Granted Patent B2

US 12,347,861 · App. 16/300,701 · Granted Jul 1, 2025

Inventors: Michael Wixom (Ann Arbor, MI); Bob Sosik (Ann Arbor, MI); Pu Zhang (Ann Arbor, MI)

Assignee: Navitas Systems, LLC

H01M4/621H01M4/043H01M4/139

Abstract

Claims (21)

1. A process for forming a free-standing electrochemically active film suitable for use in a cathode comprising:

combining a carbon based processing additive with conductive carbon, and one of an active electrode material suitable for use in a cathode or polytetrafluoroethylene binder to form an electrode precursor material, wherein said processing additive is configured to fibrilize the binder, wherein said processing additive is not activated carbon, and wherein said processing additive comprises a surface roughness and a porosity;

intermixing by blending said electrode precursor material;

combining said electrode precursor material with the other of said polytetrafluoroethylene binder or said active electrode material;

intermixing by blending said polytetrafluoroethylene binder or said active electrode material with said electrode precursor material to form an electrode film material wherein said electrode film material comprises said processing additive, said polytetrafluoroethylene binder and said active electrode material;

wherein said processing additive and said binder are intermixed by high shear mixing such that said processing additive fibrillizes said binder sufficiently to form a free-standing electrode film, and wherein said intermixing is in the absence of a solvent at greater than weight 1%; and

compressing said electrode film material into the free-standing electrode film suitable for use in a cathode.

2. The process of claim 1 , wherein said processing additive and said active electrode material are combined and intermixed to form said electrode precursor material and said electrode precursor material and said polytetrafluoroethylene binder are combined and intermixed to form said electrode film material.

3. The process of claim 1 , wherein said processing additive and said polytetrafluoroethylene binder are combined and intermixed to form said electrode precursor material and said electrode precursor material and said active electrode material are combined and intermixed to form said electrode film material.

4. The process of claim 1 , wherein said electrode film material is absent activated carbon.

5. The process of claim 1 , wherein said processing additive has an average diameter of 1 to 50 μm.

6. The process of claim 1 , wherein said surface roughness of said processing additive comprises a high-porosity surface structure defined by a pore diameter of about 10 nanometers to about 1000 nanometers and a cumulative pore volume of about 0.8 to about 2.5 mL/g.

7. The process of claim 1 , wherein said surface roughness of said processing additive comprises a high-porosity surface structure defined by a pore diameter of about 10 nanometers to about 1000 nanometers and a density of about 1500 to about 2500 kg/m 3 .

8. The process of claim 1 , wherein said electrode film comprises a thickness of 100 micrometers or less.

9. The process claim 8 , wherein said active electrode material is capable of absorbing and desorbing lithium.

10. The process of claim 1 , wherein said active electrode material comprises lithium iron phosphate.

11. The process of claim 1 , wherein said processing additive comprises a graphitized particle.

12. The process of claim 1 , wherein said processing additive is present at a concentration of 40 to 70 weight percent relative to said fibrillizable binder.

13. The process of claim 1 , wherein said processing additive comprises a pyrolized material.

14. The process of claim 1 , wherein said porosity of said processing additive is from about 35 vol % to about 40 vol %.

15. An electrochemical cell comprising an electrode comprising said electrode film of claim 1 .

Assignments (4)

Continuity (2)

References Cited (23)