ELECTRICAL COMPONENT AND METHOD
A subsea electrical connector or electrical cable having a conductor, an insulator coaxial with the conductor; and at least one of a volumetric compensating diaphragm located radially outwardly of the insulator, or a termination boot. The diaphragm or termination boot has a compound layer, the compound layer includes a graphene nano-platelet additive incorporated into a cross-linked polymer matrix to produce a polymer composite.
1 . A subsea electrical connector or electrical cable, comprising:
a conductor,
an insulator coaxial with the conductor; and
at least one of a volumetric compensating diaphragm located radially outwardly of the insulator, or a termination boot;
wherein the diaphragm or termination boot comprises a compound layer, the compound layer comprising a graphene nano-platelet additive incorporated into a cross-linked polymer matrix to produce a polymer composite.
2 . The subsea electrical connector or electrical cable according to claim 1 ,
wherein the subsea electrical connector or electrical cable comprises both a termination boot and a volumetric compensating diaphragm.
3 . The subsea electrical connector or electrical cable according to claim 1 ,
wherein a proportion of graphene nano-platelet additive expressed in parts per hundred rubber (PHR) is between 0.1 and 5.0.
4 . The subsea electrical connector or electrical cable according to claim 3 ,
wherein the proportion of graphene nano-platelet additive PHR is between 0.1 and 1.0.
5 . The subsea electrical connector or electrical cable according to claim 1 ,
wherein the compound layer is in physical contact with at least part of the insulator.
6 . The subsea electrical connector or electrical cable according to claim 4 ,
wherein the compound layer forms a sealed chamber containing an insulating liquid.
7 . The subsea electrical connector or electrical cable according to claim 4 ,
wherein the cross-linked polymer matrix comprises an elastomer.
8 . The subsea electrical connector or electrical cable according to claim 7 ,
wherein the elastomer comprises one of styrene-butadiene rubber, nitrile rubber, hydrogenated nitrile rubber, chloroprene rubber, ethylene propylene diene rubber, fluoro elastomers, perfluoro elastomers, silicone rubber, or fluoro silicone rubber.
9 . A method of manufacturing a component of a subsea electrical connector, or electrical cable according to claim 1 , the component comprising a volumetric compensating diaphragm, or a termination boot, the method comprising:
creating a compound layer of the component by determining proportions of graphene nano-platelets and a cross-linked polymer matrix for the component;
incorporating the graphene nano-platelets into the cross-linked polymer matrix in the determined proportions to produce a polymer composite; and
forming the component from the polymer composite.
10 . The method according to claim 9 , further comprising:
aligning the graphene nano-platelets in the same direction, perpendicular to a diffusion path of water through the component.
11 . The method according to claim 9 , further comprising:
moulding an elastomer through a transfer moulding process by transferring the polymer composite into a mould cavity under pressure through a small orifice to induces a high shear rate on the compound.
12 . The method according to claim 9 , further comprising:
providing a cure system in the polymer composite and applying thermal treatment to the polymer composite, causing the polymer to cross-link, to form the component.
13 . The method according to claim 9 ,
wherein a proportion of graphene nano-platelet additive is between 0.1 PHR and 5.0 PHR.
14 . The method according to claim 13 ,
wherein the proportion of graphene nano-platelet additive is between 0.1 PHR and 1.0 PHR.
15 . The method according to claim 9 ,
wherein a desired maximum leakage rate is chosen and a corresponding proportion of graphene nano platelets is determined for the polymer matrix by extracting values from a store.
16 . A method of manufacturing a subsea electrical connector, or electrical cable, the method comprising:
manufacturing a component of a subsea electrical connector or electrical cable by a method according to claim 9 ; and
coupling the component to an insulating layer of the subsea electrical connector, or electrical cable.
17 . A method of manufacturing a subsea electrical connector, or electrical cable, the method comprising:
manufacturing a component of a subsea electrical connector or electrical cable by a method according to claim 9 ,
wherein the forming comprises over-moulding the polymer composite onto an insulating layer, or co-extruding the polymer composite with the insulating layer of the subsea electrical connector or electrical cable.
18 . The subsea electrical connector or electrical cable according to claim 3 ,
wherein the proportion of graphene nano-platelet additive PHR is between 0.1 and 0.5
19 . The subsea electrical connector or electrical cable according to claim 3 ,
wherein the proportion of graphene nano-platelet additive PHR is between 0.5 and 1.0.
20 . The method according to claim 13 ,
wherein the proportion of graphene nano-platelet additive is between 0.2 PHR and 0.5 PHR
21 . The method according to claim 13 ,
wherein the proportion of graphene nano-platelet additive is between 0.5 PHR and 1.0 PHR.