Phenol alkylation catalyst precursor and catalyst, method of forming catalyst, method of regenerating catalyst, and method of alkylating phenol
A phenol alkylation catalyst exhibiting a desirable combination of activity, selectivity, and regenerability is prepared from a catalyst precursor that includes specific amounts of magnesium oxide, copper oxide or a copper oxide precursor, a hydrous magnesium aluminosilicate-containing binder, a pore-former, a lubricant, and water. Methods of forming and regenerating the catalyst, as well as a phenol alkylation method, are described.
1. A catalyst precursor comprising, based on the total weight of the catalyst precursor:
70 to 98 weight percent of magnesium oxide;
0.1 to 2 weight percent of copper oxide or a copper oxide precursor;
0.5 to 8 weight percent of a binder comprising a hydrous magnesium aluminosilicate;
1 to 15 weight percent of a pore-former;
0.2 to 5 weight percent of a lubricant; and
0.2 to 15 weight percent of water;
wherein the magnesium oxide has a Brunauer-Emmett-Teller surface area of at least 70 meter 2 /gram.
2. The catalyst precursor of claim 1 , having an unpacked density of 1.2 to 2 grams per milliliter at 23° C.
3. The catalyst precursor of claim 1 , wherein the copper oxide or a copper oxide precursor comprises cupric oxide, cupric nitrate, cuprous carbonate, a hydrate of one of the foregoing, or a combination thereof.
4. The catalyst precursor of claim 1 , wherein the pore-former comprises polyethylene glycol.
5. The catalyst precursor of claim 1 , wherein the lubricant comprises graphite, magnesium stearate, or a combination thereof.
6. The catalyst precursor of claim 1 , comprising
75 to 95 weight percent of the magnesium oxide;
0.2 to 1 weight percent of the copper oxide or copper oxide precursor;
1 to 6 weight percent of the binder comprising a hydrous magnesium aluminosilicate;
2 to 10 weight percent of the pore-former;
0.4 to 3.5 weight percent of the lubricant; and
0.6 to 12 weight percent of the water.
7. A method of forming a phenol alkylation catalyst, the method comprising:
exposing the catalyst precursor of claim 1 to a nitrogen gas flow having a weight hourly space velocity of 0.05 to 0.8 hour −1 , wherein the nitrogen gas flow has a temperature of 350 to 550° C. and is conducted for a time of 5 to 30 hours, and wherein the temperature of the nitrogen gas flow is increased to the temperature of 350 to 550° C. at a rate of 0.5 to 5° C./minute.
8. A phenol alkylation catalyst prepared by a method comprising:
exposing the catalyst precursor of claim 1 to a nitrogen gas flow having a weight hourly space velocity of 0.05 to 0.8 hour −1 , wherein the nitrogen gas flow has a temperature of 350 to 550° C. and is conducted for a time of 5 to 30 hours, and wherein the temperature of the nitrogen gas flow is increased to the temperature of 350 to 550° C. at a rate of 0.5 to 5° C./minute;
wherein the phenol alkylation catalyst exhibits a crush strength of 1 to 20 Newtons/millimeter, determined according to ASTM D4179-11.
9. A method of regenerating the phenol alkylation catalyst of claim 8 , the method comprising:
exposing the phenol alkylation catalyst to a first gas flow having a weight hourly space velocity of 0.05 to 0.8 hour −1 , a temperature of 410 to 440° C., and a pressure of 25 to 400 kilopascals, wherein the gas flow comprises nitrogen;
exposing the phenol alkylation catalyst to a second gas flow having a weight hourly space velocity of 0.05 to 0.8 hour −1 , a temperature of 10 to 50° C. greater than the temperature of the first gas flow, and a pressure of 25 to 400 kilopascals, wherein the gas flow comprises nitrogen.
10. A method of alkylating phenol, the method comprising:
reacting phenol with a C 1 -C 6 alkanol in the presence of a phenol alkylation catalyst formed by a method comprising:
exposing the catalyst precursor of claim 1 to a nitrogen gas flow having a weight hourly space velocity of 0.05 to 0.8 hour −1 , wherein the nitrogen gas flow has a temperature of 350 to 550° C. and is conducted for a time of 5 to 30 hours, and wherein the temperature of the nitrogen gas flow is increased to the temperature of 350 to 550° C. at a rate of 0.5 to 5° C./minute.
11. The method of claim 10 , wherein the C 1 -C 6 alkanol comprises methanol, said reacting phenol with a C 1 -C 6 alkanol is characterized by a feed weight hourly space velocity of 0.5 to 10 hour −1 , a pressure of 50 to 500 kilopascals, a molar ratio of C 1 -C 6 alkanol to phenol of 2:1 to 10:1, and a temperature of 450 to 490° C.