Colloidal stabilizer effective at low concentrations
This invention relates to making and using a stabilizer that is effective in small amounts and, particularly useful for stabilizing low solids liquids, e.g., dispersions, emulsions, and suspensions, used in foods, pharmaceuticals, nutraceuticals, and similar industrial applications, which comprises, microcrystalline cellulose, (preferably, colloidal hydrolyzed MCC); a first carboxymethyl cellulose having a viscosity of 30-85 cP at 2% in deionized water; and, a degree of carboxymethyl substitutions of 0.60 to 0.85, and a second carboxymethyl cellulose having a viscosity of 400-800 cP at 2% in deionized water, and a degree of carboxymethyl substitutions of 0.80 to 0.95; and, the stabilizer may be made by preparing a moist MCC “wetcake”; thoroughly mixing the wetcake with a dry blended mixture of low DS and medium DS, CMCs; preferably, in a MCC/low DS CMC/medium DS CMC ratio range of about 88/6/6 to about 92/4/4, adding that mixture to an extruder; preparing a slurry of the extrudate in deionized water; and, optionally, pumping the slurry to a spray dryer to produce a powder.
1. A colloidal MCC stabilizer, comprising:
i) hydrolyzed colloidal microcrystalline cellulose;
ii) low DS carboxymethyl cellulose having a viscosity of 30-85 cP in 2% deionized water, measured with a Brookfield RV viscometer at room temperature and 60 rpm, and a DS of about 0.60 to about 0.85; and,
iii) medium DS carboxymethyl cellulose having a viscosity of 400-800 cP in 2% deionized water, measured with a Brookfield RV viscometer at room temperature and 30 rpm, and a DS of about 0.80 to about 0.95,
wherein the weight ratio of microcrystalline cellulose/low DS carboxymethyl cellulose/medium DS carboxymethyl cellulose is in the range of from about 92/4/4 to about 88/6/6.
2. The colloidal MCC stabilizer of claim 1 , wherein the weight ratio of microcrystalline cellulose/low DS carboxymethyl cellulose / medium DS carboxymethyl cellulose is selected from the group consisting of 92/4/4, 90/5/5, and 88/6/6.
3. The colloidal MCC stabilizer of claim 1 , wherein the weight ratio of microcrystalline cellulose/low DS carboxymethyl cellulose/medium DS carboxymethyl cellulose is 88/6/6.
4. The colloidal MCC stabilizer of claim 1 , wherein the carboxymethyl cellulose are in sodium, ammonia or potassium salt form.
5. The colloidal MCC stabilizer of claim 1 , wherein the low and medium DS carboxymethyl cellulose are in sodium salt form.
6. The colloidal MCC stabilizer of claim 1 , wherein the medium DS carboxymethyl cellulose is not more than 8% wt. of the stabilizer.
7. The colloidal MCC stabilizer of claim 1 , wherein the weight ratio of the microcrystalline cellulose to the sum of the low and medium DS carboxymethyl celluloses is from about 88:12 to 92:8.
8. A beverage product comprising the stabilizer of claim 1 .
9. A beverage product of claim 8 , selected from the group consisting of chocolate dairy milk beverage containing cocoa; almond beverage containing finely ground almond; fortified calcium milk containing insoluble calcium salts; and chocolate soy beverage containing cocoa.
10. A beverage product of claim 8 comprising dairy milk, wherein the milk is selected from the group consisting of: Pasteurized milk; Retort milk; UHT milk; Full Cream milk; Hi-Calcium milk, Low Fat milk; Strawberry-flavored milk; and Chocolate-flavored milk.
11. A beverage product of claim 8 wherein the beverage product is a plant protein beverage comprising at least one milk selected from the group consisting of:
Almond milk; Soy milk; Peanut milk; Coconut milk; and Walnut milk.
12. The colloidal MCC stabilizer of claim 1 , wherein the low DS CMC and medium DS CMC comprise 8 to 12% wt. of the stabilizer.
13. The beverage product of claim 8 , wherein the stabilizer comprises 0.05% wt. to 3.5% wt. of total product.
14. The beverage product of claim 8 , wherein the stabilizer comprises 0.2 to 2.0% by weight of total product.
15. A method for preparing a stabilizer, comprising the steps of:
i) preparing a moist wetcake of hydrolyzed colloidal microcrystalline cellulose comprised of crystallites;
ii) preparing a dry blend of low DS carboxymethyl cellulose having a viscosity of 30-85 cP in 2% deionized water, measured with a Brookfield RV viscometer at room temperature and 60 rpm, and a DS of about 0.60 to about 0.85, with a medium DS carboxymethyl cellulose having a viscosity of 400-800 cP in 2% deionized water, measured with a Brookfield RV viscometer at room temperature and 30 rpm, and a DS of about 0.80 to about 0.95;
iii) blending the wetcake i) with the dry blend ii); and
iv) co-attriting the blend iii),
wherein the weight ratio of microcrystalline cellulose/low DS carboxymethyl cellulose/medium DS carboxymethyl cellulose is in the range of from about 92/4/4 to about 88/6/6.
16. The method of claim 15 , further comprising: the step of spray drying the co-attrited blend iv) to form a powder.
17. The method of claim 15 , wherein the wetcake comprises about 38-60% wt. water.
18. The method of claim 15 wherein the co-attrition step iii) is performed in an extruder, refiner, planetary mixer, colloidal mill, beat mill, kneader, or grinder.