Nonaqueous Electrolyte Secondary Battery
To provide a means capable of suppressing the occurrence of internal short circuit in a power generating element when a battery is destroyed from the outside in a nonaqueous electrolyte secondary battery having a capacity and a size corresponding to a high energy density. Provided is a nonaqueous electrolyte secondary battery which includes a power generating element including a positive electrode fabricated by forming a positive electrode active material layer containing a positive electrode active material on a surface of a positive electrode current collector, a negative electrode fabricated by forming a negative electrode active material layer containing a negative electrode active material on a surface of a negative electrode current collector, and a separator including a resin film and in which a volumetric energy density of the nonaqueous electrolyte secondary battery is 350 Wh/L or more and there is at least one direction having a tensile yield strength of 14 MPa or less at normal temperature, a tensile elongation at break of 100% or more at normal temperature, and a thermal shrinkage of 10% or less at the time of heating at 150° C. for 1 hour in a plane direction of the separator.
1 . A nonaqueous electrolyte secondary battery comprising a power generating element including:
a positive electrode fabricated by forming a positive electrode active material layer containing a positive electrode active material on a surface of a positive electrode current collector,
a negative electrode fabricated by forming a negative electrode active material layer containing a negative electrode active material on a surface of a negative electrode current collector, and
a separator including a resin film, wherein
a volumetric energy density of the nonaqueous electrolyte secondary battery is 350 Wh/L or more, and
there is at least one direction having a tensile yield strength of 14 MPa or less at normal temperature, a tensile elongation at break of 100% or more at normal temperature, and a thermal shrinkage of 10% or less at the time of heating at 150° C. for 1 hour in a plane direction of the separator.
2 . The nonaqueous electrolyte secondary battery according to claim 1 , wherein the separator has a layered structure of the resin film and a heat resistant insulating layer.
3 . The nonaqueous electrolyte secondary battery according to claim 1 or 2 , wherein a constituent of the resin film is polypropylene and/or polyethylene.
4 . The nonaqueous electrolyte secondary battery according to any one of claims 1 to 3 , wherein air permeability of the separator is 300 sec/100 cc or less as a Gurley value.
5 . The nonaqueous electrolyte secondary battery according to any one of claims 1 to 4 , wherein a thickness of the separator is from 8 to 35 μm.
6 . The nonaqueous electrolyte secondary battery according to any one of claims 1 to 5 , wherein the resin film has a three-layer structure and a thickness of a central layer of the three-layer structure is from 3 to 9 μm.
7 . The nonaqueous electrolyte secondary battery according to any one of claims 1 to 6 , wherein a ratio of a rated capacity to a pore volume of the separator is 1.9 Ah/cc or more, a ratio of a battery area to a rated capacity is 10 cm 2 /Ah or more, and a variation in porosity in the separator is 2% or less.
8 . The nonaqueous electrolyte secondary battery according to any one of claims 1 to 7 , wherein the positive electrode active material is a lithium composite oxide having a composition to be represented by a general formula: Li a Ni b M c Co d O 2 (where a, b, c and d satisfy 0.9≤a≤1.2, 0<b<1, 0<c≤0.5, 0<d≤0.5, and b+c+d=1, and M is at least one kind selected from the group consisting of Mn, Ti, Zr, Nb, W, P, Al, Mg, V, Ca, Sr and Cr).
9 . The nonaqueous electrolyte secondary battery according to any one of claims 1 to 8 , wherein the nonaqueous electrolyte secondary battery is a flat stacked type laminate battery comprising the power generating element enclosed in a battery exterior packaging body including a laminate film containing aluminum.