OSMOTICALLY DRIVEN MEMBRANE PROCESSES AND SYSTEMS AND METHODS FOR DRAW SOLUTE RECOVERY
The invention relates to osmotically driven membrane processes and systems and methods for recovering draw solutes in the osmotically driven membrane processes. Osmotically driven membrane processes involve the extraction of a solvent from a first solution by using a second concentrated solution to draw the solvent from the first solution across a semi-permeable membrane. Draw solute recovery may be carried out by various means to recover and recycle draw solutes contained within a diluted second solution and obtain a product solvent.
1 . An apparatus for recovering draw solution solutes from a dilute draw solution, the apparatus comprising:
an osmotically driven membrane system comprising one or more forward osmosis membranes, wherein the osmotically driven membrane system is configured to introduce a feed solution to a first side of the membranes and a concentrated draw solution to a second side of the membranes and output a concentrated feed solution from the first sides of the membranes and the dilute draw solution from the second sides of the membranes; and
a separation system in fluid communication with the osmotically driven membrane system and configured to receive the concentrated feed solution and the dilute draw solution, the separation system comprising:
a first distillation apparatus in fluid communication with the second sides of the membranes and configured for receiving the dilute draw solution and outputting a first vaporized draw solute stream and a product solvent in response to the introduction of a source of thermal energy;
a second distillation apparatus in fluid communication with the first sides of the membranes and configured for receiving the concentrated feed solution and outputting a second vaporized draw solute stream and a further concentrated feed solution in response to the introduction of a source of thermal energy;
a condenser disposed downstream of and in fluid communication with the first and second distillation apparatus, the condenser configured for receiving the first and second vaporized draw solute streams and a cooling fluid and outputting an at least partially condensed draw solute stream comprising condensed and vaporized draw solutes;
a closed absorption system disposed downstream of and in fluid communication with the condenser and configured for receiving the vaporized portion of draw solutes and the condensed portion of draw solutes and outputting a re-concentrated draw solution stream for return to the osmotically driven membrane system, wherein the closed absorption system comprises an absorber comprising a column and a sump, and a recirculation loop comprising a fluid transfer device and a heat exchanger.