Wavelength converting material for a light emitting device
Embodiments of the invention include a luminescent ceramic including (Ba 1-x Sr x ) 2-z Si 5-y O 4y N 8-4y :Eu z 258 phase wavelength converting material (0.5≤x≤0.9; 0≤y≤1; 0.001≤z≤0.02) and M 3 Si 3 O 3 N 4 3334 phase material (M=Ba, Sr, Eu). The M 3 Si 3 O 3 N 4 3334 phase material comprises no more than 5 weight % of the material.
1. A wavelength converting material, comprising:
a ceramic material comprising:
a (Ba 1-x Sr x ) 2-z Si 5-y O 4y N 8-4y :Eu z wavelength converting material in a first crystalline phase where 0.5≤x≤0.9; 0≤y≤1; and 0.001≤z≤0.02; and
a M 3 Si 3 O 3 N 4 material in a second crystalline phase where M is Ba, Sr, Eu, or combinations thereof; the second crystalline phase different from the first crystalline phase and comprising no more than 5 weight % of a total amount of crystalline phases in the ceramic material.
2. The wavelength converting material of claim 1 , wherein the first crystalline phase has an orthorhombic lattice metric and a cell constant ratio a*c/b 2 between 1.1290 and 1.1205.
3. The wavelength converting material of claim 1 , wherein the first crystalline phase has lattice symmetry characterized by IUC space group Pmn2 1 .
4. The wavelength converting material of claim 1 , wherein a ratio of an intensity of an X-ray powder diffraction peak of the second crystalline phase to an intensity of an X-ray powder diffraction peak of the first crystalline phase is in the range 0-0.25.
5. The wavelength converting material of claim 1 , wherein the ceramic material further comprises a M′ 2 SiO 4 material in a third crystalline phase where M′ is Ba, Sr, Eu, or combinations thereof, the third crystalline phase different from the first and second crystalline phases, the third crystalline phase comprising no more than 7 weight % of the total amount of crystalline phases in the ceramic material.
6. The wavelength converting material of claim 1 , wherein the ceramic material further comprises a M″Si 7 N 10 material in a fourth crystalline phase where M″ is Ba, Sr, Eu, or combinations thereof, the fourth crystalline phase different from the first and second crystalline phases, the fourth crystalline phase comprising less than 5 weight % of the total amount of crystalline phases in the ceramic material.
7. A device, comprising:
a light emitting diode that emits blue light; and
a wavelength converting ceramic disposed in a path of the blue light, the wavelength converting ceramic comprising:
a (Ba 1-x Sr x ) 2-z Si 5-y O 4y N 8-4y :Eu z wavelength converting material in a first crystalline phase where 0.5≤x≤0.9; 0≤y≤1; and 0.001≤z≤0.02; and
a M 3 Si 3 O 3 N 4 material in a second crystalline phase where M is Ba, Sr, Eu, or combinations thereof; the second crystalline phase different from the first crystalline phase and comprising no more than 5 weight % of a total amount of crystalline phases in the wavelength converting ceramic.
8. The device of claim 7 , wherein the wavelength converting ceramic further comprises a M′ 2 SiO 4 material in a third crystalline phase where M′ is Ba, Sr, Eu, or combinations thereof, the third crystalline phase different from the first and second crystalline phases, the third crystalline phase comprising no more than 7 weight % of the total amount of crystalline phases in the wavelength converting ceramic.
9. The device of claim 7 , wherein the wavelength converting ceramic further comprises a M″Si 7 N 10 material in a fourth crystalline phase where M″ is Ba, Sr, Eu, or combinations thereof, the fourth crystalline phase different from the first and second crystalline phases, the fourth crystalline phase comprising less than 5 weight % of the total amount of crystalline phases in the wavelength converting ceramic.
10. The device of claim 7 , wherein the wavelength converting ceramic emits amber light, the device further comprising a wavelength converting material that emits red light.
11. A method for preparing a ceramic, comprising:
forming precursors;
transferring the precursors into a ceramic green body;
firing or sintering the ceramic green body to form a ceramic comprising a (Ba 1-x Sr x ) 2-z Si 5-y O 4y N 8-4y :Eu z wavelength converting material in a first crystalline phase where 0.5≤x≤0.9; 0≤y≤1; and 0.001≤z≤0.02; and a M 3 Si 3 O 3 N 4 material in a second crystalline phase where M is Ba, Sr, Eu, or combinations thereof, the second crystalline phase different from the first crystalline phase; and
after forming the ceramic, reducing a weight percent of the second crystalline phase material.
12. The method of claim 11 , wherein reducing a weight percent of the second crystalline phase comprises heating the ceramic to a temperature between 1350 and 1700° C. under a nitrogen pressure between 20 and 300 MPa for between 0.5 and 24 hours.
13. The method of claim 11 , wherein reducing a weight percent of the second crystalline phase comprises heating the ceramic to a temperature between 1450 and 1550° C. under a nitrogen pressure between 50 and 150 MPa for between 4 and 8 hours.
14. The method of claim 11 , wherein reducing a weight percent of the second crystalline phase comprises reducing the weight percent to no more than 10 weight percent of total crystalline phases in the ceramic.
15. The method of claim 11 , wherein reducing a weight percent of the second crystalline phase comprises reducing the weight percent to no more than 5 weight percent of total crystalline phases in the ceramic.