Polyurea-poly(meth)acrylate interpenetrating polymer network adhesive compositions and methods of using the same
Provided herein are adhesive compositions comprising a polyurea-poly(meth)acrylate interpenetrating polymer network. Further provided are two-part curable adhesive compositions comprising a Part A initiator composition and a Part B activator composition. The Part A initiator composition comprises an organoborane-amine complex and the Part B activator composition comprises an isocyanate that is reactive with the amine portion of the organoborane-amine complex to liberate organoborane from the organoborane-amine complex. Further provided are methods of using an adhesive composition comprising a polyurea-poly(meth)acrylate interpenetrating polymer network, such as, for example, in joining and/or bonding together polyolefin materials (e.g., polypropylene random copolymer (PP-R) pipes).
1. An adhesive system comprising:
a first composition comprising an organoborane-amine complex and at least one amine terminated liquid polymer; and
a second composition comprising at least one polyisocyanate, at least one free radically polymerizable monomer, and at least one compound having at least two free radically polymerizable ethylenically unsaturated groups,
wherein the at least one polyisocyanate is present in the second composition in an amount of about 1% to about 15% by weight of the second composition, the at least one free radically polymerizable monomer is present in the second composition in an amount of about 45% to about 70% by weight of the second composition, and the at least one compound having at least two free radically polymerizable ethylenically unsaturated groups is present in the second composition in an amount of about 1% to about 15% by weight of the second composition.
2. The adhesive system of claim 1 , wherein the organoborane-amine complex is a trialkylborane-amine complex.
3. The adhesive system of claim 2 , wherein the trialkylborane-amine complex is tri-n-butylborane methoxypropylamine.
4. The adhesive system of claim 1 , wherein the at least one amine terminated liquid polymer has a hydrophobic flexible backbone.
5. The adhesive system of claim 1 , wherein the at least one amine terminated liquid polymer is an amine-terminated polybutadiene.
6. The adhesive system of claim 1 , wherein the at least one polyisocyanate is a tri-functional isocyanate.
7. The adhesive system of claim 1 , wherein the at least one free radically polymerizable monomer is an acrylate monomer.
8. The adhesive system of claim 1 , wherein the at least one compound having at least two free radically polymerizable ethylenically unsaturated groups is a multifunctional acrylate monomer, oligomer or polymer.
9. The adhesive system of claim 1 , wherein the at least one compound having at least two free radically polymerizable ethylenically unsaturated groups is methacrylate-terminated polybutadiene.
10. The adhesive system of claim 1 , wherein a reaction between the first composition and the second composition forms at least one elastomeric polymer.
11. The adhesive system of claim 10 , wherein the at least one elastomeric polymer is a styrene-butadiene-styrene block copolymer, an acrylonitrile-butadiene-styrene copolymer, or a combination thereof.
12. A method of bonding a first object and second object comprising:
combining a first composition and a second composition to form an adhesive composition, the first composition comprising an organoborane-amine complex and at least one amine terminated liquid polymer, and the second composition comprising at least one polyisocyanate, at least one free radically polymerizable monomer, and at least one compound having at least two free radically polymerizable ethylenically unsaturated groups, wherein the at least one polyisocyanate is present in the second composition in an amount of about 1% to about 15% by weight of the second composition, the at least one free radically polymerizable monomer is present in the second composition in an amount of about 45% to about 70% by weight of the second composition, and the at least one compound having at least two free radically polymerizable ethylenically unsaturated groups is present in the second composition in an amount of about 1% to about 15% by weight of the second composition;
applying the adhesive composition to at least one surface of the first object and/or the second object; and
curing the adhesive composition to bond the first object and second object together.
13. The method of claim 12 , wherein at least one of the first object and second object comprises a polyolefin.
14. The method of claim 12 , wherein at least one of the first object and second object is a polypropylene random copolymer (PP-R) pipe.