Method of inhibiting reactor fouling and oligomerisation of olefin using the same
Provided are a fouling inhibitor and a method of oligomerizing an olefin using the same. More particularly, in the method of oligomerizing an olefin, it is possible to minimize a total amount of polymers produced during a reaction and basically inhibit fouling of the polymers produced during the reaction onto an inner wall of a reactor by injecting a predetermined fouling inhibitor.
1. A method of oligomerizing an olefin, the method comprising: injecting a fouling inhibitor comprising a petroleum based wax into a reactor; injecting a catalyst composition into the reactor; and injecting the olefin into the reactor to perform an oligomerization reaction,
wherein the petroleum based wax is semi-solid or solid,
wherein the molecular weight of the petroleum based wax is 350 to 1000, and
wherein the petroleum based wax is one or more selected from petroleum jelly, paraffin wax, and microcrystalline wax.
2. The method of claim 1 , wherein the petroleum based wax has a hetero atom ratio of 0.0001 to 0.01 in each molecule.
3. The method of claim 1 , wherein the petroleum based wax is contained in a range of 0.05 to 10 wt % based on a total weight of a medium in the reactor.
4. The method of claim 1 , wherein the catalyst composition contains a main catalyst and a cocatalyst,
the main catalyst being a complex in which a transition metal and a hetero atom ligand represented by the following Chemical Formula 1 are coordinated with each other,
[Chemical Formula 1]
(R 1 ) n A-B-C(R 2 ) m ,
wherein in Chemical Formula 1,
A and C are each independently selected from the group consisting of phosphorus, arsenic, antimony, oxygen, bismuth, sulfur, selenium, and nitrogen,
B is a linking group between A and C,
n and m are each independently integers determined by valences and an oxidation states of A and C, respectively, and
R 1 and R 2 are each independently selected from the group consisting of substituted or unsubstituted hydrocarbyl and substituted or unsubstituted heterohydrocarbyl, R 1 (s) are equal to or different from each other when n≥2, and R 2 (s) are equal to or different from each other when m≥2.
5. The method of claim 4 , wherein B is selected from an organic linking group including substituted or unsubstituted hydrocarbylene and substituted or unsubstituted heterohydrocarbylene; and an inorganic linking group including a single atom link.
6. The method of claim 4 , wherein the hetero atom ligand is represented by the following Chemical Formula 2,
[Chemical Formula 2]
wherein in Chemical Formula 2,
R 11 to R 14 are each independently selected from the group consisting of substituted or unsubstituted hydrocarbyl and substituted or unsubstituted heterohydrocarbyl, and
R 15 and R 16 are each independently substituted or unsubstituted hydrocarbyl, or are linked with each other by substituted or unsubstituted hydrocarbylene or substituted or unsubstituted heterohydrocarbylene to form a ring.
7. The method of claim 4 , wherein the cocatalyst is one or more selected from an organic aluminum compound and an organic boron compound.
8. The method of claim 1 , wherein the performing the oligomerization reaction is performed in a temperature range of 0 to 200° C.
9. The method of claim 1 , wherein the performing the oligomerization reaction is performed in a temperature range of 40 to 100° C.
10. The method of claim 1 , wherein the performing the oligomerization reaction is performed in a pressure range of 1 to 800 bar.
11. The method of claim 1 , wherein the olefin is ethylene, and 1-hexene, 1-octene, or a mixture thereof is selectively prepared.