Color stable red-emitting phosphors
View Patent ↗A lighting apparatus includes a semiconductor light source in direct contact with a polymer composite comprising a color stable Mn 4+ doped phosphor, wherein the lighting apparatus has a color shift of ≤1.5 MacAdam ellipses after operating for at least 2,000 hour at a LED current density greater than 2 A/cm 2 , a LED wall-plug efficiency greater than 40%, and a board temperature greater than 25° C.
1. A lighting apparatus comprising a semiconductor light source in direct contact with a polymer composite comprising a color stable Mn 4+ doped phosphor, wherein the lighting apparatus has a color shift of ≤1.5 MacAdam ellipses after operating for at least 2,000 hours at a LED current density greater than 2 A/cm 2 , a LED wall-plug efficiency greater than 40%, and a board temperature greater than 25° C. wherein the color stable Mn 4+ doped phosphor is annealed K 2 SiF 6 :Mn 4+ .
2. A lighting apparatus according to claim 1 , wherein the MacAdam ellipse color shift is ≤1.