Polarizer protection film, polarizing plate comprising same, and display provided with same
Disclosed are a protective film for a polarizer with superior optical and mechanical properties, a polarizing plate including the same and a display device including the same.
1. A protective film for a polarizer, which
comprises polyethylene terephthalate (PET),
satisfies the following conditions (1) and (2):
(1) in-plane phase difference (R o )≤350 nm
(2) phase difference in thickness direction (R th )≥6,000 nm,
has a crystallinity of 35% to 55%, and
has a planar orientation coefficient (ΔP) of 0.176 to 0.25.
2. The protective film for a polarizer according to claim 1 , which has a density of 1.3 g/cm 3 to 1.5 g/cm 3 .
3. The protective film for a polarizer according to claim 1 , which has a tensile modulus (85° C.) of 3.0 GPa to 5.0 GPa.
4. The protective film for a polarizer according to claim 1 , which has a difference of a modulus (85° C.) in the width direction (TD) and a modulus (85° C.) in the length direction (MD) of smaller than 0.3 GPa.
5. The protective film for a polarizer according to claim 1 , which has a pencil hardness of 5B or greater.
6. The protective film for a polarizer according to claim 1 , which has an in-plane phase difference (R o ) at the width center of 200 nm or smaller.
7. The protective film for a polarizer according to claim 1 , which has a phase difference in thickness direction (R th ) at the width center of 6,800 nm or greater.
8. The protective film for a polarizer according to claim 1 , which has a ratio (R th /R o ) of the phase difference in thickness direction (R th ) with respect to the in-plane phase difference (R o ) at the width center of 60 or greater.
9. The protective film for a polarizer according to claim 1 , which has a variation of the in-plane phase difference (R o,max −R o,min ) within the effective width of 250 nm/m or smaller.
10. The protective film for a polarizer according to claim 1 , which has a variation of the phase difference in thickness direction (R th,max −R th,min ) within the effective width of 1,500 nm/m or smaller.
11. The protective film for a polarizer according to claim 1 , which experiences a change in the in-plane phase difference with respect to the width change (|ΔR o |/|Δx|) within the effective width of smaller than 0.3 nm/mm.
12. The protective film for a polarizer according to claim 1 , which experiences a change in the phase difference in thickness direction with respect to the width change (|ΔR th |/|Δx|) within the effective width of smaller than 1.5 nm/mm.
13. The protective film for a polarizer according to claim 1 , which has a stretching ratio in the length direction (MD) of 2.8 times to 3.5 times and a stretching ratio in the width direction (TD) of 2.9 times to 3.7 times.
14. The protective film for a polarizer according to claim 1 , which has a ratio (MD/TD) of a stretching ratio in the length direction (MD) with respect to a stretching ratio in the width direction (TD) of 0.9 to 1.1.
15. The protective film for a polarizer according to claim 1 , which has a thickness of 20 μm to 60 μm.
16. The protective film for a polarizer according to claim 1 , which has a heat setting temperature of 160-230° C.
17. A polarizing plate which comprises a polarizer and the protective film for a polarizer according to any one of claims 1 to 16 which is adjacent to at least one of the upper side and the lower side of the polarizer.
18. The polarizing plate according to claim 17 , which further comprises a hard coating layer formed on the protective film and has a pencil hardness of 1H or greater.
19. A display device which comprises a display panel and the polarizing plate according to claim 17 which is disposed on at least one of the upper side and the lower side of the display panel.