IP Library Granted Patent US 11,352,554
Granted Patent B2
US 11,352,554 · App. 16/313,299 · Granted Jun 7, 2022

Photochromic water harvesting platform

Inventors: John C. Warner (Wilmington, MA); Srinivasa R. Cheruku (Lexington, MA); Sofia Trakhtenberg (Newton, MA)
Assignee: Warner Babcock Institute for Green Chemistry, LLC
C09K9/02E03B3/28C07D491/107C09K2211/1466Y02A20/00
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Quick Facts
Patent No.
US 11,352,554
App. No.
16/313,299
Granted
Jun 7, 2022
Kind
B2
Abstract

The application discloses compounds, compositions, films and devices comprising the compounds and compositions, and their methods of use for harvesting water.

Claims (16)

1. A method for the condensation of water on a surface of a film deposited on a surface of a device, comprising:

exposing the device comprising photoactive, thermally or electrically-active or a combination of a photoactive, thermally active and/or electrically-active film, wherein the film comprises a compound having a ground state that reversibly converts to its activated state upon exposure to light, heat or an electric field, or a combination of light, heat and/or electric field, wherein the activated state of the compound is more polar than the ground state of the compound;

wherein the device is exposed for a sufficient period of time to condense moisture on or capture and adhere water droplets on the surface of the film; and

continuously collecting the water formed or collected on the surface of the device.

2. The method of claim 1 , wherein the compound is of the formula I:

wherein:

m is 0, 1, 2, 3 or 4;

n is 0, 1, 2, 3 or 4;

R is H or is selected from the group consisting of substituted or unsubstituted C 1-22 alkyl, substituted or unsubstituted C 6-10 aryl, substituted or unsubstituted alkyl-C 6-10 aryl, substituted or unsubstituted C 1-22 alkylC(O)—, substituted or unsubstituted C 1-22 alkylS(O) 1-2 —, substituted or unsubstituted C 1-22 alkylNR′C(O)— and substituted or unsubstituted C 1-22 alkoxyC(NR″)—, or a polymer;

each X is independently H or is selected from the group consisting of halo, —CN, —NO 2 , —COOH, —SH, —OH, substituted or unsubstituted C 1-6 alkyl, substituted or unsubstituted C 6-10 aryl, substituted or unsubstituted —C 1-6 alkyl-C 6-10 aryl, substituted or unsubstituted —C 1-6 alkylC(O)—, substituted or unsubstituted —C 1-6 alkylS(O) 1-2 —, substituted or unsubstituted —C 1-6 alkylNR′C(O)— and substituted or unsubstituted C 1-6 alkoxyC(NR″)—;

each Y is independently H or is selected from the group consisting of halo, —CN, —NO 2 , —COOH, —SH, —OH, substituted or unsubstituted C 1-6 alkyl, substituted or unsubstituted C 6-10 aryl, substituted or unsubstituted —C 1-6 alkyl-C 6-10 aryl, substituted or unsubstituted C 1-6 alkylC(O)—, substituted or unsubstituted C 1-6 alkylS(O) 1-2 —, substituted or unsubstituted C 1-6 alkylNR′C(O)— and substituted or unsubstituted C 1-6 alkoxyC(NR″)—;

Z is —O—, —S—, —C(O)—, —C(S)—, —C(NR′)—, —S(O) 1-2 —, —NR′— and —CR′R″—; and

R′ and R″ are each independently selected from the group consisting of H, substituted or unsubstituted C 1-6 alkyl and substituted and unsubstituted —C 1-6 alkyl-C 6-10 aryl.

3. The method of claim 1 , wherein R is a polymer deposited on the surface of the device.

4. The method of claim 3 , wherein the polymer is selected from the group consisting of polyethylene (LDPE or HDPE), polypropylene, poly(vinyl chloride), poly(vinylidene chloride), polystyrene, polyacrylonitrile, polytetrafluoroethylene (PTFE, Teflon), poly(methyl methacrylate) (PMMA), poly(vinyl acetate) (PVAc), polyisoprene, polychloroprene, poly(oxyethylene) (POE), poly(oxy-1,2-ethanediyloxycarbonyl-1,4-phenylenecarbony (PET), poly[amino(1-oxo-1,6-hexanediyl)], polystyrene, ethyl-vinyl-acetate (EVA), polylactide (PLA), polyhydroxyalkanoates (PHA), polyhydroxybutyrate (PHB), poly-L-lactide (PLLA), PDLA (poly-D-lactide) or mixtures thereof.

5. The method of claim 1 , wherein the device is configured for harvesting water from humid air and/or fog.

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 16, 2023
From: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY LLC
To: MIST MINER, INC.
Reel/Frame 065234/0303 →
RELEASE OF SECURITY INTEREST Recorded Apr 21, 2022
From: CTHULHU VENTURES LLC
To: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY, LLC
Reel/Frame 059670/0045 →
RELEASE OF SECURITY INTEREST Recorded Apr 21, 2022
From: BABCOCK, JAMES V.
To: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY, LLC
Reel/Frame 059672/0048 →
SECURITY INTEREST Recorded Mar 25, 2021
From: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY, LLC
To: CTHULHU VENTURES LLC
Reel/Frame 055732/0383 →
SECURITY INTEREST Recorded Mar 25, 2021
From: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY, LLC
To: BABCOCK, JAMES V.
Reel/Frame 055732/0403 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 10, 2019
From: WARNER, JOHN C.; CHERUKU, SRINIVASA R.; TRAKHTENBERG, SOFIA
To: WARNER BABCOCK INSTITUTE FOR GREEN CHEMISTRY, LLC
Reel/Frame 047951/0449 →
Continuity (2)
Provisional Application 62353925 · Jun 23, 2016
Related Publication 20190153306A1 · May 23, 2019