Micro alloyed steel and method for producing said steel
The invention deals with Steel for seamless pipes comprising the following chemical composition elements in weight percent: 0.04≤C≤ to 0.18, 0.10≤Si≤0.60, 0.80≤Mn≤1.90, P≤0.020, S≤0.01, 0.01≤Al≤0.06, 0.50≤Cu≤1.20, 0.10≤Cr≤0.60, 0.60≤Ni≤1.20, 0.25≤Mo≤0.60, B≤0.005, V≤0.060, Ti≤0.050, 0.010≤Nb≤0.050, 0.10≤W≤0.50, N≤0.012, where the balance is Fe and inevitable impurities. The steel of the invention can be used in offshore applications, line process pipes, structural and mechanical applications, especially where harsh environmental conditions and service temperatures down to −80° C. occur.
1. Steel for seamless pipes, comprising, in weight percent:
0.04≤C≤ to 0.18,
0.10≤Si≤0.60,
0.80≤Mn≤1.90,
P≤0.020,
S≤0.01,
0.01≤Al≤0.06,
0.50≤Cu≤1.20,
0.10≤Cr ≤0.60,
0.60≤Ni≤1.20,
0.25≤Mo≤0.60,
B≤0.005,
V≤0.060,
Ti≤0.010,
0.010≤Nb≤0.050,
0.10≤W≤0.50,
N≤0.012,
Fe and
inevitable impurities.
2. The steel according to claim 1 , wherein C is between 0.04% and 0.12%.
3. The steel according to claim 1 , wherein C is between 0.05% and 0.08%.
4. The steel according to claim 1 , wherein Mn is between 1.15% and 1.60%.
5. The steel according to claim 1 , wherein Cu is between 0.60% and 1%.
6. The steel according to claim 1 , wherein Mo is between 0.35% and 0.50%.
7. The steel according to claim 1 , wherein W is between 0.10% and 0.30%.
8. The steel according to claim 1 , wherein V is below 0.008%.
9. The steel according to claim 1 , wherein a weight ratio of carbon to manganese satisfies: 0.031≤C/Mn≤0.070.
10. The steel according to claim 1 , wherein in weight percent:
CE IIW ≤0.65% and CE Pcm ≤0.30%
where
CE IIW =C+Mn/6+(Cr+Mo+V)/5+(Ni+Cu)/15 and applies when C>0.12%, and
CE Pcm =C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B and applies when C≤0.12%.
11. The steel according to claim 1 , which has a microstructure comprising less than 15% of ferrite, the balance being bainite and martensite.
12. The steel according to claim 1 , which has an average yield strength of 550 MPa to 890 MPa, and a toughness in joules at −60° C. of at least 10% of the yield strength.
13. The steel according to claim 1 , which has an average yield strength of at least 690 MPa, and an average toughness at −80° C. of at least 69 J.
14. A method of producing a seamless steel pipe, the method comprising:
hot forming the steel according to claim 1 at a temperature of 1100° C. to 1280° C. to obtain a pipe,
then, heating the pipe to an austenitizing temperature AT above or equal to 890° C. and keeping the pipe at the austenitizing temperature AT for 5 to 30 minutes followed by cooling the pipe to an ambient temperature to obtain a quenched pipe, and
then, heating the quenched pipe to a tempering temperature TT of 580° C. to 700° C. and keeping the pipe at the tempering temperature TT for a tempering time Tt of 20 to 60 minutes followed by cooling the pipe to the ambient temperature to obtain a quenched and tempered pipe.
15. A structural and/or mechanical component, made of the steel according to claim 1 .
16. A line pipe component and/or an oil and gas accessory, made of the steel according to claim 1 .
17. Steel for seamless pipes, comprising, in weight percent:
0.04≤C≤ to 0.18,
0.10≤Si≤0.60,
0.80≤Mn≤1.90,
P≤0.020,
S≤0.01,
0.01≤Al≤0.06,
0.50≤Cu≤1.20,
0.10≤Cr ≤0.60,
0.60≤Ni≤1.20,
0.25≤Mo≤0.60,
B≤0.005,
V≤0.060,
Ti≤0.050,
0.010≤Nb≤0.050,
0.10≤W≤0.30,
N≤0.012,
Fe and
inevitable impurities.
18. The steel according to claim 17 , wherein Ti is below or equal to 0.010%.
19. The steel according to claim 17 , wherein C is between 0.04% and 0.12%.
20. The steel according to claim 17 , wherein C is between 0.05% and 0.08%.