Room temperature curable organopolysiloxane composition for protecting electric/electronic parts
A room temperature curable organopolysiloxane composition for protecting electric/electronic parts is disclosed. The composition comprises: (A) an organopolysiloxane having a viscosity at 25° C. of 20 to 1,000,000 mPa·s and having at least two silicon atom-bonded hydroxyl groups or silicon atom-bonded alkoxy groups in a molecule; (B) an alkoxysilane represented by the following general formula or a partial hydrolysis condensation product thereof: R 1 a Si(OR 2 ) (4-a) wherein R 1 is a monovalent hydrocarbon group having a carbon number of 1 to 12, R 2 is an alkyl group having a carbon number of 1 to 3, and subscript “a” is an integer of 0 to 2; (C) a mercaptobenzothiazole based compound; (D) zinc oxide powder and/or zinc carbonate powder; and (E) a catalyst for condensation reactions. The composition and/or a cured product thereof can protect electric/electronic parts from corrosive gases such as hydrogen sulfide gas and sulfuric acid contained in the atmosphere.
1. A room temperature curable organopolysiloxane composition for protecting electric/electronic parts, the room temperature curable organopolysiloxane composition comprising:
(A) 100 parts by mass of an organopolysiloxane having a viscosity at 25° C. of 20 to 1,000,000 mPa·s and having at least two silicon atom-bonded alkoxy groups in a molecule;
(B) 0.5 to 15 parts by mass of an alkoxysilane represented by the following general formula or a partial hydrolysis condensation product thereof:
R 1 a Si(OR 2 ) (4-a)
wherein R 1 is a monovalent hydrocarbon group having a carbon number of 1 to 12, R 2 is an alkyl group having a carbon number of 1 to 3, and subscript “a” is an integer of 0 to 2;
(C) 0.001 to 0.5 parts by mass of a mercaptobenzothiazole based compound;
(D) 0.1 to 30 parts by mass of zinc oxide powder having a BET specific surface area of at least 10 m 2 /g; and
(E) 0.1 to 10 parts by mass of a catalyst for condensation reactions.
2. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , wherein component (C) is mercaptobenzothiazole, dibenzothiazyl disulfide, a sodium salt of mercaptobenzothiazole, a zinc salt of mercaptobenzothiazole, a cyclohexylamine salt of mercaptobenzothiazole, morpholinodithiobenzothiazole, N-cyclohexyl-benzothiazolyl sulfenamide, N-oxydiethylene-benzothiazolyl sulfenamide, or N-tert-butylbenzothiazolyl sulfenamide.
3. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , wherein component (A) comprises a dimethylpolysiloxane having both molecular chain terminals blocked with trimethoxysiloxy groups.
4. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , wherein component (B) comprises a trifunctional alkoxysilane.
5. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 4 , wherein component (B) comprises methyltrimethoxysilane.
6. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , wherein component (C) comprises mercaptobenzothiazole.
7. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , wherein the zinc oxide powder has a BET specific surface area of at least 50 m 2 /g.
8. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , wherein component (E) comprises a titanium compound.
9. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 , further comprising a filler different from component (D).
10. A cured product formed from the room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 1 .
11. An electric/electronic part comprising the cured product according to claim 10 .
12. The room temperature curable organopolysiloxane composition for protecting electric/electronic parts according to claim 9 , comprising an inorganic filler comprising silica.