Fiber reinforcing polymer composite and articles made therefrom
Pultruded fiber reinforced polymer composite is disclosed, having a blend of conventional pultrusion resins and a rigidsol. The replacement of some of the conventional pultrusion resin with the rigidsol does not adversely affect mechanical properties but does enhance affinity of the pultruded part to a polyvinyl chloride-containing capstock.
1. A fiber reinforcing polymer composite, comprising:
(a) reinforcing fiber
(b) rigidsol having a Brookfield viscosity (ASTM D1824 25° C., 20 rpm) of about 1200—3000 centipoise, and
(c) isophthalic polyester resin,
wherein the reinforcing fiber is pultruded through the rigidsol and the isophthalic polyester resin.
2. The composite, according to claim 1 , wherein the rigidsol, when fused as a resin, has
(1) a Shore D hardness (ASTM D2240-02 after 15 seconds) of more than 60,
(2) a Tensile Strength (ASTM D638) of more than about 48 MPa,
(3) a Percent Elongation (ASTM D638) of less than 10%.
3. The composite of claim 1 , wherein the reinforcing fiber is selected from the group consisting of glass, steel, carbon, polyaramide, silica carbide, quartz, cellulose, jute, hemp, sisal, basalt, and combinations thereof.
4. The composite of claim 3 , wherein the glass fiber is selected from the group consisting of being S-2 glass, S-1 glass, ECR glass, A-R glass, D glass, R glass, E glass, and combinations thereof.
5. The composite of claim 1 , wherein the diameter of each reinforcing fiber ranges from about 13 μm to about 35 μm.
6. The composite of claim 1 , wherein the reinforcing fiber has
(a) a yield for each roving of fibers ranging from about 52 yield to about 1650 yield;
(b) a tensile strength (ASTM D2343) ranging from about 300 to about 450 Kilopounds per square inch;
(c) a tensile Modulus (ASTM D2343) ranging from about 10 to about 12 Megapounds per square inch; and
(d) a tensile Strain (ASTM D2343) ranging from about 2% to about 4%.
7. The composite of claim 1 , wherein the composite further comprises heat stabilizers, UV absorbers, fillers, release agents, biocides, pigments, or combinations thereof.
8. The composite of claim 1 , wherein the composite comprises 60-70 weight percent of reinforcing fiber, 20-30 weight percent of rigidsol, and 5-7 weight percent of isophthalic polyester resin.
9. A pultruded article shaped from the composite of claim 1 .
10. The pultruded article of claim 9 laminated to a sheet containing polyvinyl chloride.
11. A laminate of an article of the composite of claim 1 and a sheet containing polyvinyl chloride, wherein the sheet is a capstock to the article.
12. The laminate of claim 11 , wherein the article is pultruded into a building material.
13. The laminate of claim 12 , wherein the building material is selected from the group consisting of wall studs, truss supports, beams, parts of windows, parts of doors, fascia, siding, trim, decking, fencing, and ornamental non-load-bearing appurtenances.
14. A building material made of a laminate of claim 11 .