Gel network hair treatment compositions with reduced odor
The invention relates to a hair colouring and/or bleaching composition comprising at least a first aqueous component (i) and a second aqueous component (ii) being mixed prior to application onto hair, wherein the first component (i) or the second component (ii) or both components (i) and (ii) comprise a gel-network system consisting of multi-lamellar sheets and vesicles with d-spacing (interlayer spacing between sheets) between 5 nm and 50 nm, preferably 10 nm to 30 nm, more preferred 15 nm to 25 nm as measured by Small Angle X-Ray Scattering (SAXS), and the first component (i) or the second component (ii) or both comprise at least a first malodor suppressant being a compound having a distribution coefficient log P of 2 or more and a molecular weight of between 100 and 400, a method for coloring or bleaching hair, a kit comprising the above components and the use of the described hair coloring composition for colouring and/or bleaching hair with a reduced or eliminated ammonia odour.
1. A hair coloring and/or bleaching composition comprising:
a first aqueous component (i) comprising one or more oxidizing agent(s) in a cosmetically acceptable carrier; and,
a second aqueous component (ii) comprising one or more alkalizing agent(s) comprising ammonia, its salts or mixtures thereof in a cosmetically acceptable carrier,
wherein the first aqueous component (i) and the second aqueous component (ii) are mixed in a ratio ranging from 5:1 to 1:5, and the total composition after mixing the first aqueous component (i) and the second aqueous component (ii) comprises:
a) a linear and/or branched C12 to C30 fatty alcohol at from 0.5% to 20% relative to the total composition after mixing,
b) one or more polyoxyethylene C12-C30 alkyl ether nonionic surfactants at from 0.1% to 5% relative to the total composition after mixing,
c) a phosphate ester compound selected from the group consisting of alkyl phosphate ester, alkoxylated alkyl phosphate esters, and mixtures thereof at from 0.3% to 8% relative to the total composition after mixing;
d) an anionic surfactant other than the phosphate ester at from about 1% or less relative to the total composition after mixing;
e) optionally at least one oxidative dye precursor and at least one coupler or a mixture of two or more thereof;
wherein the first aqueous component (i) or the second aqueous component (ii) or both of the first aqueous component (i) and the second aqueous component (ii) comprise a gel-network system consisting of multi-lamellar sheets or vesicles or both, with d-spacing between 5 nm and 50 nm as measured by Small Angle X-Ray Scattering, and
wherein the first aqueous component (i) or the second aqueous component (ii) or both of the first aqueous component (i) and second aqueous component(ii) comprise a malodor suppressant consisting of isopropyl myristate.
2. The hair coloring and/or bleaching composition according to claim 1 wherein the total composition after mixing the first aqueous component (i) and the second aqueous component (ii) comprises
optionally from 0.5% to 30%, by total weight of the composition, of a fatty compound selected from the group consisting of mineral oil, hydrocarbon oil, and mixtures thereof.
3. The hair coloring and/or bleaching composition according to claim 1 , wherein the linear and/or branched C12 to C30 fatty alcohol is selected from the group consisting of cetyl alcohol, stearyl alcohol, cetearyl alcohol, behenyl alcohol, and mixtures of two, three or more thereof.
4. The hair coloring and/or bleaching composition according to claim 1 , wherein the one or more polyoxyethylene C12-C30 alkyl ether nonionic surfactants is selected from the group consisting of polyoxyethylene C12 to C30 alkyl ethers having at least 2 ethylene oxide units, polyoxyethylene C12 to C30 alkyl ethers having from 20 to 300 ethylene oxide units, polyoxyethylene C12 to C30 alkyl ethers having from 100 to 200 ethylene oxide units, ceteareth-25, steareth-20, steareth-100, steareth-150, steareth-200, and mixtures thereof.
5. The hair coloring and/or bleaching composition according to claim 1 , wherein the composition comprises from 0.2% to 3% or from 0.3% to 1.5%, of one or more C12-C30 alkyl ether nonionic surfactants by total weight of the composition.
6. The hair coloring and/or bleaching composition according to claim 1 , wherein the phosphate ester compound is selected from the group consisting of C12 to C30 alkyl phosphate esters, alkoxylated C12 to C30 alkyl phosphate esters, and mixtures thereof; alternatively from the group consisting of C12 to C18 alkyl phosphate esters, alkoxylated C12 to C18 alkyl phosphate esters, and mixtures thereof; alternatively from the group consisting of oleth-3 phosphate, oleth-5 phosphate, oleth-10 phosphate, cetoleth-5 phosphate, cetoleth-10 phosphate, trideceth-5 phosphate, trideceth-6 phosphate, trideceth-10 phosphate, cetyl phosphate, dicetyl phosphate, oleyl phosphate, dioleyl phosphate, stearyl phosphate, C9-15 alkyl phosphate, ceteareth-2 phosphate, ceteareth-20 phosphate, ceteth-10 phosphate, deceth-4 phosphate, glycereth-26 phosphate, PPG-5-ceteth-10 phosphate, steareth-2 phosphate, DEA-oleth-3 phosphate, DEA-oleth-3 phosphate, PEG-5 ethylhexyl ether phosphate, and mixtures thereof; alternatively from the group consisting of PPG-5-ceteth-10 phosphate, oleth-3 phosphate, oleth-10 phosphate, ceteth-10 phosphate, dicetyl phosphate, cetyl phosphate, stearyl phosphate, ceteareth-2 phosphate, and mixtures thereof; alternatively from the group consisting of ceteth-10 phosphate, dicetyl phosphate, ceteareth-2 phosphate, and mixtures thereof.
7. A hair coloring and/or bleaching composition according to claim 1 , wherein the amount of isopropyl myristate is at least 0.1% by weight.
8. A hair coloring or bleaching composition according to claim 1 , wherein the composition after mixing the first aqueous component (i) and the second aqueous component (ii) has a viscosity of from 150 to 2000 cPs.
9. A method of treating hair comprising the steps of applying a composition after mixing according to claim 1 to the hair, leaving said composition on the hair for from 2 to 60 minutes and subsequently rinsing said composition from the hair.
10. A method according to claim 9 wherein said composition is retained on the hair for a time period of less than 50 minutes.
11. A method of sequential oxidative hair coloring or hair bleaching comprising the steps of at least two sequential oxidative hair color or hair bleaching treatments, wherein the time period between each treatment is from 1 day to 60 days, and wherein each treatment comprises the steps of providing a composition according to claim 1 , applying said composition to the hair, retaining said composition on the hair for a time period of less than 50 minutes and subsequently rinsing the composition from the hair.
12. A method for coloring and/or bleaching hair with a reduced or eliminated ammonia odor comprising applying the composition of claim 1 to hair.
13. A hair coloring or bleaching kit comprising
An individually packaged first aqueous component (i) comprising, in a cosmetically acceptable carrier, one or more oxidizing agent(s) and
An individually packaged second aqueous component (ii) comprising in a cosmetically acceptable carrier, one or more alkalizing agent(s) selected from the group consisting of ammonia, its salts and mixtures thereof,
wherein the first aqueous component (i) or the second aqueous component (ii) or both the first aqueous component (i) and the second aqueous component (ii) comprise a gel-network system including multi-lamellar sheets or vesicles or both, with d-spacing between 5 nm and 50 nm as measured by Small Angle X-Ray Scattering, and the first aqueous component (i) or the second aqueous component (ii) or both comprise:
a) a linear and/or branched C12 to C30 fatty alcohol,
b) one or more polyoxyethylene C12-C30 alkyl ether nonionic surfactants,
c) a phosphate ester compound selected from the group consisting of alkyl phosphate ester, alkoxylated alkyl phosphate ester, and mixtures thereof,
d) less than 1% of an anionic surfactants other than phosphate esters and,
wherein the first aqueous component (i) or the second aqueous component (ii) or both comprise a malodor suppressant of isopropyl myristate.