch;

wherein the cover layer has a lower Shore D hardness than the outer mantle layer, the outer mantle layer has a higher Shore D hardness than the inner mantle layer, the textured outer core has a higher Shore D hardness than the inner mantle layer and the center core.

4. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.030 inch to 0.090 inch, the inner mantle layer material having a plaque Shore D hardness ranging from 30 to 50;

an outer mantle layer disposed over the inner mantle layer, the outer mantle layer having a thickness ranging from 0.025 inch to 0.070 inch, the outer mantle layer material having a plaque Shore D hardness ranging from 50 to 71, wherein the inner mantle is thicker than the outer mantle and the outer mantle is harder than the inner mantle; and

wherein the cover layer is disposed over the outer mantle layer, the cover layer having a thickness ranging from 0.025 inch to 0.050 inch, wherein the cover layer has a Shore D hardness less than the hardness of the outer mantle layer, wherein the cover layer has a lower Shore D hardness than the outer mantle layer, the outer mantle layer has a higher Shore D hardness than the inner mantle layer, the outer core has a higher Shore D hardness than the inner mantle layer and the center core.

5. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.070 inch to 0.090 inch, the inner mantle layer composed of an ionomer material, the inner mantle layer material having a plaque Shore D hardness ranging from 36 to 44;

an outer mantle layer disposed over the inner mantle layer, the outer mantle layer having a thickness ranging from 0.025 inch to 0.040 inch, the outer mantle layer composed of an ionomer material, the outer mantle layer material having a plaque Shore D hardness ranging from 65 to 71; and

wherein the cover layer is disposed over the outer mantle layer, the cover layer having a thickness ranging from 0.025 inch to 0.040 inch;

wherein the cover layer has a lower Shore D hardness than the outer mantle layer, the outer mantle layer has a higher Shore D hardness than the inner mantle layer, the outer core has a higher Shore D hardness than the inner mantle layer and the center core.

6. The golf ball according to claim 1 further comprising:

an inner mantle layer disposed over the outer core, the inner mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the inner mantle layer material having a plaque Shore D hardness ranging from 30 to 40, the inner mantle layer composed of a composed of an ionomer material;

a first center mantle layer disposed over the inner mantle layer, the first center mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the first center mantle layer material having a plaque Shore D hardness ranging from 40 to 55, the first center mantle layer composed of a fully neutralized polymer material;

a second center mantle layer disposed over the second center mantle layer, the second center mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the second center mantle layer material having a plaque Shore D hardness ranging from 45 to 55, the second center mantle layer composed of a fully neutralized polymer material;

an outer mantle layer disposed over the second center mantle layer, the outer mantle layer having a thickness ranging from 0.030 inch to 0.050 inch, the outer mantle layer composed of a composed of an ionomer material, the outer mantle layer material having a plaque Shore D hardness ranging from 60 to 75; and

wherein the cover layer is disposed over the outer mantle layer, the cover layer having a thickness ranging from 0.025 inch to 0.040 inch.

7. The golf ball according to claim 1 wherein the coating is based on polyurethane chemistry where hydroxyl functional polymers are cured with polyisocyanate-based hardeners.

8. The golf ball according to claim 1 wherein the coating is a two-part coating.

9. The golf ball according to claim 1 wherein the coating is water or solvent based.

10. The golf ball according to claim 1 wherein the coating is applied in multiple layers.

11. The golf ball according to claim 1 wherein the coating is clear or pigmented with titanium dioxide or calcium carbonate.

12. The golf ball according to claim 1 wherein the coating is based on an epoxy amine.

13. The golf ball according to claim 1 wherein the coating is applied in a dipping process or a spraying process.

14. A golf ball comprising:

an inner core;

a outer core comprising a polybutadiene and a graphene material in an amount ranging from 0.4 to 2.5 weight percent of the outer core;

a mantle layer;

a cover;

a coating disposed on the cover that is infused with graphene in an amount ranging from 0.01% to 5% based on a dry weight of the coating.

15. A golf ball comprising:

an inner core comprising a polybutadiene and a graphene material in an amount ranging from 0.4 to 2.5 weight percent of the inner core;

a textured outer core comprising a polybutadiene and a graphene material in an amount ranging from 0.4 to 2.5 weight percent of the outer core;

a mantle layer;

a cover;

a coating disposed on the cover that is infused with graphene in an amount ranging from 0.01% to 5% based on a dry weight of the coating.

Assignments (4)
SECURITY INTEREST Recorded May 17, 2023
From: TOPGOLF CALLAWAY BRANDS CORP.; OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 063692/0009 →
SECURITY AGREEMENT Recorded May 16, 2023
From: TOPGOLF CALLAWAY BRANDS CORP. (FORMERLY CALLAWAY GOLF COMPANY); OGIO INTERNATIONAL, INC.; TOPGOLF INTERNATIONAL, INC.; TRAVISMATHEW, LLC; WORLD GOLF TOUR, LLC
To: BANK OF AMERICA, N.A, AS COLLATERAL AGENT
Reel/Frame 063665/0176 →
SECURITY INTEREST Recorded May 30, 2019
From: CALLAWAY GOLF COMPANY; CALLAWAY GOLF SALES COMPANY; CALLAWAY GOLF BALL OPERATIONS, INC.; OGIO INTERNATIONAL, INC.; CALLAWAY GOLF INTERACTIVE, INC.; CALLAWAY GOLF INTERNATIONAL SALES COMPANY; TRAVISMATHEW, LLC
To: BANK OF AMERICA, N.A.
Reel/Frame 049325/0870 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2019
From: CHAVAN, VIJAY; BARTELS, DAVID
To: CALLAWAY GOLF COMPANY
Reel/Frame 048870/0020 →
Continuity (1)
Provisional Application 62639860 · Mar 7, 2018
Cited By (2)
US 12,515,108 US 12,623,121