High-efficiency strength program used for making paper in higher charge demand system
A method of enhancing paper strength properties is provided. The method comprises treating a paper sheet precursor with a polyaluminum salt, and a strengthening agent, wherein the strengthening agent comprises a dialdehyde-modified polyacrylamide copolymer and a polyacrylamide copolymer. The polyaluminum salt may be polyaluminum chloride. The methods have been demonstrated to provide, among other things, improvements in retention, strength, and dewatering.
1. A method of enhancing paper strength properties, comprising treating a paper sheet precursor with
a polyaluminum salt; and
a strengthening agent,
wherein the strengthening agent comprises a dialdehyde-modified polyacrylamide copolymer and a polyacrylamide copolymer in a molar ratio of from about 10:90 to about 90:10, wherein the dialdehyde-modified polyacrylamide copolymer is a cationic dialdehyde-modified polyacrylamide copolymer, and wherein the polyacrylamide copolymer is an amphoteric polyacrylamide copolymer,
wherein the polyaluminum salt is dosed at about 0.5 kilograms per ton of dry fibers to about 20 kilograms per ton of dry fibers,
wherein the strengthening agent is dosed at about 3 kilograms per ton of dry fibers to about 30 kilograms per ton of dry fibers.
2. The method of claim 1 , wherein the molar ratio of the dialdehyde-modified polyacrylamide copolymer to the polyacrylamide copolymer from about 40:60 to about 60:40.
3. The method of claim 1 , wherein the cationic dialdehyde-modified polyacrylamide copolymer comprises acrylamide and one or more cationic monomer unit(s) derived from a monomer selected from the group consisting of diallyldimethylammonium chloride (“DADMAC”), N-(3-dimethylaminopropyl)methacrylamide, N-(3-dimethylaminopropyl) acrylamide, trimethyl-2-methacroyloxyethylammonium chloride, trimethyl-2-acroyloxyethyl ammonium chloride, methylacryloxyethyldimethyl benzyl ammonium chloride, acryloxyethyldimethyl benzyl ammonium chloride, (3-acrylamidopropyl)trimethyl ammonium chloride, (3-methacrylamidopropyl)trimethylammonium chloride, (3-acrylamido-3-methylbutyl)trimethylammonium chloride, 2-vinylpyridine, 2-(dimethylamino)ethyl methacrylate, 2-(dimethylamino)ethyl acrylate, salts thereof, and combinations thereof.
4. The method of claim 1 , wherein the cationic dialdehyde-modified polyacrylamide copolymer comprises acrylamide and diallyldimethylammonium chloride (“DADMAC”).
5. The method of claim 1 , wherein the dialdehyde-modified polyacrylamide copolymer has been modified with a dialdehyde selected from the group consisting of glyoxal, malondialdehyde, succinic dialdehyde, and glutaraldehyde.
6. The method of claim 5 , wherein the dialdehyde is glyoxal.
7. The method of claim 1 , wherein the amphoteric polyacrylamide copolymer comprises acrylamide and one or more monomer unit(s) derived from a monomer selected from the group consisting of diallyldimethylammonium chloride (“DADMAC”), N-(3-dimethylaminopropyl)methacrylamide, N-(3-dimethylaminopropyl) acrylamide, trimethyl-2-methacroyloxyethylammonium chloride, trimethyl-2-acroyloxyethyl ammonium chloride, methylacryloxyethyldimethyl benzyl ammonium chloride, acryloxyethyldimethyl benzyl ammonium chloride, (3-acrylamidopropyl)trimethyl ammonium chloride, (3-methacrylamidopropyl)trimethylammonium chloride, (3-acrylamido-3-methylbutyl)trimethylammonium chloride, 2-vinylpyridine, 2-(dimethylamino)ethyl methacrylate, 2-(dimethylamino)ethyl acrylate, acrylic acid, methacrylic acid, itaconic acid, maleic acid, maleic anhydride, salts thereof, and combinations thereof.
8. The method of claim 1 , wherein the amphoteric polyacrylamide copolymer comprises acrylamide, diallyldimethylammonium chloride (“DADMAC”), and (meth)acrylic acid.
9. The method of claim 1 , wherein the dialdehyde-modified polyacrylamide copolymer has a weight average molecular weight of from about 100 kDa to about 10,000 kDa.
10. The method of claim 1 , wherein the polyacrylamide copolymer has a weight average molecular weight of from about 100 kDa to about 10,000 kDa.
11. The method of claim 1 , wherein the polyaluminum salt is selected from the group consisting of polyaluminum chloride, polyaluminum sulfate, potassium aluminum sulfate, hydrated potassium aluminum sulfate, aluminum sulfate, and combinations thereof.
12. The method of claim 1 , wherein the polyaluminum salt is polyaluminum chloride.
13. The method of claim 1 , wherein the basicity of the polyaluminum salt is from about 40% to about 83%.
14. The method of claim 1 , wherein the polyaluminum salt and the strengthening agent are combined prior to being delivered to the paper sheet precursor.
15. The method of claim 1 , wherein the polyaluminum salt and the strengthening agent are delivered individually to the paper sheet precursor.
16. The method of claim 1 , wherein the polyaluminum salt and the strengthening agent are delivered simultaneously to the paper sheet precursor.
17. The method of claim 1 , wherein the polyaluminum salt is dosed at about 5 kilograms per ton of dry fibers to about 20 kilograms per ton of dry fibers, wherein the strengthening agent is dosed at about 5 kilograms per ton of dry fibers to about 30 kilograms per ton of dry fibers.
18. A method of enhancing paper strength properties, comprising treating a paper sheet precursor with
a polyaluminum salt; and
a strengthening agent,
wherein the strengthening agent comprises a dialdehyde-modified polyacrylamide copolymer and/or a polyacrylamide copolymer in a molar ratio of from about 10:90 to about 90:10, wherein the dialdehyde-modified polyacrylamide copolymer is a cationic dialdehyde-modified polyacrylamide copolymer, and wherein the polyacrylamide copolymer is an amphoteric polyacrylamide copolymer,
wherein the polyaluminum salt is dosed at about 0.5 kilograms per ton of dry fibers to about 20 kilograms per ton of dry fibers,
wherein the strengthening agent is dosed at about 3 kilograms per ton of dry fibers to about 30 kilograms per ton of dry fibers.