Near-infrared absorbing fine particle dispersion liquid, near-infrared absorbing fine particle dispersion body, near-infrared absorbing transparent substrate, near-infrared absorbing laminated transparent substrate
There is provided a near-infrared absorbing fine particle dispersion liquid containing near-infrared absorbing fine particles, thereby as well as exhibiting near-infrared light absorption properties and suppressing a scorching sensation on the skin when used in structures such as window materials and the like, also enabling usage of communication devices, imaging devices, sensors and the like that employ near-infrared light through these structures, a near-infrared absorbing film or a near-infrared absorbing glass, a dispersion body or a laminated transparent substrate, the dispersion liquid containing at least composite tungsten oxide fine particles and antimony doped tin oxide fine particles and/or tin doped indium oxide fine particles as near-infrared absorbing fine particles, wherein in the composite tungsten oxide fine particles, an average value of a transmittance in a wavelength range of 800 to 900 nm is 30% or more and 60% or less, and an average value of a transmittance in a wavelength range of 1200 to 1500 nm is 20% or less, and a transmittance at a wavelength of 2100 nm is 22% or less, when a visible light transmittance is 85% at the time of calculating only light absorption by the composite tungsten oxide fine particles, and containing mixed particles of the composite tungsten oxide fine particles and antimony-doped tin oxide fine particles and/or tin-doped indium oxide fine particles dispersed in a liquid medium, wherein the liquid medium is selected from rater, an organic solvent, an oil and fat, a liquid resin, a liquid plasticizer for plastics, or a mixture thereof, wherein when a visible light transmittance is adjusted to 85% at the time of calculating only light absorption by the near-infrared absorbing fine particles in the dispersion liquid by diluting with the liquid medium, an average value of a transmittance in the wavelength range of 800 to 900 nm is 30% or more and 60% or less, an average value of a transmittance in the wavelength range of 1200 to 1500 nm is 20% or less, and a transmittance at the wavelength of 2100 nm is 11% or less.
1. A near-infrared absorbing fine particle dispersion body comprising:
a solid binder; and
mixed particles of at least (i) composite tungsten oxide fine particles, and (ii) antimony-doped tin oxide fine particles and/or tin-doped indium oxide fine particles, the mixed particles being dispersed in the solid binder,
wherein:
the composite tungsten oxide fine particles have, when a visible light transmittance is 85% at the time of calculating only light absorption by the composite tungsten oxide fine particles:
an average value of a transmittance in a wavelength range of 800 to 900 nm of 30% or more and 60% or less,
an average value of a transmittance in a wavelength range of 1200 to 1500 nm of 20% or less, and
a transmittance at a wavelength of 2100 nm of 22% or less,
the composite tungsten oxide fine particles have a dispersed particle size of 25 nm or less, and
a c-axis lattice constant of the composite tungsten oxide fine particles is 7.6073 Å or more and 7.6095 Å or less.
2. The near-infrared absorbing fine particle dispersion body according to claim 1 , wherein the binder comprises at least a thermoplastic resin or a UV curable resin.
3. The near-infrared absorbing fine particle dispersion body according to claim 2 , wherein the transparent thermoplastic resin is any one of:
one resin selected from a resin group consisting of polyethylene terephthalate resin, polycarbonate resin, acrylic resin, styrene resin, polyamide resin, polyethylene resin, vinyl chloride resin, olefin resin, epoxy resin, polyimide resin, fluororesin, ethylene-vinyl acetate copolymer, and polyvinyl acetal resin, or
a mixture of two or more resins selected from the above resin group, or
a copolymer of two or more resins selected from the above resin group.
4. The near-infrared absorbing fine particle dispersion body according to claim 1 , containing the near-infrared absorbing fine particles in an amount of 0.001 mass % or more and 80.0 mass % or less.
5. The near-infrared absorbing fine particle dispersion body according to claim 1 , wherein the near-infrared absorbing fine particle dispersion body is formed in a sheet shape, a board shape, or a film shape.
6. The near-infrared absorbing fine particle dispersion body according to claim 1 , wherein a content of the near-infrared absorbing fine particles per unit projected area contained in the near-infrared absorbing fine particle dispersion body is 0.04 g/m 2 or more and 10.0 g/m 2 or less.
7. The near-infrared absorbing fine particle dispersion body according to claim 1 , having a transmittance profile in which, when a visible light transmittance is adjusted to 70%:
an average value of a transmittance in a wavelength range of 800 to 900 nm of 13% or more and 42% or less,
an average value of a transmittance in a wavelength range of 1200 to 1500 nm of 8% or less, and
a transmittance at a wavelength of 2100 nm of 5% or less.
8. A near-infrared absorbing transparent substrate, comprising the near-infrared absorbing fine particle dispersion body according to claim 1 formed on at least one surface of a transparent substrate which is a resin substrate or a glass substrate.
9. The near-infrared absorbing transparent substrate according to claim 8 , wherein a thickness of the near-infrared absorbing fine particle dispersion body is 10 μm or less.
10. The near-infrared absorbing transparent substrate according to claim 8 , wherein the transparent substrate is the resin substrate and the resin substrate is a polyester film.
11. The near-infrared absorbing transparent substrate according to claim 8 having a transmittance profile in which, when the substrate has a thickness of 1.0 mm and a visible light transmittance is adjusted to 70%:
an average value of a transmittance in a wavelength range of 800 to 900 nm is 12% or more and 40% or less,
an average value of a transmittance in a wavelength range of 1200 to 1500 nm is 8% or less, and
a transmittance at a wavelength of 2100 nm is 3.0% or less.
12. A near-infrared absorbing laminated transparent substrate, comprising the near-infrared absorbing fine particle dispersion body of claim 1 present between a plurality of transparent substrates.
13. The near-infrared absorbing laminated transparent substrate according to claim 12 having a transmittance profile in which, when the near-infrared absorbing fine particle dispersion body has a thickness of 0.7 mm and a visible light transmittance is adjusted to 70%:
an average value of a transmittance in a wavelength range of 800 to 900 nm is 12% or more and 40% or less,
an average value of a transmittance in a wavelength range of 1200 to 1500 nm is 8% or less, and
a transmittance at a wavelength of 2100 nm is 3.0% or less.